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Enhancement of anticorrosion protection via inhibitor-loaded ZnAlCe-LDH nanocontainers embedded in sol–gel coatings

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Abstract

Inhibitor-loaded ZnAlCe layered double hydroxide (LDH) nanocontainers were prepared through the co-precipitation method. Vanadate and molybdate were used as guest inhibitors intercalating in the interlayer galleries of ZnAlCe-LDHs. The samples were characterized in terms of morphology, structure, and release behavior by scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), and inductively coupled plasma (ICP) techniques. To investigate inhibition behavior, the LDHs particles were embedded in a hybrid sol–gel (SiO x /ZrO x ) layer on aluminum alloy 2024 measured by electrochemical impedance spectroscopy (EIS). The EIS results show that the sol–gel coating with inhibitor-loaded ZnAlCe-LDH particles exhibits high corrosion resistance due to the active inhibition by the dissolution of ZnAlCe-LDHs and inhibitor anions and the exchange behavior of LDHs. Compared with the addition of ZnAlCe-MoO4-LDHs, the coating embedded with ZnAlCe-V2O7-LDHs exhibited better anticorrosion abilities and provided effective protection after a long immersion time.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant No. 51601015), URT program of Beijing Institute of Petrochemical Technology (2016J00148 and 2016J00149).

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing, 102617, China

    You Zhang, Peihang Yu, Junjie Wu, Fei Chen, Yulin Zhang, You Zuo & Yangaolin Qi

  2. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

    Peihang Yu & You Zuo

  3. Chinalco Research Institute of Science and Technology, Beijing, 100082, China

    Yindong Li

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  1. You Zhang
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Correspondence to You Zhang or Fei Chen.

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Zhang, Y., Yu, P., Wu, J. et al. Enhancement of anticorrosion protection via inhibitor-loaded ZnAlCe-LDH nanocontainers embedded in sol–gel coatings. J Coat Technol Res 15, 303–313 (2018). https://doi.org/10.1007/s11998-017-9978-6

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