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Intercalated polybenzoxazine/organoclay composites with enhanced performance in corrosion resistance

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Abstract

Organoclays modified by two different pillaring agents were introduced in polybenzoxazine (PBz) coatings on mild steel (MS). Both physicochemical properties and corrosion protection performance of composite coatings were fully investigated with the assistance of FTIR, XRD, AFM, SEM, and electrochemical measurements. The octadecyl quaternary ammonium-modified organoclays exhibited an exfoliated structure in polymer matrix, which benefited little in coatings’ barrier property. However, organoclays modified by dimethyl dioctadecyl quarternary ammonium induced an intercalated structure in composites, which greatly enhanced the corrosion resistance of poly(BA-aptms) with corrosion rate reduced by 3 and 4 orders of magnitude, respectively, compared to PBz and bare MS when 3 wt% of organoclays were added.

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Acknowledgments

This research was financially supported by the Fundamental Research Funds for the Central Universities (WA1514015), China Postdoctoral Science Foundation (2015M571509), Nanotech Foundation of Science and Technology Co and Technology Commission of Shanghai Municipality (0652nm001), the National Natural Science Funds of China (u1162110), Program of Shanghai Subject Chief Scientist (10XD1401500), and Lanpec Technologies Co, Ltd.

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Authors and Affiliations

  1. Shanghai Key Laboratory of Multiphase Structural Materials Chemical Engineering, State Key Laboratory of Chemistry Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China

    Changlu Zhou, Xin Lu & Zhong Xin

  2. Lanpec Technologies Co. Ltd, Gansu, 730070, China

    Yanfeng Zhang

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  1. Changlu Zhou
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  2. Xin Lu
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  3. Zhong Xin
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Correspondence to Zhong Xin.

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Zhou, C., Lu, X., Xin, Z. et al. Intercalated polybenzoxazine/organoclay composites with enhanced performance in corrosion resistance. J Coat Technol Res 13, 63–72 (2016). https://doi.org/10.1007/s11998-015-9722-z

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  • DOI: https://doi.org/10.1007/s11998-015-9722-z

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