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Protective Coatings Containing ZnMOF-BTA Metal–Organic Framework for Active Protection of AA2024-T3

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Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

ZnMOF-BTA, a new metal–organic framework with excellent anti-corrosion properties was prepared and characterized. Polarization and immersion tests in 3.5 wt% NaCl were performed on AA2024-T3 alloy to assess the corrosion inhibition ability of ZnMOF-BTA. It showed an inhibition efficiency of more than 90%, indicating excellent corrosion inhibition of ZnMOF-BTA on AA 2024-T3 in NaCl. Moreover, ZnMOF-BTA particles were incorporated into polyurethane coatings to create corrosion-resistant coatings. Electrochemical tests and neutral salt spray analysis were used to assess the corrosion protection ability of ZnMOF-BTA-laden polyurethane coatings. The results of electrochemical impedance spectra clearly showed the outstanding corrosion resistance and durability of ZnMOF-BTA coatings after 1440 h of immersion with a high pore resistance (Rpo) of 1.76 × 1010 Ω cm2. In addition, during the cross-cut adhesion test, the coating did not detach from the substrate, and after the impact test, there was scarcely any indication of a fracture, which further supports the notion that the coating has strong adhesion to the substrate.

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Acknowledgements

The authors acknowledge financial support from the National Natural Science Foundation of China (Nos. 52171089 and 51571202) and the LingChuang Research Project of China National Nuclear Corporation (No. E041F212Z1).

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Authors and Affiliations

  1. CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China

    Izuchukwu K. Nwokolo, Hongwei Shi, Sharjeel Ahmed, Jiwen Li & Fuchun Liu

  2. School of Materials Science and Engineering, University of Science and Technology of China, Hefei, 230026, China

    Izuchukwu K. Nwokolo, Hongwei Shi, Sharjeel Ahmed, Jiwen Li & Fuchun Liu

  3. School of Materials Science and Engineering, Shenyang University of Technology, Shenyang, 110870, China

    Hongwei Shi

  4. ZJU-UIUC Institute, International Campus, Zhejiang University, Haining, 314400, China

    Paul C. Uzoma

  5. Institute of Corrosion Science and Technology, Guangzhou, 510530, China

    Fuchun Liu

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  1. Izuchukwu K. Nwokolo
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Nwokolo, I.K., Shi, H., Uzoma, P.C. et al. Protective Coatings Containing ZnMOF-BTA Metal–Organic Framework for Active Protection of AA2024-T3. Acta Metall. Sin. (Engl. Lett.) 36, 1893–1908 (2023). https://doi.org/10.1007/s40195-023-01600-0

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