Abstract
Biodiesel commonly experiences oxidative and hydrolytic degradations, leading to problems of low storage stability and corrosion of fuel containers. The present study investigates the fabrication and use of electroless-deposited nickel alloys, containing phosphorus and tungsten, as potential coating materials that effectively protect steel-based biodiesel containers from corrosion. Through long-term static immersion and high-temperature oxidation tests, coupled with surface analyses of the coatings and assessments of the biodiesel’s acidity and storage stability, it is determined that a nickel coating with 15 wt% of phosphorus is favorably compatible with biodiesel, both in terms of corrosion protection and fuel stability.
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References
Meher, L, Vidya Sagar, D, Naik, S, “Technical Aspects of Biodiesel Production by Transesterification: A Review.” Renew. Sustain. Energy Rev., 10 248–268 (2006)
Madras, G, Kolluru, C, Kumar, R, “Synthesis of Biodiesel in Supercritical Fluids.” Fuel, 83 2029–2033 (2004)
Ma, F, Hanna, M, “Biodiesel Production: A Review.” Bioresour. Technol., 70 1–16 (1999)
Ramadhas, A, Jayaraj, S, Muraleedharan, C, “Biodiesel Production from High FFA Rubber Seed Oil.” Fuel, 84 335–340 (2005)
Sharma, Y, Singh, B, “Development of Biodiesel: Current Scenario.” Renew. Sustain. Energy Rev., 13 1646–1651 (2009)
Tickell, J, Roman, K, Tickell, K, From the Fryer to the Fuel Tank: The Complete Guide to Using Vegetable Oil as an Alternative Fuel. Biodiesel America, 2000
Nabi, M, Akhter, M, Zaglul Shahadat, M, “Improvement of Engine Emissions with Conventional Diesel Fuel and Diesel-Biodiesel Blends.” Bioresour. Technol., 97 372–378 (2006)
US EPA, A Comprehensive Analysis of Biodiesel Impacts on Exhaust Emissions. US EPA, Washington, 2002
Cannell, M, “Carbon Sequestration and Biomass Energy Offset: Theoretical, Potential and Achievable Capacities Globally, in Europe and the UK.” Biomass Bioenergy, 24 97–116 (2003)
Tilman, D, Hill, J, Lehman, C, “Carbon-Negative Biofuels from Low-Input High-Diversity Grassland Biomass.” Science, 314 1598–1600 (2006)
Gubler, R, “Subsidies and Regulations Keep Biodiesel Markets Growing.” Ind. Biotechnol., 3 22–24 (2007)
deMan, J, Tie, F, DeMan, L, “Formation of Short Chain Volatile Organic Acids in the Automated AOM Method.” J. Am. Oil Chem. Soc., 64 993–996 (1987)
Loury, M, “Possible Mechanisms of Autoxidative Rancidity.” Lipids, 7 671–675 (1972)
Waynick, J, Characterization of Biodiesel Oxidation and Oxidation Products: CRC Project No. AVFL-2b. National Renewable Energy Laboratory: NREL/TP-540-39096 (2005)
Bondioli, P, Gasparoli, A, Lanzani, A, et al., “Storage Stability of Biodiesel.” J. Am. Oil Chem. Soc., 72 699–702 (1995)
Knothe, G, “Analyzing Biodiesel: Standards and Other Methods.” J. Am. Oil Chem. Soc., 83 823–833 (2006)
Geller, D, Adams, T, Goodrum, J, et al., “Storage Stability of Poultry Fat and Diesel Fuel Mixtures: Specific Gravity and Viscosity.” Fuel, 87 92–102 (2008)
Kaul, S, Saxena, R, Kumar, A, et al., “Corrosion Behavior of Biodiesel from Seed Oils of Indian Origin on Diesel Engine Parts.” Fuel Process. Technol., 88 303–307 (2007)
Knothe, G, Dunn, R, “Dependence of Oil Stability Index of Fatty Compounds on Their Structure and Concentration and Presence of Metals.” J. Am. Oil Chem. Soc., 80 1021–1026 (2003)
Ashassi-Sorkhabi, H, Rafizadeh, S, “Effect of Coating Time and Heat Treatment on Structures and Corrosion Characteristics of Electroless Ni–P Alloy Deposits.” Surf. Coat. Technol., 176 318–326 (2004)
Peeters, P, Hoorn, G, Daenen, T, et al., “Properties of Electroless and Electroplated Ni–P and its Application in Microgalvanics.” Electrochim. Acta, 47 161–169 (2001)
ASTM G31-72, Standard Practice for Laboratory Immersion Corrosion Testing of Metals. Annual Book of ASTM Standards. ASTM, Philadelphia, PA, 2004
Firestone, D, Official Methods and Recommended Practices of the American Oil Chemists’ Society. AOCS, Champaign, IL, 2004
Knothe, G, “Some Aspects of Biodiesel Oxidative Stability.” Fuel Process. Technol., 88 669–677 (2007)
Leung, D, Koo, B, Guo, Y, “Degradation of Biodiesel Under Different Storage Conditions.” Bioresour. Technol., 97 250–256 (2006)
Balaraju, J, Anandan, C, Rajam, K, “Influence of Codeposition of Copper on the Structure and Morphology of Electroless Ni–W–P Alloys from Sulphate- and Chloride-Based Baths.” Surf. Coat. Technol., 200 3675–3681 (2006)
Palaniappa, M, Seshadri, S, “Friction and Wear Behavior of Electroless Ni–P and Ni–W–P Alloy Coatings.” Wear, 265 735–740 (2008)
Peng, C, Lan, C, Dai, Y, “Speciation and Quantification of Vapor Phases in Soy Biodiesel and Waste Cooking Oil Biodiesel.” Chemosphere, 65 2054–2062 (2006)
Miyashita, K, Takagi, T, “Study on the Oxidative Rate and Prooxidant Activity of Free Fatty Acids.” J. Am. Oil Chem. Soc., 63 1380–1384 (1986)
Waynick, J, “Evaluation of the Stability, Lubricity, and Cold Flow Properties of Biodiesel Fuels.” Proc. 6th International Conference on Stability and Handling of Liquid Fuels, Vancouver, BC, Canada, 1997
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The authors acknowledge the support (contract P-00-30268) from the Metal and Materials Technology Center (MTEC), National Science and Technology Development Agency (NSTDA), Thailand.
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Sukkasi, S., Sahapatsombut, U., Sukjamsri, C. et al. Electroless Ni-based coatings for biodiesel containers. J Coat Technol Res 8, 141–147 (2011). https://doi.org/10.1007/s11998-010-9286-x
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DOI: https://doi.org/10.1007/s11998-010-9286-x