Abstract
Thermal energy release and hydrogen generation due to breakaway oxidation of Zr fuel cladding materials are of concern in accident scenarios involving extreme temperature increase (up to 1200 °C). As a result, potential accident tolerant fuel cladding (ATFC) materials and coatings are being investigated. Physical vapor deposited CrN coatings are considered as possible protective barrier materials for Zircaloys. In addition, Fe–Cr-Al alloys are considered potential candidate materials for ATFC due the formation of protective alumina at high temperatures which maintains resistance by preventing oxide breakdown. Both CrN-coated Zircaloys and a Fe–Cr-Al model alloy were exposed to 300 °C water and steam environments up to 1200 °C to evaluate their resistance to corrosion under normal reactor operating conditions and to high temperature steam oxidation. Surface analytical techniques are used to evaluate the effectiveness of oxides and/or coatings over the 300 °C water to 1000 °C steam temperature regime.
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Daub, K., Persaud, S.Y., Rebak, R.B., Van Nieuwenhove, R., Ramamurthy, S., Nordin, H. (2019). Investigating Potential Accident Tolerant Fuel Cladding Materials and Coatings. In: Jackson, J., Paraventi, D., Wright, M. (eds) Proceedings of the 18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems – Water Reactors. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-04639-2_95
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DOI: https://doi.org/10.1007/978-3-030-04639-2_95
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