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Anode electrochemical thermal modification of metals and alloys

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Abstract

This scientific review is devoted to the mechanism of the anode heating in aqueous electrolytes and its application for the heat and thermochemical treatment of steels and titanium alloys. The heating and electrochemical peculiarities of the anode hardening are considered, the technological possibilities for improving the operational properties using nitrohardening, carbonizing, or oxidation are described. A short history of the studies and designs including industrial devices for the technologies of the anode hardening is presented.

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References

  1. Lazarenko, B.R, Fursov, S.P, Faktorovich, A.A., Galanina, E.K., and Duradzhi, V.N., Kommutatsiya toka na granitse metal-elektrolit (Current Commutation at an Interface of Metal-Electrolyte), Kishinev: Rus. Istor. Soc. Acad. Nauk of Soviet Socialist Republic of Moldova, 1971, pp. 11–13.

    Google Scholar 

  2. Yasnogorodckii, I. Z., Electrolyte Heating of Metals, in Elektrokhimicheskaya i elektromekhanicheskaya obrabotka metallov (Electrochemical and Electromechanical Treatment of Metals), Leningrad: Mashinostr., 1971.

    Google Scholar 

  3. Vanin, V.S., Heating Metals in Electrolyte, Elektrotermiya, 1967, no. 55, pp. 18–19.

  4. Brinza, V.N., Anagorskii, L.A., Frantsenyuk, I.V., Chulkov, V.V., Chernenilov, M.F., Piseukov, B.A., Malyshko, N.F., and Losikhin, V.M., USSR, Inventor’s Certifiate no. 296829, Byull. Izobret., 1983, no. 9.

  5. Belkin, P.N., Elektrokhimiko-termicheskaya obrabotka metallov i splavov, (Electrochemical and Thermal Treatment of Metals and alloys), Moscow: Mir, 2005.

    Google Scholar 

  6. Duradzhi, V.N. and Parsadanyan, A.S., Nagrev metallov v elektrolitnoi plazme (Electrolyte Plasma Heating of Metals), Chisinau: Shtiintsa, 1988.

    Google Scholar 

  7. Belkin, P.N., Ganchar, V.I., and Petrov, Yu.N., Investigation of a Vapor Film Conduction upon Anode Electrolyte Heating, Dokl. Akad. Nauk of Soviet Union, 1986, vol. 291, no. 5, pp. 1116–1119.

    Google Scholar 

  8. Belkin, P.N., Ganchar, V.I., Davydov, A.D., Dikusar, A.I., and Pasinkovskii, E.A., Anodic Heating in Aqueous Solutions of Electrolytes and its Use for Treating Metal Surfaces, Surf. Eng. Appl. Electrochem., 1997. no 2., pp. 1–15.

  9. Belkin, P.N., Thermal and Physical Peculiarities of Anode Heating in Aqueous Electrolytes, Mater. 2-oi mezhdunarod. konf. po elektrochim. i elektrolitnoplazm. metodam modifik. metal. poverkhnostei (Proc. 2nd Int. Conf. Electrochem. Electrolyte-Plasmic Meth. Modif. Metal Surf.), Kostroma, Nekrasov Gos. Univ.; Moscow, Inf. Tsentr MATI-Tsiolkovskii RGTU, 2007, pp. 175–189.

    Google Scholar 

  10. Belkin, P.N. and Belikhov, A.B., Stationary Temperature of the Anode Heated in Aqueous Electrolytes, Inzh. Fiz. Zh., 2002, vol. 75, no. 6, pp. 19–24.

    Google Scholar 

  11. Ganchar, V.I., Parameters of Heat Transfer in the Process of Anode Electrolyte Heating, Inzh. Fiz. Zh., 1991, vol. 60, no. 1, pp. 92–95.

    Google Scholar 

  12. Belkin, P.N., Mukhacheva, T.L., and D’yakov, I.G., Peculiarities of Distribution of Heat Flows in the System Anode-Vapor-Gas Shell upon the Anode Electrolyte Heating, Inzh. Fiz. Zh., 2008, vol. 71, no. 6, pp. 1027–1033.

    Google Scholar 

  13. Ganchar, V.I., Zgardan, I.M., and Dikusar, A.I., Anode Dissolution of Iron in the Process of Electrolyte Heating, Elektron. Obrab. Mater., 1994. no. 4, pp. 69–77.

  14. Ganchar, V.I., Zgardan, I.M., and Dicusar, A.I., Anodic Dissolution of Chromium Upon Electrolyte Heating, Surf. Eng. Appl. Electrochem., 1996. no 5, pp. 13–19.

  15. Zgardan, I.M., Ganchar, V.I., and Dicusar, A.I., Anomalous Dissolution of Copper under Conditions of Electrolytic Heating, Elektrokhimiya., 1999, no.4, pp. 542–544.

  16. Zhirov, A.V., D’yakov, I.G., and Belkin, P.N., Dissolution and Oxidation of Carbon Steels under Anode Heating in Aqueous Solutions, Izv. Vyssh. Uchebn. Zaved. Khim. Khimich. Tekhnol., 2010, no. 3, pp. 89–93.

  17. D’yakov, I.G. and Naumov, A.R., On Electrochemical Reactions under Anode Heating in Aqueous Electrolytes Based on Ammonium Chloride, Elektron. Obrab. Mater., 2006, no. 6, pp. 4–9.

  18. Resner, E., Marks, G., Zaitsev, V.A., and Sukhotin, A.M., Electrode Wear upon Treatment of Low-Carbon Steel in Electrolyte Plasma in the Anode Process, Elektron. Obrab. Mater., 1983, no. 3, pp. 59–61.

  19. Shkurpelo, A.I., Belkin, P.N., and Pasinkovskii, E.A., Phase Composition and Structure of a Surface Layer of Armco Iron and Austenitic Stainless Cr-Ni Steel 12X18H10T after Nitrocementation upon the Anode Electrolyte Heating, Fiz. Khim. Obrab. Mater., 1993, no. 2, pp. 116–125.

  20. Belikhov, A.B. and Belkin, P.N., Peculiarities of Anode Cementation of Iron Graphites, Elektron. Obrab. Mater., 1998, no. 5–6, pp. 23–31.

  21. Belkin, P.N., Krit, B.L., D’yakov, I.G., Vostrikov, V.G., and Mukhacheva, T.L., Anode Saturation of Steels with Nitrogen and Carbon in Aqueous Solutions of Electrolytes that Contain Carbamide, Metalloved. Termich. Obrab. Met., 2010, no. 1, pp. 32–36.

  22. Grishina, E.P., Zhirov, A.V., Belkin, P.N., and Dikusar, A.I., Effect of Anode Electrochemical Thermal Oxidation on Corrosion Resistance of Steel 45, Elektron. Obrab. Mater., 2008, no. 5, pp. 57–62.

  23. Chernova, G.P., Bogdashkina, N.L., Parshutin, V.V., Revenko, V.G., Tomashov, N.D., Belkin, P.N., Pasinkovskii, E.A., and Factorovich, A.A., Electrochemical and Corrosion Behavior of Steel 40X Nitrided in Electrolyte Plasma, Zashchita Met., 1984, vol. 20, no. 3, pp. 408–411.

    Google Scholar 

  24. Revenko, V.G., Chernova, G.P., Parshutin, V.V., Bogdashkina, N.L., Tomashov, N.D., Belkin, P.N., and Pasinkovskii, E.A., Effect of Nitriding in Electrolyte on Protective Properties of Conversion Coatings, Zashchita Met., 1988, vol. 24, no. 2, pp. 204–210.

    Google Scholar 

  25. Blashchuk, V.E., Kareta, N.M., Onoprienko, L.M., Belkin, P.N., and Pasinkovskii, E.A., Effect of Electrolyte Nitriding on Corrosion Resistance of Commercial Titanium VT1-0, Elektron. Obrab. Mater., 1986, no. 3, pp. 20–22.

  26. Duradzhi, V.N., Morar’, N.N., Polotebnova, N.A., and Kiseeva, L.V., On Phase Composition of a Surface of Metals, Treated in Electrolyte Plasma, Elektron. Obrab. Mater., 1986, no. 1, pp. 49–52.

  27. Lazarenko, B.R., Duradzhi, V.N., Factorovich, A.A., and Bryantsev, I.V., USSR Inventor’s Certificate no. 461161, Byull. Izobret., 1975, no. 7.

  28. Duradzhi, V.N., Bryantsev, I.V., and Tovarkov, A.K., USSR, Inventor’s Certificate no. 618447, Byull. Izobret., 1978, no. 29.

  29. Factorovich, A.A., Belkin, P.N., and Pasinkovskii, E.A., USSR, Inventor’s Certificate no. 621799, Byull. Izobret., 1978, no. 32, p. 97.

  30. Belkin, P.N. and Pasinkovskii, E.A., Thermal and Chemicothermal Treatment of Steels upon Heating in Electrolyte Solutions, Metalloved. Termich. Obrab. Met., 1989, no. 5, pp. 12–17.

  31. Kusmanov, S.A., D’yakov, I.G., and Belkin, P.N., Effect of Carbon-Bearing Components of Electrolyte on Characteristics of Chemicothermal Cementation, Vopr. Materialoved., 2009, no. 4, pp. 7–13.

  32. Yerokhin, A.L., Nie, X., Leyland, A., Matthews, A., Dowey, S.J., Plasma Electrolysis for Surface Engineering, Surf. Coat. Techn., 1999, no. 122, pp. 73–93.

  33. Mukhacheva, T.L., D’yakov, I.G., and Belkin, P.N., Peculiarities of Two-Component Saturation of Construction Steels with Nitrogen and Carbon upon Electrolyte Heating, Vopr. Materialoved., 2009, no. 2, pp. 38–45.

  34. Kuzenkov, S.E. and Saushkin, B.P., Steel-45 Borating in Electrolytic Plasma, Elektron. Obrab. Mater., 1996, no. 4–6, pp. 24–28.

  35. Zemskii, S.V., Factorovich, A.A., Belkin, P.N., and Pasinkovskii, E.A., USSR, Inventor’s Certificate no. 969761, Byull. Izobret., 1982, no. 40.

  36. Tarasov, A.N. and Prokof’ev, M.A., Hardening of a Stomatologic Point Tool from Titanium Alloys by Electrolyte Nitriding on an UKHTO-5M Device, Elektron. Obrab. Mater., 1991, no. 2, pp. 20–22.

  37. Tarasov, A.N., Belkin, P.N., Prokof’ev, M.A., and Machulin, S.A., USSR, Inventor’s Certificate no. 1744148, Byull. Izobret., 1992, no. 24.

  38. Belkin, P.N., Borisov, A.M., Vostrikov, V.G., D’yakov, I.G., Romanovskii, E.A., and Serkov, M.V., Application of Spectrometry of NBS of Protons for Study of Anode Chemicothermal Treatment of Titanium, Fiz, Khim. Obrab. Mater., 2006, no. 1, pp. 59–61.

  39. Gertsriken, D.S., Tyshkevich, V.M., Mazanko, V.F., Fal’chenko, V.M., Mikhailov, V.V., Peretyatku, P.V., Pasinkovskii, E.A., and Yanovich, A.I., Peculiarities of Electroerosion Alloying and Electrolyte Heating of Titanium with Nickel Coating, Elektron. Obrab. Mater., 1996, no. 2–3, pp. 11–17.

  40. Mikhailov, V.V., Duradzhi, V.N., Gitlevich, A.E., and Andreeva, L.N., Effect of Electrospark Discharge and Electrolyte Plasma on a Surfac Layer of Metals, Elektron. Obrab. Mater., 1981, no. 5, pp. 26–28.

  41. Lazarenko, B.R., Duradzhi, V.N., Bryantsev, I.V., and Mikhailov, V.V., USSR, Inventor’s Certificate no. 789629, Byull. Izobret., 1980, no. 47.

  42. Ignat’kov, D.A., Michailov, V.V., and Pasinkovskii, E.A., Phase-Structural and Remaining Strain State upon Combined Modification of Metal Surfaces by Electrospark Alloying and Electrolyte Plasmic Nitriding, Mater. 2-oi mezhdunarod. nauch.-tekhn. konf. po elektrochim. i elektrolitnoplazm. metodam modifik. metal. poverkhnostei (Proc. 2nd Int. Conf. Electrochem. Electrolyte-Plasmic Meth. Modif. Metal Surf.), Kostroma, Nekrasov Gos. Univ.; Moscow, Inf. Tsentr MATI-Tsiolkovskii RGTU, 2007, pp. 206–211.

    Google Scholar 

  43. Parshutin, V.V. and Pasinkovskii, E.A., Enhancement of Corrosion Resistance of Steels Using Chemicothermal Treatment in Electrolytes, Elektron. Obrab. Mater., 2007, no. 6, pp. 26–28.

  44. Parshutin, V.V. and Pasinkovskii, E.A., Moldova Patent no. 2959, Byull. Izobret., 2006, no. 1.

  45. Khamurar’, V.I., Belkin, P.N., Ganchar, V.I., Govberg, M.G., and Rozental’, Ya.Sh., USSR, Inventor’s Certificate no. 1349012, Byull. Izobret., 1987, no. 40.

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Correspondence to P. N. Belkin.

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Original Russian Text © P.N. Belkin, 2010, published in Elektronnaya Obrabotka Materialov, 2010, No. 6, pp. 29–41.

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Belkin, P.N. Anode electrochemical thermal modification of metals and alloys. Surf. Engin. Appl.Electrochem. 46, 558–569 (2010). https://doi.org/10.3103/S1068375510060049

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