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Photo- and Electroluminescent Properties of the Yb3+ Complex with Pyrazole-Substituted 1,3-Diketone and 1,10-Phenanthroline

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Abstract

This study is devoted to luminescent properties of the new [Yb(L)3(phen)] complex with near-infrared emission, where L is the anion of 4,4,4-trifluoro-1-(naphthyl-2)butane-1,3-dione, and phen is 1,10-phenanthroline. It is shown that the electronic excitation energy can be efficiently transferred to Yb3+ ion electronic levels by selecting the ligand environment. To study the electroluminescent properties, a multilayer organic light-emitting diode (OLED) with the ITO/PEDOT:PSS/PVK/Yb-complex/TPBi/LiF/Al structure is designed. The efficiency of the fabricated infrared OLED is close to the record values presented in the literature for the close type of the Yb3+ complexes.

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Funding

The [Yb(L)3(phen)] complex synthesis was supported by the Russian Science Foundation, project no. 17-72-20088-p. The study of photophysical properties of the [Yb(L)3(phen)] complex was supported by the Russian Foundation for Basic Research, project no. 20-02-00222.

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Authors and Affiliations

  1. Lebedev Physical Institute, Russian Academy of Sciences, 119991, Moscow, Russia

    M. T. Metlin, D. O. Goryachii, N. P. Datskevich, D. F. Aminev, D. A. Metlina & I. V. Taidakov

  2. Bauman Moscow State Technical University, 105005, Moscow, Russia

    M. T. Metlin

  3. Plekhanov Russian University of Economics, 117997, Moscow, Russia

    I. V. Taidakov

  4. Lomonosov Moscow State University, 119991, Moscow, Russia

    R. K. Asanov

Authors
  1. M. T. Metlin
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  2. D. O. Goryachii
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  3. N. P. Datskevich
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  4. R. K. Asanov
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  5. D. F. Aminev
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  6. D. A. Metlina
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  7. I. V. Taidakov
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Correspondence to M. T. Metlin.

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Translated by A. Kazantsev

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Metlin, M.T., Goryachii, D.O., Datskevich, N.P. et al. Photo- and Electroluminescent Properties of the Yb3+ Complex with Pyrazole-Substituted 1,3-Diketone and 1,10-Phenanthroline. Bull. Lebedev Phys. Inst. 48, 139–143 (2021). https://doi.org/10.3103/S1068335621050055

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