Abstract
The local molecular dynamics in a polymer matrix based on polyvinylbutyral for solid polyelectrolyte is studied by means of FTIR spectroscopy. The effect low molecular weight polyethylene glycols with average masses of 200, 400, and 600 g/mol have on the effective size of the free volume elements and the ionic conductivity in the polymer matrix is considered in the context of the free volume model.
Similar content being viewed by others
REFERENCES
Membrany i membrannye tekhnologii (Membranes and Membrane Technologies), Yaroslavtsev, A.B., Ed., Moscow: Nauchnyi Mir, 2013.
Ivanchev, S.S. and Myakin, S.V., Russ. Chem. Rev., 2010, vol. 79, p. 101.
Wen, C.-Y., Chen, Y.-C., Wang, C.-M., et al., Ionics, 2018, vol. 24, p. 1385.
Wang, W., Guan, S., Li, M., Zheng, J., and Xu, C., Org. Electron., 2018, vol. 56, p. 268.
Chen, K.-F., Liu, C.-H., Hsieh, C.-K., et al., J. Power Sources, 2014, vol. 247, p. 939.
Bhide, A. and Hariharan, K., Eur. Polym. J., 2007, vol. 43, p. 4253.
Kuila, T., Acharya, H., Srivastava, S.K., et al., Mater. Sci. Eng. B, 2007, vol. 137, p. 217.
Kamalova, D.I. and Remizov, A.B., J. Mol. Struct., 2016, vol. 1125, p. 800.
Kamalova, D.I., Remizov, A.B., and Salakhov, M.Kh., Konformatsionnye zondy v izuchenii lokal’noi podvizhnosti polimerov (Conformation Probes in the Study of Local Polymer Motion), Moscow: Fizmatkniga, 2008.
Kamalova, D.I., Shaimukhametova, E.R., and Salakhov, M.Kh., Uch. Zap. Kazan. Univ., Ser. Fiz.-Mat. Nauki, 2013, vol. 155, no. 1, p. 78.
Oh, H.J., Freeman, B.D., McGrath, J.E., Lee, C.H., and Paul, D.R., Polymer, 2014, vol. 55, p. 235.
Kelly, F.N. and Bueche, F.J., J. Polym. Sci., 1961, vol. 50, p. 549.
Van Krevelen, D.W. and Nijenhuis, K.Te., Properties of Polymers, Amsterdam: Elsevier, 2009.
Stolov, A.A., Kamalova, D.I., Remizov, A.B., and Zgadzai, O.E., Polymer, 1996, vol. 37, p. 3049.
Gierke, T.D., Munn, G.E., and Wilson, F.C., J. Polym. Sci., Polym. Phys. Ed., 1981, vol. 19, p. 1687.
Li, Y., Wang, J., Tang, J., Liu, Y., and He, Y., J. Power Sources, 2009, vol. 187, p. 305.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by V. Alekseev
About this article
Cite this article
Kamalova, D.I., Abdrazakova, L.R. & Naumova, S.N. Studying Local Molecular Mobility in the Polymer Matrix of a Fuel Element via FTIR Spectroscopy. Bull. Russ. Acad. Sci. Phys. 83, 360–363 (2019). https://doi.org/10.3103/S1062873819030304
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1062873819030304