Abstract
A method of alloying steel with vanadium by means of vanadium converter slag is considered. Thermodynamic analysis of the reduction of the oxides in vanadium slag during ladle treatment of the steel permits determination of the process parameters. The reduction of elements from oxides present in vanadium slag-in particular, vanadium, iron, and manganese-is evaluated in terms of the residual content of the corresponding oxides. It follows from thermodynamic calculations and experiments that, with optimal proportions of the reducing agents, relatively complete reduction of vanadium (98–99%) and iron from vanadium converter slag by carbon and silicon is possible, with limited reduction of titanium and manganese.
Similar content being viewed by others
References
Rol’ vanadiya v mikrolegirovannykh stalyakh (Role of Vanadium in Microalloyed Steel), Smirnov, L.A., Ed., Yekaterinburg: Gos. Nauchnyi Tsentr RF Ural’skii Institut Metallov, 2001.
Zayats, S., in Problemy proizvodstva i primeneniya stali s vanadiem: Materialy Mezhdunarodnogo nauchno-tekhnicheskogo seminara (Production and Use of Vanadium Steel: Proceedings of an International Seminar), Yekaterinburg: UrO RAN, 2007, pp. 80–95.
Rovnushkin, V.A., in Trudy vtorogo kongressa staleplavil’shchikov (Proceedings of the Second Congress of Steelmakers), Moscow: MISiS, 1994, pp. 250–251.
Rovnushkin, V.A. and Smirnov, L.A., in Problemy proizvodstva i primeneniya stali s vanadiem: Materialy Mezhdunarodnogo nauchno-tekhnicheskogo seminara (Production and Use of Vanadium Steel: Proceedings of an International Seminar), Yekaterinburg: UrO RAN, 2007, pp. 95–121.
Solov’ev, M.A. and Tolstoguzov, N.V., Izv. Vyssh. Uchebn. Zaved., Chern. Metall., 1996, no. 2, pp. 8–12.
Dmitrienko, V.I., Nokhrina, O.I., Rozhikhina, I.D., and Rybenko, I.A., Izv. Vyssh. Uchebn. Zaved., Chern. Metall., 2010, no. 6, pp. 38–41.
Klimov, V.Yu., Mochalov, S.P., and Rybenko, I.A., in Modelirovanie, programmnoe obespechenie i naukoemkie tekhnologii v metallurgii: Trudy Vserossiiskoi nauchnoprakticheskoi konferentsii (Simulation, Software, and High Technology in Metallurgy: Proceedings of a Russian Conference), Novokuznetsk: Izd. SibGIU, 2001, pp. 435–439.
Smirnov, L.A., Proizvodstvo i ispol’zovanie vanadievykh shlakov (Production and Use of Vanadium Slag), Moscow: Metallurgiya, 1985.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.I. Nokhrina, I.D. Rozhikhina, V.I. Dmitrienko, M.A. Golodova, Yu.A. Efimenko, 2014, published in “Izvestiya VUZ. Chernaya Metallurgiya,” 2014, No. 2, pp. 27–30.
About this article
Cite this article
Nokhrina, O.I., Rozhikhina, I.D., Dmitrienko, V.I. et al. Reduction of metals from vanadium converter slag by means of carbon and silicon. Steel Transl. 44, 99–102 (2014). https://doi.org/10.3103/S0967091214020156
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S0967091214020156