Skip to main content
SpringerLink
Log in

Transformation of the polyconjugation systems of humic acids in the course of the metamorphism of caustobioliths

  • Published:
Solid Fuel Chemistry Aims and scope Submit manuscript

Abstract

As found with the use of EPR and IR spectroscopy, the formation of aromatic polyconjugation systems by the destruction of aliphatic molecular fragments is the main transformation mechanism of the molecular structure of the humic acids (HAs) of caustobioliths in the course of their metamorphism. In this case, the final stage of the formation of the polyconjugation systems is the polymerization of monoaromatic fragments. At the stage of the genesis of brown coal, when a sharp decrease in the concentration of monoaromatic fragments is observed and the concentration of the polyconjugation systems increases, the sizes of planar graphite-like structures also increase. It is shown that the method of colloid chemical fractionation [1] makes it possible to obtain HA preparations with regulated concentrations of condensed aromatic structures and aliphatic fragments.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lishtvan, I.I., Kaputskii, F.N., Yanuta, Yu.G., et al., Khim. Interesakh Ustoich. Razvit., 2006, vol. 14, no. 4, p. 391.

    CAS  Google Scholar 

  2. Lukoshko, E.S., Bambalov, N.N., Khoruzhik, A.V., et al., Zapovedniki Belorussii, 1988, no. 12, p. 95.

  3. Lukoshko, E.S., Bambalov, N.N., Khoruzhik, A.V., et al., Khim. Tverd. Topl. (Moscow), 1988, no. 5, p. 3.

  4. Bambalov, N.N., Maryganova, V.V., Prokhorov, S.G., and Strigutskii, V.P., Dokl. Nats. Akad. Nauk Belarusi, 1988, vol. 42, no. 6, p. 95.

    Google Scholar 

  5. Lishtvan, I.I., Dudarchik, V.M., Kovrik, S.I., et al., Kolloidn. Zh., 2009, vol. 71, no. 2, p. 299.

    Google Scholar 

  6. Lishtvan, I.I., Tomson, A.E., Sokolova, T.V., et al., Khim. Tverd. Topl. (Moscow), 2011, no. 3, p. 3.

  7. Naumova, G.V., Strigutskii, V.P., Zhmakova, N.F., et al., Vestsi Nats. Akad. Nauk Belarusi, Ser. Khim. Nav., 1999, no. 1, p. 62.

  8. Naumova, G.V., Strigutskii, V.P., Zhmakova, N.F., and Ovchinnikova, T.F., Khim. Tverd. Topl. (Moscow), 2001, no. 2, p. 3.

  9. Navosha, Yu.Yu., Abstracts of Papers, Vseros. konf. “Guminovye veshchestva v biosfere” (All-Russia Conf. “Humic Substances in the Biosphere”), St. Petersburg, 2005, p. 35.

  10. Chukov, S.N., Strukturno-funktsional’nye parametry organicheskogo veshchestva pochv v usloviyakh antropogennogo vozdeistviya (Structural and Functional Parameters of the Organic Matter of Soil under Anthropogenic Impact Conditions), St. Petersburg, 2001.

  11. Saab, S.C. and Martin-Neto, L., J. Braz. Chem. Soc, 2003, vol. 14, no. 1, p. 1.

    Google Scholar 

  12. Tr. IV Vseros. konf. “Guminovye veshchestva v biosfere” (Proc. IV All-Russia Conf. “Humic Substances in the Biosphere”), St. Petersburg, 2007, p. 668.

  13. Khimicheskii entsiklopedicheskii slovar’ (Chemical Encyclopedic Dictionary), Moscow: Sov. Entsiklopediya, 1983, p. 489.

  14. Cherepanova, E.S., Lyubchenko, L.S., Strigutskii, V.P., and Lukovnikov, A.F., Khim. Tverd. Topl. (Moscow), 1985, no. 6, p. 15.

  15. Lishtvan, I.I., Strigutskii, V.P., Bambalov, N.N., et al., Vestsi Nats. Akad. Nauk Belarusi, Ser. Khim. Nav., 1990, no. 4, p. 7.

  16. Strigutskii, V.P., Bambalov, N.N., Prokhorov, S.G., and Smirnova, V.V., Khim. Tverd. Topl. (Moscow), 1996, no. 6, p. 29.

  17. Lishtvan, I.I., Strigutskii, V.P., Tsaryuk, T.Ya., and Drebenkova, I.V., Vest. Fonda Fund. Issled., 2009, no. 3, p. 22.

  18. Lishtvan, I.I., Maiko, L.P., Strigutskii, V.P., and Tsaryuk, T.Ya., Dokl. Nats. Akad. Nauk Belarusi, 2008, vol. 52, no. 6, p. 56.

    CAS  Google Scholar 

  19. Liogon’kii, B.I., Strigutskii, V.P., Aleksanyan, R.Z., et al., Dokl. Akad. Nauk BSSR, 1981, vol. 25, no. 9, p. 825.

    Google Scholar 

  20. Dudarchik, V.M., Prokhorov, S.G., Smychnik, T.P., et al., Dokl. Nats. Akad. Nauk Belarusi, 2003, vol. 47, no. 3, p. 78.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute for Nature Management, Belarussian Academy of Sciences, ul. F. Skoriny 10, Minsk, 220114, Belarus

    I. I. Lishtvan, V. P. Strigutskii, Yu. G. Yanuta, A. M. Abramets, Yu. Yu. Navosha, N. S. Glukhova & V. N. Aleinikova

Authors
  1. I. I. Lishtvan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. P. Strigutskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. G. Yanuta
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. M. Abramets
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. Yu. Navosha
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. S. Glukhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. N. Aleinikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. S. Glukhova.

Additional information

Original Russian Text © I.I. Lishtvan, V.P. Strigutskii, Yu.G. Yanuta, A.M. Abramets, Yu.Yu. Navosha, N.S. Glukhova, V.N. Aleinikova, 2012, published in Khimiya Tverdogo Topliva, 2012, No. 3, pp. 14–19.

About this article

Cite this article

Lishtvan, I.I., Strigutskii, V.P., Yanuta, Y.G. et al. Transformation of the polyconjugation systems of humic acids in the course of the metamorphism of caustobioliths. Solid Fuel Chem. 46, 153–158 (2012). https://doi.org/10.3103/S036152191203007X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S036152191203007X

Keywords

Search

Navigation