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Structural-Group Composition and Biological Activity of Humic Acids Obtained from Brown Coals of Russia and Mongolia

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Abstract

The biological activity of humic preparations in the form of sodium and potassium humates was investigated depending on the structural group parameters of humic acids (HAs): the degree of aromaticity (fa), a hydrophilic–hydrophobic parameter (fhh), and a parameter reflecting the ratio between aromatic and aliphatic fragments in the organic matter of HAs (far/al). Native and modified HAs isolated from peat and brown coals of Russia and Mongolia, the composition of which was characterized using proximate and ultimate analysis and 13С NMR (CP MAS) spectroscopy, were used as preparations. It was established that modification by destructive alkylation and the subsequent bitumen removal changed the structural-group composition of HAs, increased the degree of aromaticity, and led to an increase in their biological activity.

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REFERENCES

  1. Orlov, D.S., Soros. Obrazovat. Zh., 1997, no. 2, p. 56.

  2. Perminova, I.V., Doctoral (Chem.) Dissertation, Moscow: Moscow State Univ., 2000.

  3. Khristeva, L.A., Guminovye udobreniya. Teoriya i praktika ikh primeneniya (Humic Fertilizers: Theory and Practice of Their Application), Dnepropetrovsk: DSKhI, 1973, no. 4, p. 5.

  4. Gorovaya, A.I. and Kulik, A.F., Guminovye udobreniya. Teoriya i praktika ikh primeneniya (Humic Fertilizers: Theory and Practice of Their Application), Dnepropetrovsk: DSKhI, 1980, no. 7, p. 74.

  5. Aleksandrova, I.V., Organicheskoe veshchestvo tselinnykh i osvoennykh pochv (Organic Matter of Virgin and Developed Soils), Moscow: Nauka, 1972, p. 30.

  6. Aleksandrova, I.V., Pochvovedenie, 1977, no. 5, p. 31.

  7. Aleksandrova, I.V., Pochvovedenie, 1983, no. 11, p. 22.

  8. Dragunov, S.S., Guminovye udobreniya. Teoriya i praktika ikh primeneniya (Humic Fertilizers: Theory and Practice of Their Application), Dnepropetrovsk: DSKhI, 1980, no. 7, p. 5.

  9. Apraksina, S.M., Dumbai, I.N., and Dulenko, V.I., Puti pererabotki uglei Ukrainy (Ways of Coal Processing in Ukraine), Kiev: Naukova Dumka, 1988, p. 98.

  10. Kukharenko, T.A., Khim. Tverd. Topl. (Moscow), 1976, no. 2, p. 24.

  11. Zherebtsov, S.I., Malyshenko, N.V., Smotrina, O.V., Lyrshchikov, S.Yu, Bryukhovetskaya, L.V., and Isma-gilov, Z.R., Khim. Interesakh Ustoich. Razvit., 2015, vol. 23, no. 4, p. 439.

    CAS  Google Scholar 

  12. Dobbs, L.B., Canellas, L.P., Olivares, F.L., Aguiar, N.O., Facanha, A.R., Peres, L.E.P., Azevedo, M., Spaccini, R., and Piccolo, A., J. Agricult. Food Chem., 2010, vol. 58, no. 6, p. 3681.

    Article  CAS  Google Scholar 

  13. Taits, E.M. and Andreeva, I.A., Metody analiza i ispytaniya uglei (Methods for the Analysis and Testing of Coals), Moscow: Nedra, 1983.

  14. Zherebtsov, S.I. and Ismagilov, Z.R., Solid Fuel Chem., 2012, vol. 46, no. 6, p. 339.

  15. Zherebtsov, S.I. and Moiseev, A.I., Solid Fuel Chem., 2009, vol. 43, no. 2, p. 71.

  16. Zherebtsov, S.I., Musin, Yu.V., and Moiseev, A.I., Khim. Rastit. Syr’ya, 2009, no. 2, p. 125.

  17. Khil’ko, S.L., Kovtun, A.I., and Rybachenko, V.I., Khim. Tverd. Topl. (Moscow), 2011, no. 5.

  18. Glebko, L.I. and Maksimov, O.B., Novye metody issledovaniya guminovykh kislot (New Methods for Studying Humic Acids), Elyakov, G.B., Ed., Vladivostok: Izd. Akad. Nauk SSSR, 1972.

    Google Scholar 

  19. Voronina, L.P., Yakimenko, O.S., and Terekhova, V.A., Agrokhimiya, 2012, no. 6, p. 50.

  20. Praktikum po rastenievodstvu (Crop Manual), Vavilov, P.P, Gritsenko, V.V, and Kuznetsov, V.S, Eds., Moscow: Kolos, 1983.

  21. GOST (State Standard) 12038-84: Crop Seeds: Methods for Determining Germination, Moscow: Izd. Standartov, 1984, p. 30.

  22. GOST (State Standard) R 54221-2010: Humic Preparations from Brown and Oxidized Coals: Test Methods, Moscow: Standartinform, 2012, p. 10.

  23. Kalabin, G.A., Kanitskaya, L.V., and Kushnarev, D.F., Kolichestvennaya spektroskopiya YaMR prirodnogo organicheskogo syr’ya i produktov ego pererabotki (Quantitative NMR Spectroscopy of Natural Organic Raw Materials and Their Conversion Products), Moscow: Khimiya, 2000.

  24. Zherebtsov, S.I., Malyshenko, N.V., Sokolov, D.A., and Ismagilov, Z.R., Vestn. Kuzbass. Gos. Tekh. Univ., 2016, no. 4, p. 108.

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Authors and Affiliations

  1. Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, 650000, Kemerovo, Russia

    S. I. Zherebtsov, N. V. Malyshenko, K. S. Votolin & Z. R. Ismagilov

  2. Institute of Soil Science and Agrochemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    V. A. Androkhanov & D. A. Sokolov

  3. Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, 13330, Ulan Bator, Mongolia

    J. Dugarjav

Authors
  1. S. I. Zherebtsov
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  2. N. V. Malyshenko
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  3. K. S. Votolin
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  4. V. A. Androkhanov
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  5. D. A. Sokolov
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  6. J. Dugarjav
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  7. Z. R. Ismagilov
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Corresponding authors

Correspondence to S. I. Zherebtsov, N. V. Malyshenko, K. S. Votolin, V. A. Androkhanov, D. A. Sokolov, J. Dugarjav or Z. R. Ismagilov.

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Translated by V. Makhlyarchuk

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Zherebtsov, S.I., Malyshenko, N.V., Votolin, K.S. et al. Structural-Group Composition and Biological Activity of Humic Acids Obtained from Brown Coals of Russia and Mongolia. Solid Fuel Chem. 53, 145–151 (2019). https://doi.org/10.3103/S0361521919030121

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  • DOI: https://doi.org/10.3103/S0361521919030121

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