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Synthesis of MSn(OH)6 (where M = Mg, Ca, Zn, Mn, or Cu) materials at room temperature

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Central European Journal of Chemistry

Abstract

Applying a metathesis approach (MCl2·xH2O+Na2SnO3·xH2O→MSn(OH)6+NaCl+xH2O), Schoenfliesite-type materials with general formula MSn(OH)6 (where M=Ca, Cu, Mg, Mn or Zn) were synthesized at room-temperature. The high lattice-energy of the by-product alkali halide NaCl drives the reaction in the forward direction leading to the formation of the desired materials. The materials synthesized were characterized by powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) to elucidate structural and micro structural features.

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Authors and Affiliations

  1. Department of Mechanical Engineering, Colorado State University, Fort Collins, CO, 80523, USA

    Jonathan W. Kramer, Brandon Kelly & Venkatesan Manivannan

Authors
  1. Jonathan W. Kramer
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  2. Brandon Kelly
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  3. Venkatesan Manivannan
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Correspondence to Venkatesan Manivannan.

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Kramer, J.W., Kelly, B. & Manivannan, V. Synthesis of MSn(OH)6 (where M = Mg, Ca, Zn, Mn, or Cu) materials at room temperature. cent.eur.j.chem. 8, 65–69 (2010). https://doi.org/10.2478/s11532-009-0094-z

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  • DOI: https://doi.org/10.2478/s11532-009-0094-z

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