Abstract
The crystal structure of the title compound, [Ni(C8H20N4)(C12H8N2)](ClO4)2, has been determined by X-ray diffraction. The Ni(II) ion is six coordinated with four nitrogen atoms of the tetradentate macrocyclic ligand and two nitrogen atoms of the bidentate ligand in a distorted octahedron geometry. The folded tetradentate macrocyclic ligand adopts a configuration having four five-membered chelate rings in distorted eclipsed conformations. The four hydrogen atoms of the amine groups of the macrocyclic ligand are on the same side towards the bidentate ligand.
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Lin, YC., Lu, TH., Liao, FL. et al. Crystal Structure of (1,10-Phenanthroline-W,N′)(1,4,7,10-tetraazacyclododecane- N,N′,N″,N‴ )nickel(II) Diperchlorate. ANAL. SCI. 19, 967–968 (2003). https://doi.org/10.2116/analsci.19.967
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DOI: https://doi.org/10.2116/analsci.19.967