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Crystal Structure of a Nickel(II) Complex with the Macrocyclic Azadibenzo-14-crown-4 Ether Ligand Containing the Embedded Di(α-pyridyl)bispidone Moiety

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Abstract

The crystal structure of the nickel(II) complex with substituted azadibenzo-14-crown-4 ether containing the embedded di(α-pyridyl)bispidone moiety having the formula [L(H2O)Ni(NO3) Ni(H2O)L](ClO4)3 · 0.7EtOH was studied by X-ray diffraction (T = 150(2) K, R = 0.0628). In the complex cation two five-coordinate nickel complexes are bridged by the nitrate anion to form a dimer. The distorted octahedral environment of Ni atoms is formed by four nitrogen atoms of the molecule L and the oxygen atoms of the water molecule and the NO -3 anion. In the nickel complex, like in the cobalt and copper complexes studied previously, the bispidine moiety of the molecule L adopts a chair-chair conformation.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    I. N. Polyakova, V. I. Sokol & V. S. Sergienko

  2. Peoples’ Friendship University of Russia, Moscow, 117198, Russia

    N. M. Kolyadina & N. A. Polyanskaya

  3. National Research Centre “Kurchatov Institute,”, Moscow, 123098, Russia

    V. B. Kvartalov

  4. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”, Russian Academy of Sciences, Moscow, 119333, Russia

    V. B. Kvartalov

Authors
  1. I. N. Polyakova
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  2. V. I. Sokol
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  3. V. S. Sergienko
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  4. N. M. Kolyadina
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  5. V. B. Kvartalov
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  6. N. A. Polyanskaya
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Corresponding author

Correspondence to V. I. Sokol.

Additional information

Original Russian Text © I.N. Polyakova, V.I. Sokol, V.S. Sergienko, N.M. Kolyadina, V.B. Kvartalov, N.A. Polyanskaya, 2018, published in Kristallografiya, 2018, Vol. 63, No. 3, pp. 409–414.

† Deceased.

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Polyakova, I.N., Sokol, V.I., Sergienko, V.S. et al. Crystal Structure of a Nickel(II) Complex with the Macrocyclic Azadibenzo-14-crown-4 Ether Ligand Containing the Embedded Di(α-pyridyl)bispidone Moiety. Crystallogr. Rep. 63, 358–363 (2018). https://doi.org/10.1134/S1063774518030203

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  • DOI: https://doi.org/10.1134/S1063774518030203

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