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Synthesis, crystal structure, and properties of an azido-bridged 1D nickel hexaazamacrocyclic complex

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Abstract

A new complex of [Ni(C15H32N6)(N3)]ClO4 · H2O was obtained by the reaction of macrocyclic precursor complex [Ni(C15H32N6)]ClO4 with sodium azide in water solution, and characterized by EA, IR, PXRD and single-crystal X-ray diffraction (CIF file CCDC no. 930570). Single X-ray diffraction analysis reveals that the central nickel(II) ion displays six-coordinate octahedral coordination geometry by coordination with four nitrogen atoms of N −3 macrocyclic ligand and two nitrogen atoms of ligand. In this complex, each μ1,3-N −3 binds two nickel(II) ions, resulting a 1D chain. Magnetic measurements have been performed on the complex, showing strong antiferromagnetic coupling interaction within the metal center.

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Authors and Affiliations

  1. Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan, 430074, P.R. China

    H. Xia, X. L. Yu & G. Yan

  2. Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281-S3, B-9000, Ghent, Belgium

    K. van Hecke

Authors
  1. H. Xia
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  2. X. L. Yu
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  3. G. Yan
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  4. K. van Hecke
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Correspondence to H. Xia.

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Xia, H., Yu, X.L., Yan, G. et al. Synthesis, crystal structure, and properties of an azido-bridged 1D nickel hexaazamacrocyclic complex. Russ J Coord Chem 40, 943–947 (2014). https://doi.org/10.1134/S1070328414120148

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  • DOI: https://doi.org/10.1134/S1070328414120148

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