Skip to main content
Log in

Evaluation of the combined deterioration by freeze–thaw and carbonation of mortar incorporating BFS, limestone powder and calcium sulfate

  • Original Article
  • Published:
Materials and Structures Aims and scope Submit manuscript

A Correction to this article was published on 08 November 2017

This article has been updated

Abstract

The durability performance of cementitious material is traditionally based on assessing the effect of a single degradation process. However, this study investigates the coupled deterioration properties of mortar incorporating industrial solid waste—ground granulated blast furnace slag (BFS) and different mineral admixtures, such as calcium sulfate (CS) and limestone powder (LSP). The combined deterioration properties caused by carbonation and frost damage in the mortar sample were experimentally investigated with respect to accelerated carbonation and freeze–thaw tests. Different degrees of deterioration, i.e. after subjected to 12, 30 and 60 freeze–thaw cycles, were induced in the freeze–thaw tests. The experimental investigation of single degradation revealed that the compressive strength, frost resistance and carbonation resistance decrease as the BFS replacement ratio increases by weight from 0 to 45%. The less amount of CH in the BFS cement leads to the carbonation progress more easily. Moreover, to achieve the same strength as ordinary Portland cement, 2 wt% CS and 4 wt% LSP in the BFS mortar are required. However, the data shows that incorporating LSP into the BFS mortar produces a lower frost resistance. The combined damage tests revealed that different deterioration degrees resulting from 12, 30 and 60 freeze–thaw cycles slightly decreased the carbonation resistance, which is related to the decrease in the inkbottle pore volume due to its water retention characteristics. Simultaneously, the pre-carbonation deterioration could effectively decrease the surface mass scaling of the freeze–thaw and the pore structure undergoes densification due to pre-carbonation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

Change history

  • 08 November 2017

    Due to an unfortunate turn of events, this article was published with an erroneous version of Fig. 9. Please find on this page the correct version of Fig. 9 that should be regarded by the reader as the final version.

References

  1. Zhao J, Cai GC, Zhao S (2014) Influences of freeze–thaw cycle and curing time on chloride ion penetration resistance of Sulphoaluminate cement concrete. Constr Build Mater 53:305–311

    Article  Google Scholar 

  2. Chung CW, Shon CS, Kim YS (2010) Chloride ion diffusivity of fly ash and silica fume concretes exposed to freeze–thaw cycles. Constr Build Mater 24:1739–1745

    Article  Google Scholar 

  3. Gerard B, Marchland J (2000) Influence of cracking on the diffusion properties of cement-based materials: part I: influence of continuous cracks on the steadystate regime. Cem Concr Res 30:37–43

    Article  Google Scholar 

  4. Özbay E, Karahan O, Lachemi M, Hossain K, Atis CD (2012) Dual effectiveness of freezing–thawing and sulfate attack on high-volume slag-incorporated ECC. Composites B 45:1384–1390

    Article  Google Scholar 

  5. Çavdar Ahmet (2014) Investigation of freeze–thaw effects on mechanical properties of fiber reinforced cement mortars. Composites B 58:463–472

    Article  Google Scholar 

  6. Neves R, Sena B, Branco F, De Brito J, Castela A, Montemor MF (2015) Assessing concrete carbonation resistance through air permeability measurements. Constr Build Mater 82:304–309

    Article  Google Scholar 

  7. Parrott LJ (1996) Some effects of cement and curing upon carbonation and reinforcement corrosion in concrete. Mater Struct 29:164–173

    Article  Google Scholar 

  8. Thomas MDA, Shehata MH, Shashiprakash SG, Hopkins DS, Cail K (1999) Use of ternary cementitious systems containing silica fume and fly ash in concrete. Cem Concr Res 29:1207–1214

    Article  Google Scholar 

  9. ACI 213R (2003) Guide for structural lightweight-aggregate concrete. American Concrete Institute, Farmington Hills, p 38

    Google Scholar 

  10. Liu W, Cui HZ, Dong ZJ, Xing F, Zhang HC, Lo Tommy Y (2016) Carbonation of concrete made with dredged marine sand and its effect chloride binding. Constr Build Mater 120:1–9

    Article  Google Scholar 

  11. Zhang P, Zhao T, Jin Z (2008) Influence of freezing and thawing on carbonation of concrete materials. Sichuan Build Sci 34:66–68 (in Chinese)

    Google Scholar 

  12. Mehta PK, Monteiro PJM (2013) Concrete: microstructure, properties, and materials, 4th edn. McGraw-Hill Education, New York City

    Google Scholar 

  13. Leemann A, Moro F (2017) Carbonation of concrete: the role of CO2 concentration, relative humidity and CO2 buffer capacity. Mater Struct. doi:10.1617/s11527-016-0917-2

  14. Cizer O, Navarro CR, Agudo ER, Elsen J, Elsen J, Gemert DV, Balen KV (2012) Phase and morphology evolution of calcium carbonate precipitated by carbonation of hydrated lime. J Mater Sci 47:6151–6165

    Article  Google Scholar 

  15. Chao J, Gu XL et al (2016) Discussion of ‘‘Assessing concrete carbonation resistance through air permeability measurements’’ by R. Neves, Construction and Building Materials 82(2015):304–309. Constr Build Mater 102:913–915

    Article  Google Scholar 

  16. Lim S, Mondal P (2015) Effects of incorporating nanosilica on carbonation of cement paste. J Mater Sci 50:3531–3540

    Article  Google Scholar 

  17. Powers TC (1945) Working hypothesis for further studies of frost resistance of concrete. Am Concr Inst J 16:245

    Google Scholar 

  18. Powers TC, Helmuth RA (1953) Theory of volume changes in hardened Portland-cement pasted during freezing. Highw Res Board 32:285–297

    Google Scholar 

  19. Kamada E (1988) Frost damage and pore structure of concrete. Proc Jpn Concr Inst 10:51–60 (in Japanese)

    Google Scholar 

  20. Shirota TK, Murakami K (2014) Application study of a small amount mixed material to the blast furnace cement A species for the purpose of improving durability and reducing environmental impact. Concr Eng Proc 2:125–134

    Google Scholar 

  21. Wachi MH, Ryo KN, TsujiMasaru JR (2011) A study on the fundamental properties of concrete using ground granulated blast furnace slag-rich cement. Takenaka Technol Res Rep 67:1–6

    Google Scholar 

  22. Sun W, Mu R, Luo X, Miao CW (2002) Effect of chloride salt, freeze–thaw cycling and externally applied load on the performance of the concrete. Cem Concr Res 32:1859–1864

    Article  Google Scholar 

  23. Zhao J, Cai GC, Gao DY (2011) Study on bonding characteristic of mixed-type chloride ion in sulphoaluminate cement. Key Eng Mater 467:698–702

    Article  Google Scholar 

  24. Sagawa T, Hama Y, Tsukamoto Y (2015) Effect of anhydrite and limestone powder on the strength development and hydration of blast-furnace slag cement type A. Cem Sci Concr Tech 68:239–245 (in Japanese)

    Article  Google Scholar 

  25. Pang B, Zhou ZH, Cheng X, Du P, Xu HX (2016) ITZ properties of concrete with carbonated steel slag aggregate in salty freeze-thaw environment. Constr Build Mater 114:162–171

    Article  Google Scholar 

  26. Zomeren AV (2011) Changes in mineralogical and leaching properties of converter steel slag resulting from accelerated carbonation at low CO2 pressure. Waste Manag 31:2236–2244

    Article  Google Scholar 

  27. Hesami S, Modarres A, Soltaninejad M, Madani H (2016) Mechanical properties of roller compacted concrete pavement containing coal waste and limestone powder as partial replacements of cement. Constr Build Mater 111:625–636

    Article  Google Scholar 

  28. Aprianti E, Shafigh P, Bahri S, Farahani JN (2015) Supplementary cementitious materials origin from agricultural wastes—a review. Constr Build Mater 74:176–187

    Article  Google Scholar 

  29. Zhang WY, Hama Y, Na SH (2015) Drying shrinkage and microstructure characteristics of mortar incorporating ground granulated blast furnace slag and shrinkage reducing admixture. Constr Build Mater 93:267–277

    Article  Google Scholar 

  30. Na SH, Hama Y, Taniguchi M, Katsura O, Sagawa T, Zakaria M (2012) Experimental investigation on reaction rate and self-healing ability in fly ash blended cement mixtures. J Adv Concr Technol 10:240–253

    Article  Google Scholar 

  31. Moura WA, Goncalves JP, Lime MBL (2007) Copper slag waste as a supplementary cementing material to concrete. J Mater Sci 42:2226–2230

    Article  Google Scholar 

  32. Park H, Jeong Y, Jun Y (2016) Strength enhancement and pore-size refinement in clinker-free CaO activated GGBFS systems through substitution with gypsum. Cem Concr Compos 68:57–65

    Article  Google Scholar 

  33. Ahmed MD, Abd E, Ayman AA (2016) Long term study of mechanical properties, durability and environmental impact of limestone cement concrete. Alex Eng J 55:1465–1482

    Article  Google Scholar 

  34. Dhir RK, Limbachiya MC, Mc Carthy MJ, Chaipanich A (2007) Evaluation of Portland limestone cements for use in concrete construction. Mater Struct 40:459–473

    Article  Google Scholar 

  35. Ramezanianpour AA, Ghiasvand E, Nickseresht I, Mahdikhani M, Moodi F (2009) Influence of various amounts of limestone powder on performance of Portland limestone cement concretes. Cem Concr Compos 31:715–720

    Article  Google Scholar 

  36. Cyr M, Lawrence P, Ringot E (2006) Efficiency of mineral admixtures in mortars: quantification of the physical and chemical effects of fine admixtures in relation with compressive strength. Cem Concr Res 36:264–277

    Article  Google Scholar 

  37. Guemmadi Z, Resheidat M, Chabil H, Toumi B (2009) Modeling the influence of limestone filler on concrete: a novel approach for strength and cost, Jordan. J Civil Eng 3:158–171

    Google Scholar 

  38. Lee ST, Hooton RD, Jung HS, Park DH, Choi CS (2008) Effect of limestone filler on the deterioration of mortars and pastes exposed to sulfate solutions at ambient temperature. Cem Concr Res 38:68–76

    Article  Google Scholar 

  39. Pipilikaki P, Katsioti M, Gallias JL (2009) Performance of limestone cement mortars in a high sulfates environment. Constr Build Mater 23:1042–1049

    Article  Google Scholar 

  40. Moon HY, Jung HS, Kim JP (2004) Diffusion of chloride ions in limestone powder concrete. J Korea Concr Inst 161:859–865

    Article  Google Scholar 

  41. ASTM C231-97. Standard test method for resistance of concrete to rapid freezing and thawing, Annual book of ASTM standards

  42. JIS A 1148 (2010) Method of test for resistance of concrete to freezing and thawing, Japan Industrial Standards Committee (in Japanese)

  43. ASTM C666-97. Standard test method for resistance of concrete to rapid freezing and thawing. Annual book of ASTM standards

  44. Nam J, Kim G, Lee B, Hasegawa R, Hama Y (2016) Frost resistance of polyvinyl alcohol fiber and polypropylene fiber reinforced cementitious composites under freeze thaw cycling. Compos B 90:241–290

    Article  Google Scholar 

  45. JIS A 1153 (2013) Method of accelerated carbonation test for concrete, Japan Industrial Standards Committee (in Japanese)

  46. Kayyali O (1985) Mercury intrusion porosimetry of concrete aggregate. Mater Struct 18:259–262

    Article  Google Scholar 

  47. Zhang WY, Zakaria M, Hama Y (2013) Influence of aggregate materials characteristics on the drying shrinkage properties of mortar and concrete. Constr Build Mater 49:500–510

    Article  Google Scholar 

  48. Karen S, Ruben S, Barbara L (2015) A practical guide to microstructural analysis of cementitious materials. Taylor and Francis Group, Boca Raton

    Google Scholar 

  49. Ngrockiene D, Skripkiunas G, Girskas G (2011) Predicting frost resistance of concrete with different coarse aggregate concentration by porosity parameters. Mater Sci 17:203–207

    Google Scholar 

  50. Zhang Y, Ye G. Effect of limestone powder on microstructure of ternary cementitious system. http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.459.3440&rep=rep1&type=pdf

  51. Harada H (1996) A study on the formation mechanism of various properties of concrete from the pore void structure. Shimizu Corp Res Rep 63:1–10

    Google Scholar 

  52. Kaufmann J, Loser R, Leemann A (2009) Analysis of cement-bonded materials by multi-cycle mercury intrusion and nitrogen sorption. J Colloid Interface Sci 336:730–737

    Article  Google Scholar 

  53. Moro F, Bohni H (2002) Ink-bottle effect in mercury intrusion porosimetry of cement-based Materials. J Colloid Interface Sci 246:135–149

    Article  Google Scholar 

  54. Tsakiroglou CD, Payatakes AC (1990) A new simulator of mercury porosimetry for the characterization of porous materials. J Colloid Interface Sci 137:315–339

    Article  Google Scholar 

  55. VocÏka R, Galle C, Dubois M, Lovera P (2000) Mercury intrusion porosimetry and hierarchical structure of cement pastes: theory and experiment. Cem Concr Res 30:521–527

    Article  Google Scholar 

  56. Yoshida S, Nawa T, Taguchi F, Hi Watanabe (2008) Influence of pore structure on carbonation of concrete with Belite-based cement and ground granulated blast-furnace slag at low water/binder ratio. Jpn Soc Civil Eng 64:1–15

    Google Scholar 

  57. Ishibashi M, Matushita H, Sagawa Y, Kawabata Y (2006) Microstructure, strength and carbonation of mortar using recycled aggregate. Proc Jpn Concr Inst 28:1487–1492

    Google Scholar 

  58. Yoshida R, Kishi T (2012) Properties of pore structure measured by step-by-step mercury intrusion porosimetry test. In: Second international conference on microstructural-related durability of cementitious composites, The Netherlands, April

Download references

Acknowledgements

The authors gratefully acknowledge the funding support from Steel Foundation for Environmental Protection Technology, Japan.

Funding

This study was funded by Steel Foundation for Environmental Protection Technology, Japan.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yukio Hama.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

A correction to this article is available online at https://doi.org/10.1617/s11527-017-1111-x.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, W., Na, S., Kim, J. et al. Evaluation of the combined deterioration by freeze–thaw and carbonation of mortar incorporating BFS, limestone powder and calcium sulfate. Mater Struct 50, 171 (2017). https://doi.org/10.1617/s11527-017-1039-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1617/s11527-017-1039-1

Keywords

Navigation