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Recent progress on inorganic composite electrolytes for all-solid-state lithium batteries

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Abstract

To address the low energy density and potential safety issues of modern lithium-ion batteries (LIBs), all-solid-state lithium batteries (ASSLBs) with solid-state electrolytes (SSEs) have emerged as a highly promising option. Among different SSEs, inorganic electrolytes (IEs) are the most probable to replace organic liquid electrolytes because of their relatively high lithium ionic conductivity and wide cell voltage window. Nevertheless, IEs encounter challenges such as elevated interfacial resistance, limited ionic conductivity at room temperature, and air instabilities. Different hybrid solid electrolytes, including organic–inorganic hybrid solid electrolytes (OIHSEs) and inorganic composite electrolytes (ICEs), have been developed to overcome these difficulties. While OIHSEs have been reviewed thoroughly, ICEs have been reviewed rarely, despite their crucial role in the advancement of ASSLBs. This review focuses on the synthesis methodologies, structures, compositions, and electrochemical performance of ICEs, providing a comprehensive overview of the present state-of-art ICEs, with constructive conclusions and perspectives for different ICEs on varied purposes. Ultimately, this review aims to shed light on potential research directions for the designing and building of practical ASSLBs with varying ICEs, thereby promoting the energy storage application of ASSLBs.

Graphical abstract

The recent advances in “Inorganic composite electrolytes for all-solid-state lithium batteries” were reviewed, with an emphasis on their compositions, synthesis techniques, electrochemical performances, and applications. Several research directions are offered to design and manufacture viable ICEs.

Highlights

  • This review provides a comprehensive overview of the present state-of-art inorganic composite electrolytes, with constructive conclusions and perspectives for different ICEs on varied purposes.

  • This review focuses on the synthesis methodologies, structures, compositions, and electrochemical performance of inorganic composite electrolytes in ASSLBs.

Discussion

The implementation of all-solid-state lithium batteries emerges as a pivotal remedy for addressing the safety concerns and energy density limitations inherent in conventional lithium-ion batteries. The decision between inorganic electrolytes and hybrid solid electrolytes, specifically the relatively unexplored inorganic composite electrolytes, necessitates thorough deliberation and underscores the importance of interdisciplinary collaboration. The utilization of theoretical computations and the development of durable and environmentally friendly energy solutions are imperative for augmenting the efficacy and security of all-solid-state batteries, while also promoting the adoption of sustainable energy technologies in diverse societies.

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Reproduced with permission from Ref. [31]. Copyright © 2019 Wiley–VCH.

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Funding

This work was supported financially by the National Key R&D Program of China (No. 2018YFE0181300), the National Natural Science Foundation of China (21905035), Liaoning Revitalization Talents Program (XLYC1907093), and the Liaoning Natural Science Foundation (20180510043).

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Authors and Affiliations

  1. College of Environmental Science and Engineering, Dalian Maritime University, Dalian, 116026, China

    Maurice Abitonze, Catherine Sekyerebea Diko, Yimin Zhu & Yan Yang

  2. SINOPEC (Dalian) Research Institute of Petroleum and Petrochemicals Co., Ltd., Dalian, China

    Yan Yang

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  1. Maurice Abitonze
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  2. Catherine Sekyerebea Diko
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  3. Yimin Zhu
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  4. Yan Yang
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MA: Conceptualization, Formal analysis, Writing—original draft; CSD: Editing; YZ: Conceptualization; YY: Conceptualization, Writing—reviewing and editing, Supervision, Funding acquisition.

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Correspondence to Yimin Zhu or Yan Yang.

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Abitonze, M., Diko, C.S., Zhu, Y. et al. Recent progress on inorganic composite electrolytes for all-solid-state lithium batteries. MRS Energy & Sustainability (2024). https://doi.org/10.1557/s43581-023-00076-w

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