Abstract
This article reviews the most recent progress in the development of Nb-silicide-based in situ composites for potential applications in turbine engines with service temperatures of up to 1350°C. These composites contain high-strength Nb silicides that are toughened by a ductile Nb solid solution. Preliminary composites were derived from binary Nb-Si alloys, while more recent systems are complex and are alloyed with Ti, Hf, W, B, Ge, Cr, and Al. Alloying schemes have been developed to achieve an excellent balance of roomtemperature toughness, fatigue-crack-growth behavior, high-temperature creep performance, and oxidation resistance over a broad range of temperatures. Nb-silicide-based composites are described with emphasis on processing, microstructure, and performance. Nb silicide composites have been produced using a range of processing routes, including induction skull melting, investment casting, hot extrusion, and powder metallurgy methods. Nb silicide composite properties are also compared with those of Ni-based superalloys.
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References
B.P. Bewlay, M.R. Jackson, and M.F.X Gigliotti, in Intermetallic Compounds—Principles and Practice, Vol. 3, edited by R.L. Fleischer and J.H. Westbrook (John Wiley & Sons, 2001) p. 541.
P.R. Subramanian, M.G. Mendiratta, D.M. Dimiduk, and M.A. Stucke, Mater. Sci. Eng., AA239–240 (1997) p. 1.
B.P. Bewlay, M.R. Jackson, and P.R. Subramanian, JOM 51 (1999) p. 32.
B.P. Bewlay, J.J. Lewandowski, and M.R. Jackson, JOM 49 (1997) p. 46.
B.P. Bewlay, M.R. Jackson, J.-C. Zhao, and P.R. Subramanian, Metall. Mater. Trans. 34A (October 2003) in press.
D.M. Berczik, United Technologies Corp., U.S. Patent No. 5,693,156 (December 2, 1997); U.S. Patent No. 5,595,616 (January 21, 1997).
B.P. Bewlay, M.R. Jackson, and H.A. Lipsitt, Metall. Trans. A 27A (1996) p. 3801.
J.H. Schneibel, M.J. Kramer, O. Unal, and R.N. Wright, Intermetallics 9 (2001) p. 25.
S.J. Balsone, B.P. Bewlay, M.R. Jackson, P.R. Subramanian, J.-C. Zhao, A. Chatterjee, and T.M. Heffernan, in Proc. of the 2001 International Symposium on Structural Intermetallics, edited by K.J. Hemker, D.M. Dimiduk, H. Clemens, R. Darolia, H. Inui, J.M. Larsen, V.K. Sikka, M. Thomas, and J.D. Whittenberger (The Minerals, Metals and Materials Society, Warrendale, PA, 2001) p. 99.
M.G. Mendiratta, J.J. Lewandowski, and D.M. Dimiduk, Metall. Trans. A 22A (1991) p. 1573.
M.G. Mendiratta and D.M. Dimiduk, Metall. Trans. A 24A (1993) p. 501.
P.R. Subramanian, M.G. Mendiratta, and D.M. Dimiduk, J. Met. 48 (1) (1996) p. 33.
J.D. Rigney and J.J. Lewandowski, Metall. Trans. A 27A (1996) p. 3292.
M.R. Jackson, B.P. Bewlay, and J.-C. Zhao, General Electric Co., U.S. Patent No. 6,419,765 (July 16, 2002).
M.R. Jackson, R.G. Rowe, and D.W. Skelly, in High-Temperature Ordered Intermetallic Alloys VI, Part 2, edited by J.A. Horton, I. Baker, S. Hanada, R.D. Noebe, and D.S. Schwartz (Mater. Res. Soc. Symp. Proc. 364, Pittsburgh, 1995) p. 1339.
J.J. Lewandowski, D. Padhi, and S. Solv’yev, in Structural Intermetallics 2001, edited by K. Hemker, D.M. Dimiduk, H. Clemens, R. Darolia, H. Inui, J.M. Larsen, V.K. Sikka, M. Thomas, and J.D. Whittenberger (The Minerals, Metals and Materials Society, Warrendale, PA, 2001) p. 371.
H. Choe, D. Chen, J.H. Schneibel, and R.O. Ritchie, Intermetallics 9 (2001) p. 319.
W.A. Zinsser and J.J. Lewandowski, Metall. Trans. A 29A (1998) p. 1749.
W.A. Zinsser, S. Solv’yev, and J.J. Lewandowski, in High-Temperature Ordered Intermetallic Alloys VIII, edited by E.P. George, M.J. Mills, and M. Yamaguchi (Mater. Res. Soc. Symp. Proc. 552, Warrendale, PA, 1999) p. KK6.10.1.
A. Samant and J.J. Lewandowski, Metall. Trans. A 28A (1997) p. 389.
A. Samant and J.J. Lewandowski, Metall. Trans. A 28A (1997) p. 2297.
D. Padhi and J.J. Lewandowski, Metall. Mater. Trans. A 34A (4) (2003) p. 967.
M.G. Mendiratta, R. Goetz, D.M. Dimiduk, and J.J. Lewandowski, Metall. Trans. A 26A (1995) p. 1767.
G.L. Erickson, JOM 47 (1995) p. 36.
C.L. Ma, Y. Tan, H. Tanaka, A. Kasama, R. Tanaka, Y. Mishima, and S. Hanada, in High-Temperature Ordered Intermetallic Alloys IX, edited by J.S. Schneibel, K.J. Hemker, R.D. Noebe, S. Hanada, and G. Sauthoff (Mater Res. Soc. Symp. Proc. 646, Warrendale, PA, 2001) p. N5.39.1.
P.R. Subramanian, T.A. Parthasarathy, M.G. Mendiratta, and D.M. Dimiduk, Scripta Metall. 32 (8) (1995) p. 1227.
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Bewlay, B.P., Jackson, M.R., Zhao, J.C. et al. Ultrahigh-Temperature Nb-Silicide-Based Composites. MRS Bulletin 28, 646–653 (2003). https://doi.org/10.1557/mrs2003.192
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DOI: https://doi.org/10.1557/mrs2003.192