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The balance of mechanical and environmental properties of a multielement niobium-niobium silicide-basedIn Situ composite

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Abstract

This article describes room-temperature and high-temperature mechanical properties, as well as oxidation behavior, of a niobium-niobium silicide basedin situ composite directionally solidified from a Nb-Ti-Hf-Cr-Al-Si alloy. Room-temperature fracture toughness, high-temperature tensile strength (up to 1200 °C), and tensile creep rupture (1100 °C) data are described. The composite shows an excellent balance of high- and low-temperature mechanical properties with promising environmental resistance at temperatures above 1000 °C. The composite microstructures and phase chemistries are also described. Samples were prepared using directional solidification in order to generate an aligned composite of a Nb-based solid solution with Nb3Si- and Nb5Si3-type silicides. The high-temperature mechanical properties and oxidation behavior are also compared with the most recent Ni-based superalloys. This composite represents an excellent basis for the development of advanced Nb-based intermetallic matrix composites that offer improved properties over Ni-based superalloys at temperatures in excess of 1000 °C.

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References

  1. R.W. Buckman, Jr.: inAlloying, J.L. Walter, M.R. Jackson, and C.T. Sims, eds., ASM INTERNATIONAL, Metals Park, OH, 1988, pp. 419–45.

    Google Scholar 

  2. M.R. Jackson, B.P. Bewlay, R.G. Rowe, D.W. Skelly, and H.A. Lipsitt:J. of Met., 1996, vol. 48 (1), pp. 39–46.

    CAS  Google Scholar 

  3. P.R. Subramanian, M.G. Mendiratta, and D.M. Dimiduk:J. Met. 1996, vol. 48 (1), pp. 33–38.

    CAS  Google Scholar 

  4. P.R. Subramanian, M.G. Mendiratta, and D.M. Dimiduk:Mater. Res. Soc. Symp. Proc., 1994, vol. 322, pp. 491–502.

    CAS  Google Scholar 

  5. D.M. Dimiduk, M.G. Mendiratta, and P.R. Subramanian: inStructural Intermetallics, R. Darolia, J.J. Lewandowski, C.T. Liu, P.L. Martin, D.B. Miracle, and M.V. Nathal eds., TMS, Warrendale, PA, 1993, pp. 619–30.

    Google Scholar 

  6. M.G. Mendiratta, J.J. Lewandowski, and D.M. Dimiduk:Metall. Trans. A, 1991, vol. 22A, pp. 1573–81.

    CAS  Google Scholar 

  7. M.G. Mendiratta and D.M. Dimiduk:Metall. Trans. A, 1993, vol. 24A, pp. 501–04.

    CAS  Google Scholar 

  8. J.D. Rigney, P.R. Singh, and J.J. Lewandowski:Mater. Res. Soc. Symp. Proc., 1994, vol. 322, pp. 502–09.

    Google Scholar 

  9. I. Weiss, M. Thirukkonda, and R. Srinivasan:Mater. Res. Soc. Symp. Proc., 1994, vol. 322, pp. 377–86.

    CAS  Google Scholar 

  10. B.P. Bewlay, H.A. Lipsitt, W.J. Reeder, M.R. Jackson, and J.A. Sutliff: inProcessing and Fabrication of Advanced Materials for High Temperature Applications III, V.A. Ravi, T.S. Srivatsan, and J.J. Moore, eds. TMS Warrendale, PA, 1993, pp. 547–65.

    Google Scholar 

  11. M.R. Jackson, R.G. Rowe, and D.W. Skelly: GE-CRD. WRDC Contract No. F33615-91-C-5613, Annual Report, 1994.

  12. M.R. Jackson and K.D. Jones: inRefractory Metals Extraction, Processing and Applications, K.C. Liddell, D.R. Sadoway, and R.G. Bautista, eds., TMS, Warrendale, PA, 1991, pp. 310–20.

    Google Scholar 

  13. K.-M. Chang, B.P. Bewlay, J.A. Sutliff, and M.R. Jackson:J. Met., 1992, vol. 44 (6), p. 59.

    CAS  Google Scholar 

  14. Standard Test Method for Plane-Strain Fracture Toughness of Metallic Materials, ASTM STP E-399, ASTM, Philadelphia, PA, 1983, July, pp. 488–512.

  15. Standard Practice for R-Curve Determination, ASTM STP E 561-94, ASTM, Philadelphia, PA, 1994.

  16. B.P. Bewlay, M.R. Jackson, W.J. Reeder, and H.A. Lipsitt.High Temperature Ordered Intermetallic Alloys VI, Materials Research Society Symposia Proceedings, Materials Research Society, Pittsburgh, PA, 1994, vol. 364, pp. 943–48.

    Google Scholar 

  17. P.R. Subramanian, M.G. Mendiratta, G.A. Henshall, and M.J. Strum:High Temperature Ordered Intermetallic Alloys VI, Materials Research Society Symposia Proceedings, Materials Research Society, Pittsburgh, PA, 1994, vol. 364, pp. 937–42.

    Google Scholar 

  18. P.R. Subramanian, T.A. Parthasarathy, M.G. Mendiratta, and D.M. Dimiduk:Scripta Metall., 1995, vol. 32 (8), pp. 1227–32.

    Article  Google Scholar 

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Bewlay, B.P., Jackson, M.R. & Lipsitt, H.A. The balance of mechanical and environmental properties of a multielement niobium-niobium silicide-basedIn Situ composite. Metall Mater Trans A 27, 3801–3808 (1996). https://doi.org/10.1007/BF02595629

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  • DOI: https://doi.org/10.1007/BF02595629

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