Abstract
Water-splitting electrolysis, using a renewable power source, has been widely considered as a promising energy conservation and storage technology that is environmentally friendly. In order to lower the required energy barrier and to improve the energy-conversion efficiency of hydrogen evolution and oxygen evolution on the electrodes, highly efficient and durable electrocatalysts are essential. To date, various preparation methods and theoretical models have been developed to accelerate the catalyst design and to further understand the associated electrocatalytic mechanism. In this issue of MRS Bulletin, all aspects of non-noble metal-based electrocatalysts for water splitting involving standard methodology, surface electronic structure engineering, morphology design, interface effects, pH operation range, activity descriptors, and operational stability are discussed. These discussions indicate the importance of materials innovations for the realization of highly efficient and durable electrocatalysts for large-scale cost-effective water splitting.
Similar content being viewed by others
References
Z.W. Seh, J. Kibsgaard, C.F. Dickens, I. Chorkendorff, J.K. Nørskov, T.F. Jaramillo, Science 355, 4998 (2017).
L. Liardet, X. Hu, ACS Catal. 8, 644 (2018).
G. Dong, M. Fang, H. Wang, S. Yip, H.Y. Cheung, F. Wang, C.Y. Wong, S.T. Chu, J.C. Ho, J. Mater. Chem. A 3, 13080 (2015).
S. Sun, H. Li, Z. J. Xu, Joule 2, 1024 (2018).
D. Voiry, M. Chhowalla, Y. Gogotsi, N.A. Kotov, Y. Li, R.M. Penner, R.E. Schaak, P.S. Weiss, ACS Nano 12, 9635 (2018).
T. Shinagawa, A.T. Garcia-Esparza, K. Takanabe, Sci. Rep. 5, 13801 (2015).
X. Zou, Y. Zhang, Chem. Soc. Rev. 44, 5148 (2015).
B. Bayatsarmadi, Y. Zheng, A. Vasileff, S.Z. Qiao, Small 13, 1700191 (2017).
Q. Li, Y. Bao, F. Bai, MRS Bull. 45 (7), 569 (2020).
Y. Shi, Y. Zhou, D.R. Yang, W.X. Xu, C. Wang, F.B. Wang, J.J. Xu, X.H. Xia, H.Y. Chen, J. Am. Chem. Soc. 139, 15479 (2017).
Y. He, Q. He, L. Wang, C. Zhu, P. Golani, A.D. Handoko, X. Yu, C. Gao, M. Ding, X. Wang, F. Liu, Q. Zeng, P. Yu, S. Guo, B.I. Yakobson, L. Wang, Z.W. Seh, Z. Zhang, M. Wu, Q.J. Wang, H. Zhang, Z. Liu, Nat. Mater. 18, 1098 (2019).
D. Yan, Y. Li, J. Huo, R. Chen, L. Dai, S. Wang, Adv. Mater. 29, 1606459 (2017).
Z. Cai, Y. Bi, E. Hu, W. Liu, N. Dwarica, Y. Tian, X. Li, Y. Kuang, Y. Li, X.Q. Yang, H. Wang, X. Sun, Adv. Energy Mater. 8, 1701694 (2018).
Q. He, Y. Wan, H. Jiang, Z. Pan, C. Wu, M. Wang, X. Wu, B. Ye, P.M. Ajayan, L. Song, ACS Energy Lett. 3, 1373 (2018).
R. Zhang, Y.-C. Zhang, L. Pan, G.-Q. Shen, N. Mahmood, Y.-H. Ma, Y. Shi, W. Jia, L. Wang, X. Zhang, W. Xu, J.-J. Zou, ACS Catal. 8, 3803 (2018).
A. Indra, M. Tallarida, D. Schmeißer, P.W. Menezes, P. Strasser, M. Driess, C. Das, A. Bergmann, N.R. Sahraie, J. Am. Chem. Soc. 136, 17530 (2014).
L. Yang, Z. Guo, J. Huang, Y. Xi, R. Gao, G. Su, W. Wang, L. Cao, B. Dong, Adv. Mater. 29, 1704574 (2017).
Y. Yu, G.H. Nam, Q. He, X.J. Wu, K. Zhang, Z. Yang, J. Chen, Q. Ma, M. Zhao, Z. Liu, F.R. Ran, X. Wang, H. Li, X. Huang, B. Li, Q. Xiong, Q. Zhang, Z. Liu, L. Gu, Y. Du, W. Huang, H. Zhang, Nat. Chem. 10, 638 (2018).
F. Cheng, Y. Su, J. Liang, Z. Tao, J. Chen, Chem. Mater. 22, 898 (2010).
C. Xie, W. Chen, S. Du, D. Yan, Y. Zhang, J. Chen, B. Liu, S. Wang, Nano Energy 71, 104653 (2020).
R. Wei, M. Fang, G. Dong, C. Lan, L. Shu, H. Zhang, X. Bu, J.C. Ho, ACS Appl. Mater. Interfaces 10, 7079 (2018).
P. Strasser, S. Koh, T. Anniyev, J. Greeley, K. More, C. Yu, Z. Liu, S. Kaya, D. Nordlund, H. Ogasawara, M.F. Toney, A. Nilsson, Nat. Chem. 2, 454 (2010).
H. Li, C. Tsai, A.L. Koh, L. Cai, A.W. Contryman, A.H. Fragapane, J. Zhao, H.S. Han, H.C. Manoharan, F. Abild-Pedersen, J.K. Nørskov, X. Zheng, Nat. Mater. 15, 48 (2016).
M. Fang, G. Dong, R. Wei, J.C. Ho, Adv. Energy Mater. 7, 1700559, 1 (2017).
X. Xu, X. Tian, Z. Zhong, L. Kang, J. Yao, J. Power Sources 424, 42 (2019).
L. Zeng, K. Zhou, L. Yang, G. Du, L. Liu, W. Zhou, ACS Appl. Energy Mater. 1, 6279 (2018).
T. Ling, D.Y. Yan, H. Wang, Y. Jiao, Z. Hu, Y. Zheng, L. Zheng, J. Mao, H. Liu, X.W. Du, M. Jaroniec, S.Z. Qiao, Nat. Commun. 8, 1509 (2017).
R. Frydendal, M. Busch, N.B. Halck, E.A. Paoli, P. Krtil, I. Chorkendorff, J. Rossmeisl, ChemCatChem 7, 149 (2015).
Q. Yang, Q. Xu, H.-L. Jiang, Chem. Soc. Rev. 46, 4774 (2017).
J.-H. Tang, Y. Sun, MRS Bull. 45 (7), 548 (2020).
F. Safizadeh, E. Ghali, G. Houlachi, Int. J. Hydrogen Energy 40, 256 (2015).
M. Huynh, D.K. Bediako, D.G. Nocera, J. Am. Chem. Soc. 136, 6002 (2014).
J.E. Bennett, Int. J. Hydrogen Energy 5, 401 (1980).
I. Katsounaros, J. C. Meier, S.O. Klemm, A.A. Topalov, P.U. Biedermann, M. Auinger, K.J.J. Mayrhofer, Electrochem. Commun. 13, 634 (2011).
L. Niu, L. Sun, L. An, D. Qu, X. Wang, Z. Sun, MRS Bull. 45 (7), 562 (2020).
W. Tong, M. Forster, F. Dionigi, S. Dresp, R. Sadeghi Erami, P. Strasser, A.J. Cowan, P. Farràs, Nat. Energy, doi:https://doi.org/10.1038/s41560-020-0550-8.
G. Janani, H. Choi, S. Surendran, U. Sim, MRS Bull. 45 (7), 539 (2020).
B. Hammer, J.K. Nørskov, Adv. Catal. 45, 71 (2000).
N. Danilovic, R. Subbaraman, D. Strmcnik, V.R. Stamenkovic, N.M. Markovic, J. Serbian, Chem. Soc. 78, 2007 (2013).
J. Hwang, R.R. Rao, L. Giordano, Y. Katayama, Y. Yu, Y. Shao-Horn, Science 358, 751 (2017).
D.H. Ha, B. Han, M. Risch, L. Giordano, K.P.C. Yao, P. Karayaylali, Y. Shao- Horn, Nano Energy 29, 37 (2016).
W. Gou, M. Zhang, J. Wu, Q. Dong, Y. Qu, MRS Bull. 45 (7), 555 (2020).
K. Macounova, M. Makarova, P. Krtil, Electrochem. Commun. 11, 1865 (2009).
X. Rong, J. Parolin, A.M. Kolpak, ACS Catal. 6, 1153 (2016).
Z.J. Zhao, S. Liu, S. Zha, D. Cheng, F. Studt, G. Henkelman, J. Gong, Nat. Rev. Mater. 4, 792 (2019).
S. Ye, F. Luo, Q. Zhang, P. Zhang, T. Xu, Q. Wang, D. He, L. Guo, Y. Zhang, C. He, X. Ouyang, M. Gu, J. Liu, X. Sun, Energy Environ. Sci. 12, 1000 (2019).
A.R. Hillman, J. Solid State Electrochem. 15, 1647 (2011).
R. Frydendal, E.A. Paoli, B.P. Knudsen, B. Wickman, P. Malacrida, I.E.L. Stephens, I. Chorkendorff, ChemElectroChem 1, 2075 (2014).
Z. Feng, W.T. Hong, D.D. Fong, Y.L. Lee, Y. Yacoby, D. Morgan, Y. Shao-Horn, Acc. Chem. Res. 49, 966 (2016).
F. Calle-Vallejo, O.A. Díaz-Morales, M.J. Kolb, M.T.M. Koper, ACS Catal. 5, 869 (2015).
M. Fang, W. Gao, G. Dong, Z. Xia, S. Yip, Y. Qin, Y. Qu, J.C. Ho, Nano Energy 27, 247 (2016).
H. Xu, J. Wan, H. Zhang, L. Fang, L. Liu, Z. Huang, J. Li, X. Gu, Y. Wang, Adv. Energy Mater. 8, 1 (2018).
W. Yuan, S. Wang, Y. Ma, Y. Qiu, Y. An, L. Cheng, ACS Energy Lett. 5, 692 (2020).
X. Lu, C. Zhao, Nat. Commun. 6, 1 (2015).
K. Zhu, T. Wu, Y. Zhu, X. Li, M. Li, R. Lu, J. Wang, X. Zhu, W. Yang, ACS Energy Lett. 2, 1654 (2017).
H.S. Han, Y.R. Hong, J. Woo, S. Mhin, K.M. Kim, J. Kwon, H. Choi, Y.C. Chung, T. Song, Adv. Energy Mater. 9, 1 (2019).
L. Yu, H. Zhou, J. Sun, F. Qin, F. Yu, J. Bao, Y. Yu, S. Chen, Z. Ren, Energy Environ. Sci. 10, 1820 (2017).
D. Senthil Raja, H.W. Lin, S.Y. Lu, Nano Energy 57, 1 (2019).
Z. Cai, X. Bu, P. Wang, W. Su, R. Wei, J.C. Ho, J. Yang, X. Wang, J. Mater. Chem. A 7, 21722 (2019).
E. Coy, MRS Bull. 45 (7), 574 (2020).
Acknowledgments
This work is financially supported by the General Research Fund (CityU 11211317) and the Theme-Based Research Scheme (T42-103/16-N) of the Research Grants Council of Hong Kong SAR, China, the National Natural Science Foundation of China (Grant 51672229), and the Science Technology and Innovation Committee of Shenzhen Municipality (Grant JCYJ20170818095520778).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bu, X., Li, Y. & Ho, J.C. Efficient and stable electrocatalysts for water splitting. MRS Bulletin 45, 531–538 (2020). https://doi.org/10.1557/mrs.2020.170
Published:
Issue Date:
DOI: https://doi.org/10.1557/mrs.2020.170