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Study of the performance of SnxSbySz/carbon nanofibers composite as anode of sodium-ion batteries

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Abstract

Sodium-ion batteries (SIBs) have emerged as a promising alternative for energy storage. In this work, it has been synthesized a nanocomposite material of SbxSbySz/Carbon nanofibers (CNFs) using low-cost synthesizing methods. First, CNFs have been obtained by electrospinning method with subsequent carbonation at 700°C. Afterward, a SbxSbySz thin coating is deposited on the CNFs by chemical bath deposition technique to obtain the SbxSbySz/CNFs. In order to obtain the SnSb2S4 crystalline phase, the composite is heated at 300°C in nitrogen atmosphere. The evaluation of this nanocomposite as the anode for SIBs has a reversible discharge capacity of 180 mAh g-1 and a columbic efficiency of 61.4% after 9 cycles. On the other hand, the resistance associated to the charge transfer to the CNFs decreases from 115.03 Ω to 77.86 Ω due to the incorporation of SnxSbySz. Finally, an easy and inexpensive route has been proposed for the synthesis of SbxSbySz/CNFs composite with great potential to be used as anode material for SIBs.

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References

  1. P.K. Nayak, L. Yang, W. Brehm, and P. Adelhelm, Chem. Int. Ed. 57, 102–120 (2018).

    Article  CAS  Google Scholar 

  2. J.Y. Hwang, S.T. Myung, and Y.K. Sun, Chem. Soc. Rev. 46, 3529–3614 (2017).

    Article  CAS  Google Scholar 

  3. M.S. Balogun, Y.L. Qiu, P. Liu, and Y. Tong, Carbon 98, 162–178 (2016).

    Article  CAS  Google Scholar 

  4. Y. You, and A. Manthiram, Adv. Energy. Mater. Int. 8, 1–12 (2018).

    Google Scholar 

  5. J. Deng, W.B. Luo, S.L. Chou, H.K. Liu, and S.X. Dou, Adv. Energy. Mater. 8, 1–17 (2018).

    Google Scholar 

  6. T. Jin, Q. Han, Y. Wang, and L. Jiao, Small 14, 1–26 (2018).

    Google Scholar 

  7. H. Hou, X. Qui, W. Wei, Y. Zhang, and X. Ji, Adv. Energy. Mater. 7, 1–30 (2017).

    Google Scholar 

  8. M. Lao, Y. Zhang, W. Luo, Q. Yan W. Sun, And S.X. Dou, Adv. Mater. 29, 1–23 (2017).

    Article  Google Scholar 

  9. Y. Zhang, Q. Zhou, J. Zhu, Q. Yan, S.X Dou, and W. Sun, Funct. Mater. 27, 1–34 (2017).

    Google Scholar 

  10. Y. Liang, W.H. Lai, Z. Miao, and S.L. Chou, Nano Energy 14, 1–20 (2018).

    Google Scholar 

  11. J.M. Jung, C.L. Lee, S. Yu, and I.D. Kim, Nano Lett. 4, 703–750 (2016).

    CAS  Google Scholar 

  12. C. Chen, G. Li, J. Zhu, Y. Lu, M. Jiang, Y. Hu, Z. Shen, and X. Zhang, Carbon 120, 380–391 (2017).

    Article  CAS  Google Scholar 

  13. P.K. Nair, A.R. García-Angelmo, and M.T.S. Nair, Phys. Status. Solidi A. 213, 170–177 (2016).

    Article  CAS  Google Scholar 

  14. L.A. Rodríguez-Guadarrama, I.L. Alonso-Lemus, J. Campos-Álvarez, And J. Escorcia-García, MRS. Adv. 4, 2035–2042 (2019).

    Article  Google Scholar 

  15. U. Chalapachi, B. Poornaprakash, and S.H. Park, J. Sol. Energy. 139, 238–248 (2016).

    Article  Google Scholar 

  16. H. Dittrich, A. Stadler, D. Topa, H.J. Schimper, and A. Basch, Phys. Status Solidi A 206, 1034–1041 (2009).

    Article  CAS  Google Scholar 

  17. D. Abdelkader, F.C. Akkari, N. Khemiri, R. Miloua, F. Antoni, B. Gallas, and M. Kanzari, Physica B: Condensed Matter. 546, 33–43 (2018).

    Article  CAS  Google Scholar 

  18. U. Chalapachi, B. Poornaprakash, C.H. Ahn, and S.H. Park, Mater. Sci. Semicond. Process. 84, 138–143 (2018).

    Article  Google Scholar 

  19. W. Leang, and B. Pan, Forest 10, 1–12 (2019).

    Google Scholar 

  20. M. Keskinates, B. Yilmaz, Y. Ulusu, and M. Bayrakci, Mater. Chem. Phys. 205, 522–529 (2018).

    Article  CAS  Google Scholar 

  21. D.A. Gopakumar, A.R. Pai, Y.B. Pottathara, D. Pasquini, L.C. Morais, M. Luke, N. Kalarikkal, Y. Grohens, and S. Thomas, Appl. Mater. Interfaces. 23, 20032–20043 (2018).

    Article  Google Scholar 

  22. V.R. Minna Reddy, S. Gedi, C. Park, and R.W. Miles, Curr. Appl. Phys. 15, 588–598 (2015).

    Article  Google Scholar 

  23. S. Aksaya, T. Özer, and M. Zor, Eur. Phys. J. Appl. Phys. 47, p1-p3 (2009).

  24. M. Muneeb, B. Ismail, T. Fazal, R.A. Khan, A.M. Khan, A. Bilal, B. Muhammad, and A.R. Khan, Arab. J. Chem. 4, 1117–1125 (2018).

    Article  Google Scholar 

  25. J. Xia, K. Jiang, J. Xie, S. Gou, L. Liu, Y. Zhang, S. Nie, Y. Yuan, H. Yan, and X. Wang, Chem. Eng. J. 359, 1244–1251 (2019).

    Article  CAS  Google Scholar 

  26. H. Zhai, H. Jiang, Y. Qian, X. Cai, H. Liu, Y. Qiu, M. Jin, F. Xiu, X. Liu, and L. Lai, Mater. Chem. Phys. 240, 1–8 (2020).

    Article  Google Scholar 

  27. Y. Wu, P. Nie, L. Wu, H. Dou, and X. Zhang, Chem. Eng. J. 334, 932–938 (2018).

    Article  CAS  Google Scholar 

  28. C.J. Diliegros-Godines, J. Santos-Cruz, N.R. Mathews, And M. Pal, J. Mater. Sci. 53, 11562–11573 (2018).

    Article  CAS  Google Scholar 

  29. C. Zou, L. Zhang, X. Hu, Z. Wang, T. Wik, And M. Peacht, J. Power Sources 30, 286–296 (2018).

    Article  Google Scholar 

  30. M. Kakunuri, S. Kaushik, A. Saini, and C.S. Sharma, Bull. Mater. Sci. 3, 435–439 (2017).

    Article  Google Scholar 

  31. X. Yan, Z. Tai, J. Chen, And Q. Xue, Nanoscale 3, 212–216 (2011).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Sustentabilidad de los Recursos Naturales y Energía, CINVESTAV, Unidad Saltillo, Av. Industria Metalúrgica 1062, Parque Industrial, Ramos Arizpe, 25900, Coahuila, Mexico

    L. A. Rodríguez-Guadarrama

  2. Parque Industrial, CONACYT-CINVESTAV, Unidad Saltillo, Av. Industria Metalúrgica 1062, Ramos Arizpe, 25900, Coahuila, México

    J. Escorcia-García

  3. Institute of Physics, Benemérita Universidad Autónoma de Puebla, San Claudio and 184 Sur 72574, Puebla, Mexico

    E. Quiroga-González

  4. Sustentabilidad de los Recursos Naturales y Energía, CONACYT-CINVESTAV, Unidad Saltillo, Av. Industria Metalúrgica 1062, Ramos Arizpe, 25900, Coahuila, México

    I. L. Alonso-Lemus

Authors
  1. L. A. Rodríguez-Guadarrama
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  2. J. Escorcia-García
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  3. E. Quiroga-González
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  4. I. L. Alonso-Lemus
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Correspondence to I. L. Alonso-Lemus.

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Rodríguez-Guadarrama, L.A., Escorcia-García, J., Quiroga-González, E. et al. Study of the performance of SnxSbySz/carbon nanofibers composite as anode of sodium-ion batteries. MRS Advances 5, 2917–2927 (2020). https://doi.org/10.1557/adv.2020.371

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