Abstract
Thin titanium films of 200 nm thickness were prepared by physical vapor deposition over conducting glass plates and anodized to form titanium oxide nanostructured film that demonstrates photoactivity under ultraviolet visible (UV-vis) illumination. Absorbance and photoelectrochemical measurements indicate that the anodized and nitrogen annealed films absorb UV-vis (λ = 300 to 800 nm) illumination to produce a current of 2.5 mA at 0 V and 3 mA at +0.4 V versus Ag/AgCl. A photocurrent of 110 µA and an open-circuit photovoltage (VOC) of 300 mV was noted without application of external bias. Long-term stability tests showed that the photocurrent was stable for 2 h under continuous illumination. The titanium oxide prepared from a small fraction of titanium deposited over conducting glass demonstrates almost similar activity compared with titanium oxides prepared on foils. The material offers promising potential in other applications such as environmental remediation and photocatalytic water splitting.
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K. Rajeshwar, de N.R. Tacconi, C.R. Chenthamarakshan Semiconductor-based composite materials: Preparation, properties, and performance. Chem. Mater. 13, 2765 (2001)
K. Kalyanasundaram, M. Gratzel Photovoltaic performance of injection solar cells and other applications of nanocrystalline oxide layers. Proc. Indian Acad. Sci.-Chem. Sci. 109, 447 (1997)
K.S. Raja, V.K. Mahajan, M. Misra Determination of photo conversion efficiency of nanotubular titanium oxide photo-electrochemical cell for solar hydrogen generation. J. Power Sources 159, 1258 (2006)
J.M. Macak, M. Zlamal, J. Krysa, P. Schmuki Self-organized TiO2 nanotube layers as highly efficient photocatalysts. Small 3, 300 (2007)
A. Kongkanand, K. Tvrdy, K. Takechi, M. Kuno, P.V. Kamat Quantum dot solar cells. Tuning photoresponse through size and shape control of CDSE-TiO2 architecture. J. Am. Chem. Soc. 130, 4007 (2008)
W. Chanmanee, A. Watcharenwong, C.R. Chenthamarakshan, P. Kajitvichyanukul, de N.R. Tacconi, K. Rajeshwar Formation and characterization of self-organized TiO2 nanotube arrays by pulse anodization. J. Am. Chem. Soc. 130, 965 (2008)
K.S. Raja, M. Misra, V.K. Mahajan, T. Gandhi, P. Pillai, S.K. Mohapatra Photo-electrochemical hydrogen generation using band-gap modified nanotubular titanium oxide in solar light. J. Power Sources 161, 1450 (2006)
M. Gomez, E. Magnusson, E. Olsson, A. Hagfeldt, S.E. Lindquist, C.G. Granqvist Nanocrystalline Ti-oxide-based solar cells made by sputter deposition and dye sensitization: Efficiency versus film thickness. Sol. Energy Mater. Sol. Cells 62, 259 (2000)
G.K. Mor, O.K. Varghese, M. Paulose, K. Shankar, C.A. Grimes A review on highly ordered, vertically oriented TiO2 nanotube arrays: Fabrication, material properties, and solar energy applications. Sol. Energy Mater. Sol. Cells 90, 2011 (2006)
J.M. Macak, H. Tsuchiya, P. Schmuki High-aspect-ratio TiO2 nanotubes by anodization of titanium. Angew. Chem. Int. Ed. 44, 2100 (2005)
Z. Liu, X. Zhang, S. Nishimoto, M. Jin, D. Tryk, T. Murakami, A. Fujishima Highly ordered TiO2 nanotube arrays with controllable length for photoelectrocatalytic degradation of phenol. J. Phys. Chem. C 112, 253 (2008)
R. Beranek, H. Tsuchiya, T. Sugishima, J. Macak M., L. Taveira, S. Fujimoto, H. Kisch, P. Schmuki Enhancement and limits of the photoelectrochemical response from anodic TiO2 nanotubes. Appl. Phys. Lett. 87, 243114 1 (2005)
S.Z. Chu, K. Wada, S. Inoue, S. Todoroki Fabrication and characteristics of nanostructures on glass by a1 anodization and electrodeposition. Electrochim. Acta 48, 3147 (2003)
P.M. Martin, B.F. Monzyk, E.C. Burckle, J.R. Busch, R.J. Gilbert, K.A. Dasse Progress towards development of a photolytic artificial lung. Mater. Sci. Eng., B 119, 246 (2005)
G.K. Mor, O.K. Varghese, M. Paulose, C.A. Grimes Transparent highly ordered TiO2 nanotube arrays via anodization of titanium thin films. Adv. Funct. Mater. 15, 1291 (2005)
D.J. Yang, H.G. Kim, S.J. Cho, W.Y. Choi Thickness-conversion ratio from titanium to TiO2 nanotube fabricated by anodization method. Mater. Lett. 62, 775 (2008)
V. Subramanian, E.E. Wolf, P.V. Kamat Semiconductor-metal composite nanostructures. To what extent do metal nanoparticles improve the photocatalytic activity of TiO2 films? J. Phys. Chem. B 105, 11439 (2001)
V. Subramanian, P.V. Kamat, E.E. Wolf Mass-transfer and kinetic studies during the photocatalytic degradation of an azo dye on optically transparent electrode thin film. Ind. Eng. Chem. Res. 42, 2131 (2003)
Y. Sohn, Y. Smith, M. Misra, V. Subramanian Electrochemically assisted photocatalytic degradation of methyl orange using anodized titanium dioxide nanotubes. Appl. Catal., B 84, 372 (2008)
P. Xiao, B.B. Garcia, Q. Guo, D.W. Liu, G.Z. Cao TiO2 nanotube arrays fabricated by anodization in different electrolytes for biosensing. Electrochem. Commun. 9, 2441 (2007)
K.S. Raja, T. Gandhi, M. Misra Effect of water content of ethylene glycol as electrolyte for synthesis of ordered titania nanotubes. Electrochem. Commun. 9, 1069 (2007)
I. Robel, V. Subramanian, M.K. Kuno, P.V. Kamat Quantum dot solar cells. Harvesting light energy with CDSE nanocrystals molecularly linked to mesoscopic TiO2 films. J. Am. Chem. Soc. 128, 2385 (2006)
G. Zhang, H. Huang, Y. Zhang, H.L.W. Chan, L. Zhou Highly ordered nanoporous TiO2 and its photocatalytic properties. Electrochem. Commun. 9, 2854 (2007)
V. Subramanian Nanostructured semiconductor composites for solar cells. Interface 16, 32 (2007)
A. Kar, Y. Smith, V. Subramanian Improved photocatalytic degradation of textile dye using titanium dioxide nanotubes formed over titanium wires. Environ. Sci. Technol. 43, 3260 (2009)
S.K. Mohapatra, M. Misra, V.K. Mahajan, K.S. Raja A novel method for the synthesis of titania nanotubes using sonoelectrochemical method and its application for photoelectrochemical splitting of water. J. Catal. 246, 362 (2007)
L.C. Lei, Y.L. Su, M.H. Zhou, X.W. Zhang, X.Q. Chen Fabrication of multi-non-metal-doped TiO2 nanotubes by anodization in mixed acid electrolyte. Mater. Res. Bull. 42, 2230 (2007)
K. Vinodgopal, I. Bedja, P.V. Kamat Nanostructured semiconductor films for photocatalysis. Photoelectrochemical behavior of SnO2/TiO2 composite systems and its role in photocatalytic degradation of a textile azo dye. Chem. Mater. 8, 2180 (1996)
T. Bak, J. Nowotny, M. Rekas, C.C. Sorrell Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects. Int. J. Hydrogen Energy 27, 991 (2002)
G.K. Mor, K. Shankar, M. Paulose, O.K. Varghese, C.A. Grimes Enhanced photocleavage of water using titania nanotube arrays. Nano Lett. 5, 191 (2005)
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Kar, A., Pando, R. & Vaidyanathan, S.(. Photoelectrochemical responses of anodized titanium oxide films. Journal of Materials Research 25, 82–88 (2010). https://doi.org/10.1557/JMR.2010.0023
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DOI: https://doi.org/10.1557/JMR.2010.0023