Abstract
The phase stability of Ni–Al clusters of nanometer size was studied by using the embedded atom model and Monte Carlo simulation techniques. For temperatures of 500 and 1000 K and for a range of compositions below 70 at.% Al, the equilibrium structures of the system were determined and compared with the bulk results. We found that the bulk NiAl (B2) and Ni3Al (L12) phases were stable phases in the nanoparticle system; however, for deviations from ideal composition, the analysis revealed that, because of the surface effect, the composition of the clusters was not uniform. There was a core region in which the structure was ordered, B2 or L12, with a composition very close to the ideal, and a chemically disordered mantle region that allocated the deviations from ideal stoichiometries; in this way, a larger phase field appeared, indicating trends similar to those found in experiments on nanocrystalline Ni–Al powder [S.K. Pabi and B.S. Murty, Mater. Sci. Eng. A214, 146 (1996)]. For concentrations between 37 and 51 at.% Al, an intermediate phase, similar to the tetragonal L10 martensite, appeared.
Similar content being viewed by others
References
P.S. Khadkikar, I.E. Locci, K. Vedula, and G.M. Michal, Metall. Transact. 24A, 83 (1993).
I.M. Robertson and C.M. Wayman, Phil. Mag. A 48, 6299 (1983).
R.W. Siegel, Physics Today. Oct. 64 (1993).
R.W. Siegel, Sci. Am., Dec. (1996).
R.W. Siegel, Rev. Mater. Sci. 21, 559 (1991).
H. Gleiter, Prog. Mater. Sci. 33, 223 (1989).
H. Gleiter, Nanostruct. Mater. 1, 1 (1992).
R.A. Andrievski, J. Mater. Sci. 29, 614 (1994).
K.W. Liu, J.S. Zhang, J.G. Wang, and G.L. Chen, J. Mater. Res. 13, 1198 (1998).
K. Aoki, X.M. Wang, A. Menezawa, and T. Masumoto, Mater. Sci. Eng. A179, 390 (1994).
S.K. Pabi and B.S. Murty, Mater. Sci. Eng., A214, 146 (1996).
C. Koch and Y.S. Cho. Nanostruct. Mater. 1, 207 (1992).
G.F. Zhou, M.J. Zwanenburg, and H. Bakker. J. Appl. Phys. 78, 3438 (1995).
M.S. Daw and M.I. Baskes, Phys. Rev. B 29, 6443 (1984).
S.M. Foiles and M.S. Daw, J. Mater. Res. 2, 5 (1987).
A.F. Voter and S.P. Chen, Mater. Res. Soc. Symp. Proc. 82, 175 (1987).
Y. Mishin and D. Farkas. Phil. Mag. A 73, 169 (1997).
D. Farkas, B. Mutasa, C. Vailhe, and K. Ternes, Model. Simulation Mater. Sci. Eng. 3, 201 (1995).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
de Debiaggi, S.R., Campillo, J.M. & Caro, A. Phase stability of Ni–Al nanoparticles. Journal of Materials Research 14, 2849–2854 (1999). https://doi.org/10.1557/JMR.1999.0380
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1999.0380