Abstract
Yttria-stabilized cubic zirconia powders and coatings produced by the sol-gel method have been investigated by Perturbed Angular Correlation Spectroscopy (PAC). Results indicate that the metastable cubic phase is retained during heating and cooling cycles. The hyperfine interaction that describes this cubic phase, once crystallized, exhibits two components in a constant ratio of 4 : 1. The components represent different vacancy configurations. For the fast movement of oxygen vacancies starting at 750 °C, which is reflected by the damping of the hyperfine pattern, an activation energy of 0.96 eV was determined.
Similar content being viewed by others
References
M. Rühle, N. Claussen, and H. Heuer, in Advances in Ceramics, Vol. 12, edited by N. Claussen, M. Rühl, and H. Heuer (The American Ceramic Society, Westerville, OH, 1984), p. 352.
K. Tsukuma, K. Ueda, K. Matsushita, and M. Shimada, J. Am. Ceram. Soc. 68 (2), C-56 (1985).
S. Stecura, Am. Ceram. Soc. Bull. 56 (12), 1082 (1977).
R. J. Bratton and S. K. Lau, in Advances in Ceramics, Vol. 3, edited by H. Heuer and L. W. Hobbs (The American Ceramic Society, Westerville, OH, 1981), p. 226.
E. M. Logothetis, in Advances in Ceramics, Vol. 3, edited by H. Heuer and L. W. Hobbs (The American Ceramic Society, Westerville, OH, 1981), p. 388.
H. Isaacs, in Advances in Ceramics, Vol. 3, edited by H. Heuer and L. W. Hobbs (The American Ceramic Society, Westerville, OH, 1981), p. 406.
Section V, in Advances in Ceramics, Vol. 12, edited by N. Claussen, M. Rühl, and H. Heuer (The American Ceramic Society, Westerville, OH, 1984), pp. 555–690.
B. E. Yoldas, J. Am. Ceram. Soc. 65 (8), 337 (1982).
P. C. Rivas, J. A. Martinéz, M. C. Caracoche, A. R. López García, L. C. Klein, and R. S. Pavlik, Jr., J. Am. Ceram. Soc. 78 (5), 1329 (1995).
R. Caruso, N. Pellegri, O. de Sanctis, M. C. Caracoche, and P. C. Rivas, in Metal-Organic Chemical Vapor Deposition of Electronic Ceramics, edited by S. B. Desu, D. B. Beach, B. W. Wessels, and S. Gokoglu (Mater. Res. Soc. Symp. Proc. 335, Pittsburgh, PA, 1994).
M. Forker, private communication.
H. Jaeger, J. A. Gardner, J. C. Haygarth, and R. L. Rasera, J. Am. Ceram. Soc. 69 (6), 458 (1986).
M. C. Caracoche, M. T. Dova, A. R. Lopez García, J. A. Martínez, and P. C. Rivas, Hyp. Int. 39, 117 (1988).
P. C. Rivas, M. C. Caracoche, A. F. Pasquevich, J. A. Martínez, A. M. Rodríguez, A. R. López-García, and S. R. Mintzer, J. Am. Ceram. Soc. 79 (4), 831 (1996).
A. Baudry, P. Boyer, and A. L. de Oliveira, Hyp. Int. 10, 1003 (1981).
H. Jaeger, Ph.D. Thesis, Oregon State University (1987).
R. Caruso, N. Pellegri, O. de Sanctis, M. C. Caracoche, and P. C. Rivas, J. Sol-Gel Sci. Technol. 3, 241 (1994).
A. J. Marshall and C. F. Mears, J. Chem. Phys. 56 (3), 1226 (1972).
J. A. Gardner, H. Jaeger, H. T. Su, W. H. Warnes, and J. C. Haygarth, Physica B 150, 223 (1988).
Joint Committee on Powder Diffraction Standards, Powder Diffraction File, Card No. 30-1468, edited by R. Jenkins, R. Anderson, and G. J. McCarthy (International Center for Diffraction Data, Swarthmore, PA, 1992).
Ph. Colomban and E. Bruneton, J. Non-Cryst. Solids 147&148, 201 (1992).
C. R. A. Cattlow, A. V. Chadwick, G. N. Greaves, and L. M. Moroney, J. Am. Ceram. Soc. 69 (3), 272 (1986).
P. Li, I-Wei, and J. E. Penner-Han, Phys. Rev. B 48, 10 063 (1993).
C. J. Howard, R. J. Hill, and B. E. Reichert, Acta Crystallogr. B44, 116 (1988).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rivas, P.C., Caracoche, M.C., Martínez, J.A. et al. Phase structure and thermal evolution in coatings and powders obtained by the sol-gel process: Part I. ZrO2−11.3 mol% Y2O3 . Journal of Materials Research 12, 493–500 (1997). https://doi.org/10.1557/JMR.1997.0071
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1997.0071