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Modulated structure in Bi2+xSr2−xCu1+yO6+δ

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Abstract

The modulated structure in solid solution Bi2+xSr2−xCu1+yO6+δ (0.1 < x < 0.6, y ∼ x/4) has been investigated by means of powder x-ray diffraction, electron diffraction, and transmission electron microscopy. The [010] component of the modulation vector decreases almost linearly with increasing x, from 5.2b (x = 0.1) to 4.2b (x = 0.5), where b is the unit length of the average structure along the [010] direction, and is little sensitive to excess oxygen content δ. A structure model of the modulation based on a periodic substitution of Sr for Bi and formation of Bi blocks whose size varies with x is proposed. Relations among various modulations appearing in other related phases such as the Pb-substituted 105 K Tc phase are discussed.

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Authors and Affiliations

  1. Institute for Chemical Research, Kyoto University, Uji, Kyoto, 611, Japan

    Zenji Hiroi, Yasunori Ikeda, Mikio Takano & Yoshichika Bando

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  1. Zenji Hiroi
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  2. Yasunori Ikeda
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  3. Mikio Takano
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  4. Yoshichika Bando
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Hiroi, Z., Ikeda, Y., Takano, M. et al. Modulated structure in Bi2+xSr2−xCu1+yO6+δ. Journal of Materials Research 6, 435–445 (1991). https://doi.org/10.1557/JMR.1991.0435

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  • DOI: https://doi.org/10.1557/JMR.1991.0435

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