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Determination of BTEX in Water Samples with an SPME Hollow Fiber Coated Copper Wire

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Abstract

A piece of copper wire coated with a polypropylene hollow fiber membrane was used as an SPME fiber and its efficiency for extraction of BTEX compounds from the headspace of water samples prior to GC analysis was evaluated. Under optimum extraction conditions, limits of detection for benzene, toluene, ethylbenzene, m-p-xylene, and o-xylene were found to be 0.11, 0.22, 0.26, 0.37, and 0.26 μg L−1, respectively. Low detection limits, wide linear dynamic ranges, good reproducibility (RSD% <4), high fiber capacity and higher mechanical durability are some of the most important advantages of the new fiber.

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References

  1. http://www.epa.org

  2. Hinwood AL, Rodriguez C, Runnion T, Farrar D, Murray F, Horton A et al (2007) Chemosphere 66:533–541. doi:10.1016/j.chemosphere.2006.05.040

    Article  CAS  Google Scholar 

  3. Chen CS, Hseu YC, Liang SH, Kuo J, Chen SC (2007) J Hazard Mater 153:309–319

    Google Scholar 

  4. http://www.atsdr.cdc.gov/toxprofiles

  5. Serrano A, Gallego M (2004) J Chromatogr A 1045:181–188. doi:10.1016/j.chroma.2004.06.028

    Article  CAS  Google Scholar 

  6. Panavaite D, Padarauskas A, Vickackaite V (2006) Anal Chim Acta 571:45–50. doi:10.1016/j.aca.2006.04.035

    Article  CAS  Google Scholar 

  7. Mehdinia A, Mousavi MF, Shamsipur M (2006) J Chromatogr A 1134:24–31. doi:10.1016/j.chroma.2006.08.087

    Article  CAS  Google Scholar 

  8. Ji J, Deng C, Shen W, Zhang X (2006) Talanta 69:894–899. doi:10.1016/j.talanta.2005.11.032

    Article  CAS  Google Scholar 

  9. Pavon JLP, Sanchez MN, Laespada MEF, Cordero BM (2007) J Chromatogr A 1175:106–111. doi:10.1016/j.chroma.2007.10.044

    Article  Google Scholar 

  10. Kubinec R, Berezkin VG, Gorova R, Addova G, Mracnova H, Sojak L (2004) J Chromatogr B Analyt Technol Biomed Life Sci 800:295–301. doi:10.1016/j.jchromb.2003.09.009

    Article  CAS  Google Scholar 

  11. Shutao W, Yan W, Hong Y, Jie Y (2006) Chromatographia 63:365–371. doi:10.1365/s10337-006-0750-9

    Article  Google Scholar 

  12. Farajzadeh MA, Mardani A (2001) Anal Sci 17:1059–1062. doi:10.2116/analsci.17.1059

    Article  CAS  Google Scholar 

  13. Esteve-Turrillas FA, Armenta S, Garrigues S, Pastor A, De la Guardia M (2007) Anal Chim Acta 587:89–96. doi:10.1016/j.aca.2007.01.036

    Article  CAS  Google Scholar 

  14. Mirmohseni A, Abdollahi H, Rostamizadeh K (2007) Sens Actuators B Chem 121:365–371. doi:10.1016/j.snb.2006.03.054

    Article  Google Scholar 

  15. Lanyon YH, Marrazza G, Tothill IE, Mascini M (2005) Biosens Bioelectron 20:2089–2096. doi:10.1016/j.bios.2004.08.034

    Article  CAS  Google Scholar 

  16. Tizzard AC, Bergsma JH, Lloyd-Jones G (2006) Biosens Bioelectron 22:759–763. doi:10.1016/j.bios.2006.01.011

    Article  CAS  Google Scholar 

  17. Arthur CL, Pawliszyn J (1990) Anal Chem 62:2145–2148. doi:10.1021/ac00218a019

    Article  CAS  Google Scholar 

  18. Arthur CL, Killam LM, Buchholz KD, Pawliszyn J (1992) Anal Chem 64:1960–1966. doi:10.1021/ac00041a034

    Article  CAS  Google Scholar 

  19. Liebich HM, Gesele E (1999) J Chromatogr A 843:237–245. doi:10.1016/S0021-9673(99)00416-1

    Article  CAS  Google Scholar 

  20. Kim H, Nochetto C, McConnell L (2002) Anal Chem 74:1054–1060. doi:10.1021/ac010960j

    Article  CAS  Google Scholar 

  21. Chong SL, Wang D, Hayes JD, Wilhite BW, Malik A (1997) Anal Chem 69:3889–3898. doi:10.1021/ac9703360

    Article  CAS  Google Scholar 

  22. Djozan D, Assadi Y (1999) Microchem J 63:276–284. doi:10.1006/mchj.1999.1791

    Article  CAS  Google Scholar 

  23. Djozan D, Assadi Y, Haddadi SH (2001) Anal Chem 73:4054–4058. doi:10.1021/ac0100188

    Article  CAS  Google Scholar 

  24. Farajzadeh MA, Matin AA (2002) Anal Sci 18:77–81. doi:10.2116/analsci.18.77

    Article  CAS  Google Scholar 

  25. Farajzadeh MA, Hatami M (2002) Anal Sci 18:1221–1226. doi:10.2116/analsci.18.1221

    Article  CAS  Google Scholar 

  26. Farajzadeh MA, Hatami M (2004) Chromatographia 59:259–262

    CAS  Google Scholar 

  27. Farajzadeh MA, Hatami M (2003) J Sep Sci 26:802–808. doi:10.1002/jssc.200301297

    Article  CAS  Google Scholar 

  28. Farajzadeh MA, Rahmani NA (2005) Talanta 65:700–704. doi:10.1016/j.talanta.2004.07.039

    Article  CAS  Google Scholar 

  29. Matin AA, Maleki R, Farajzadeh MA, Farhadi K, Hosseinzadeh R, Jouyban A (2007) Chromatographia 66:383–387. doi:10.1365/s10337-007-0348-x

    Article  CAS  Google Scholar 

  30. Zuba D, Parczewski A, Rozanska M (2001) Paper no 46 presented at the 39th Annual TIAFT meeting, Prague, Czech Republic

  31. Pawliszyn J (1997) Solid phase microextraction: Theory and practice. Wiley-VCH, Weinheim, New York

    Google Scholar 

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Correspondence to Mir Ali Farajzadeh.

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Farajzadeh, M.A., Matin, A.A. Determination of BTEX in Water Samples with an SPME Hollow Fiber Coated Copper Wire. Chroma 68, 443–446 (2008). https://doi.org/10.1365/s10337-008-0726-z

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  • DOI: https://doi.org/10.1365/s10337-008-0726-z

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