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Application of Amine and Phosphotungstic Acid Groups as a Novel Bifunctional Fiber Coating in SPME-HPLC of Volatile Phenols in Water

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Abstract

The utilization of a bifunctional amine and H3PW12O40 (PW12) as a direct solid-phase microextraction (D-SPME) coating was investigated for the first time. The fiber was synthesized using positively charged 3-aminopropyltriethoxysilane as the crosslinking agent, and provided sites for the immobilization of PW12. Fourier transform infrared spectroscopy and field emission scanning electron microscopy were used to characterize the synthetic compound. This new fiber was developed to determine some chlorophenols [4-chlorophenol (4-CPh), 2,3-dichlorophenol (2,3-DCPh), and 2,4,6-trichlorophenol (2,4,6-TCPh)] via SPME-HPLC. Using the experimental design method, the adsorption and desorption factors of the fiber—including ionic strength and adsorption and desorption times—for the three chlorophenols were systematically investigated by SPME-HPLC-UV. In the concentration range 50–5000 µg L−1, the calibration curves were linear for the analytes and the limits of detection varied from 0.3 to 2.5 µg L−1. The single-fiber repeatability and fiber-to-fiber reproducibility were in the ranges 4.8–6.4 and 10.2–12.1%, respectively. The application of the fiber to environmental water samples spiked at 70 µg L−1 with the chlorophenols yielded recoveries in the range 88.80–92.88%. Advantages of this novel bifunctional-coated SPME fiber include its increased extraction efficiency for chlorophenols and its long lifetime (it was used for >70 cycles of D-SPME-HPLC operation without showing any appreciable reduction in extraction performance).

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References

  1. Holopainen S, Luukkonen V, Nousiainen M, Sillanpää M (2013) Talanta 114:176–182

    Article  CAS  Google Scholar 

  2. Vayssieres L (2003) Adv Mater 15:464–466

    Article  CAS  Google Scholar 

  3. Arthur CL, Pawliszyn J (1990) Anal Chem 62:2145–2148

    Article  CAS  Google Scholar 

  4. Alizadeh R (2016) Talanta 146:831–838

    Article  CAS  Google Scholar 

  5. Zhang S, Du Z, Li G (2013) Talanta 115:32–39

    Article  CAS  Google Scholar 

  6. Li X, Zhong M, Xu S, Sun C (2006) J Chromatogr A 1135:101–108

    Article  CAS  Google Scholar 

  7. Lord H, Pawliszyn J (2000) J Chromatogr A 885:153–193

    Article  CAS  Google Scholar 

  8. Dietz C, Sanz J, Cámara C (2006) J Chromatogr A 1103:183–192

    Article  CAS  Google Scholar 

  9. Li W, Li L, Wang Z, Cui A, Sun C, Zhao J (2001) Mater Lett 49:228–234

    Article  CAS  Google Scholar 

  10. Cai W, Zhou Y, Bao R, Yue B, He H (2013) Chin J Catal 34:193–199

    Article  CAS  Google Scholar 

  11. Anandan S, Yoon M, Park S-E (2003) J Photosci 10:231–236

    CAS  Google Scholar 

  12. Zhou Y, Bao R, Yue B, Gu M, Pei S, He H (2007) J Mol Catal A Chem 270:50–55

    Article  CAS  Google Scholar 

  13. Zhou Y, Yue B, Bao R-L, Liu S-X, He H-Y (2006) Chin J Chem 24:1001–1005

    Article  CAS  Google Scholar 

  14. Shiju NR, Alberts AH, Khalid S, Brown DR, Rothenberg G (2011) Angew Chem 123:9789–9793

    Article  Google Scholar 

  15. Liu H, Li J, Liu X, Jiang S (2009) Talanta 78:929–935

    Article  CAS  Google Scholar 

  16. Kim Y, Ketpang K, Jaritphun S, Park JS, Shanmugam S (2015) J Mater Chem A 3:8148–8155

    Article  CAS  Google Scholar 

  17. Fazaeli R, Aliyan H, Tangestaninejad S, Foroushani SP (2014) J Iran Chem Soc 11:1687–1701

    Article  CAS  Google Scholar 

  18. Păcurariu C, Mihoc G, Popa A, Muntean SG, Ianoş R (2013) Chem Eng J 222:218–227

    Article  Google Scholar 

  19. Mousavi M, Noroozian E, Jalali-Heravi M, Mollahosseini A (2007) Anal Chim Acta 581:71–77

    Article  CAS  Google Scholar 

  20. Pinto PCR, da Silva EAB, Rodrigues ArEd (2010) Ind Eng Chem Res 49:12311–12318

    Article  CAS  Google Scholar 

  21. Xie W, Pawliszyn J, Mullett W, Matuszewski B (2007) J Pharm Biomed Anal 45:599–608

    Article  CAS  Google Scholar 

  22. Li Q, Wang X, Yuan D (2009) J Chromatogr 1216:1305–1311

    Article  CAS  Google Scholar 

  23. Bagheri H, Mir A, Babanezhad E (2005) Anal Chim Acta 532:89–95

    Article  CAS  Google Scholar 

  24. Liu X, Ji Y, Zhang Y, Zhang H, Liu M (2007) J Chromatogr 1165:10–17

    Article  CAS  Google Scholar 

  25. López-Jiménez FJ, Rubio S, Pérez-Bendito D (2008) J Chromatogr 1195:25–33

    Article  Google Scholar 

  26. Llorca-Pórcel J, Martínez-Parreño M, Martínez-Soriano E, Valor I (2009) J Chromatogr A 1216:5955–5961

    Article  Google Scholar 

  27. Fattahi N, Assadi Y, Hosseini MRM, Jahromi EZ (2007) J Chromatogr A 1157:23–29

    Article  CAS  Google Scholar 

  28. Villar-Navarro M, Ramos-Payán M, Luis Pérez-Bernal J, Fernández-Torres R, Callejón-Mochón M, Ángel Bello-López M (2012) Talanta 99:55–61

    Article  CAS  Google Scholar 

  29. Li X-S, Xu L-D, Shan Y-B, Yuan B-F, Feng Y-Q (2012) J Chromatogr A 1265:24–30

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Qom, 37185-359, Qom, Iran

    Maryam Bordbar & Reza Alizadeh

  2. Department of Chemistry, Faculty of Science, Payame Noor University, Tehran, Iran

    Javad Noori-Ahmadabadi & Ali Yeganeh-Faal

Authors
  1. Maryam Bordbar
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  2. Javad Noori-Ahmadabadi
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  3. Ali Yeganeh-Faal
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  4. Reza Alizadeh
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Correspondence to Maryam Bordbar.

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Bordbar, M., Noori-Ahmadabadi, J., Yeganeh-Faal, A. et al. Application of Amine and Phosphotungstic Acid Groups as a Novel Bifunctional Fiber Coating in SPME-HPLC of Volatile Phenols in Water. Chromatographia 80, 1605–1613 (2017). https://doi.org/10.1007/s10337-017-3402-3

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  • DOI: https://doi.org/10.1007/s10337-017-3402-3

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