Abstract
High efficiency of near infrared polymer light-emitting diodes with bilayer structure was obtained. The diode structure is ITO/PEDOT/L1/L2/Ba/Al, where L1 is phenyl-substituted poly [p-phenylphenylene vinylene] derivative (P-PPV), L2 is 9,9-dioctylfluorene (DOF) and 4,7-bis (3-hexylthiophen)-2-yl-2,l,3-naphthothiadiazole (HDNT) copolymer (PFHDNT10). The electroluminescence (EL) spectrum of diodes from PFHDNT10 is at 750 nm located in the range of near infrared. The maximum external quantum efficiency is up to 2.1% at the current density of 35 mA/cm2. The improvement of the diode’s performances was considered to be the irradiative excitons confined in the interface between L1 and L2 layers.
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References
Burroughes, J. H., Bradley, D. D. C., Brown, A. R. et al., Light-emitting diodes based on conjugated polymers, Nature, 1990, 347: 539–541.
Gustafsson, G., Cao, Y., Treacy, G. M. et al., Flexible light-emitting diodes made from soluble conducting polymers, Nature, 1990, 357:477–479.
Tang, C. W., Vanslyke, S. A., Chen, C. H., Electroluminescence of doped organic thin films, J. Appl. Phys., 1989, 65: 3610–3616.
Vignli, T., Lidzey, D. G., Bradley, D. D. C., Efficient energy transfer from blue to red in tetraphenylporphyrin-doped poly(9,9-dioctylfluorene) light-emitting diodes, Adv. Mater, 2000, 12: 58–62.
Chen, F. C., Yang, Y., Thompson, M. E. et al., High-performance polymer light-emitting diodes doped with a red phosphorescent indium complex, Appl. Phys. Lett., 2002, 80: 2308–2310.
Gong, X., Ostrowski, J. C., Bazan, G. C. et al., Red electrophosphorescence from polymer doped with iridium complex, Appl. Phys. Lett., 2003, 81: 3711–3713.
Klarner, G., Lee, J., Davey, M. H. et al., Exciton migration and trapping in copolymers based on dialkylfluorenes, Adv. Mater, 1999, 11: 115–119.
Bernius, M. T., Inbasekaran, M., Brien, J. et al., Progress with light-emitting polymers, Adv. Mater, 2000, 13: 1737–1750.
Klaerner, G., Miller, R. D., Polyfluorene derivatives: effective conjugation lengths from well-defined oligomers, Macromolecules, 1998, 31:2007–2009.
Beaupre, S., Leclerc, M., Fluorene-based copolymers for red-lightemitting diodes, Adv. Funct. Mater, 2002, 12: 192–196.
Hou, Q., Xu, Y., Yang, W. et al., Novel red-emitting fluorine-based copolymers, J. Mater Chem., 2002, 12: 2887–2892.
Yang, R., Tian, R., Hou, Q. et al., Synthesis and optical and electroluminescent properties of novel conjugated copolymers derived from fluorene and benzoselenadiazole, Macromolecules, 2003, 36: 7453–7460.
Yang, J., Jiang, C., Zhang, Y. et al., High-efficiency saturated red emitting polymers derived from fluorine and naphthoselenadiazole, Macromolecules, 2004, 37: 1211–1218.
Peng, J., Xu, Y., Hou, Q. et al., Electroluminescence and photoluminescence of dioctylfluorene and 4,7-dithien-2-yl-2,l,3-benzothiadiazole copolymers, Chinese Science Bulletin, 2002, 47: 1714–1717.
Becker, H., Spreitzer, H., Kreuder, W. et al., Soluble PPVs with enhanced performance-a mechanictic approach, Adv. Mater, 2000, 12:42–48.
Campell, A. J., Bradley, D. D. C., Antoniadis, H., Dispersive electron transport in an electroluminescent polyfluorene copolymer measured by the current integration time-of-flight method, Appl. Phys. Lett., 2001, 79: 2133–2135.
Corcoran, N., Arias, A. C., Kim, J. S. et al., Increased efficiency in vertically segregated thin-film conjugated polymer blends for light-emitting diodes, Appl. Phys. Lett., 2003, 82: 299–301.
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Yong, Z., Jian, Y., Qiong, H. et al. Near infrared polymer light-emitting diodes. Chin.Sci.Bull. 50, 957–960 (2005). https://doi.org/10.1360/04wb0128
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DOI: https://doi.org/10.1360/04wb0128