Over 95% of large-scale length uniformity in template-assisted electrodeposited nanowires by subzero-temperature electrodeposition
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In this work, we report highly uniform growth of template-assisted electrodeposited copper nanowires on a large area by lowering the deposition temperature down to subzero centigrade. Even with highly disordered commercial porous anodic aluminum oxide template and conventional potentiostatic electrodeposition, length uniformity over 95% can be achieved when the deposition temperature is lowered down to -2.4°C. Decreased diffusion coefficient and ion concentration gradient due to the lowered deposition temperature effectively reduces ion diffusion rate, thereby favors uniform nanowire growth. Moreover, by varying the deposition temperature, we show that also the pore nucleation and the crystallinity can be controlled.
KeywordsCu nanowire template-assisted electrodeposition length uniformity low-temperature electrodeposition nucleation crystallinity
anodic aluminum oxide
standard hydrogen electrode
scanning electron microscope
transmission electron microscope.
Length uniformity in template-assisted electrodeposited nanowires is of great importance in realizing the nanowires as building blocks for various technological applications that specifically involve electron flow through the nanowires such as thermoelectric [1, 2], spintronics [3, 4], photovoltaics , interconnects [6, 7], and phase-change memory devices . In feasibility aspect, template-assisted nanowires have an extraordinary advantage over other nanowires that are grown by different methods such as vapor-liquid-solid method  and electroless-etched method [10, 11]. In detail, the template can be readily used as a supporting matrix without any further fabrication process. Supporting matrix, which is essential in fabricating nanowire-based electronic devices, provides mechanical robustness, electrical insulation among adjacent nanowires, and fabrication feasibility when contacting the electrodes at the ends of the nanowires .
Ideally, template-assisted electrodeposited nanowires should all be connected to the conducting electrodes at the both ends. At one end, the seed layer that works as a working electrode holds all nanowires, but the problem arises from the other end. Nonuniform ion transport that is near and inside the template pores results in nonuniform growth of the nanowires. This in turn creates only a few numbers of nanowires that are fully grown to be exposed out of the template. By continuing the electrodeposition to further grow the premature nanowires, the fully grown nanowires start to create semi-spherical caps that completely block the other remaining pores having shorter nanowires, especially in widely used porous anodic aluminum oxide (AAO) due to its high porosity and packing density. This is extremely critical in fabricating the nanowire-based devices since only a limited numbers of the nanowires are actually in contact at the both ends. In other words, major portion of the nanowires is malfunctioning.
Several attempts on the uniform growth of template-assisted electrodeposited nanowires have been made recently such as pulsed electrodeposition [13, 14, 15], low-temperature electrodeposition , ultrasonic milling , and applying forced convection to the bulk electrolyte . The most successful result achieved so far to the authors' best knowledge is from Stacy and co-workers where they achieved up to 93% of length uniformity in Bi2Te3 nanowires with length of 62-68 μm by employing pulsed electrodeposition in a well-ordered homemade AAO template at low deposition temperature (1°C to 4°C) . Among the above-mentioned methods used to enhance the length uniformity, lowering the deposition temperature is shown to be highly effective, easily manipulated, and straightforward to proceed . However, intensive study regarding the temperature effect on the growth of template-assisted electrodeposited nanowires is rarely done despite its importance [16, 18, 19].
Herein, we report highly uniform growth of template-assisted electrodeposited copper (Cu) nanowires by lowering the deposition temperature down to subzero centigrade. Cu nanowire is regarded as potential candidates for various applications including interconnects [6, 7], giant magnetoresistive materials [3, 4], infrared polarizer , and cooling applications [21, 22]. The ion diffusion rate, which directly influences the electrodeposition behavior thereby length uniformity, can be appropriately controlled by varying the deposition temperature. Moreover, we show that the pore nucleation and the crystallinity can also be controlled by varying the deposition temperature.
Commercially available AAO, Anodisc™ (nominal pore size 20 nm, Whatman, Maidstone, Kent, UK), which is about 60-μm thick, was used as an electrodeposition template. Anodisc™ can additionally give the most harsh electrodeposition conditions since this template exhibits extremely disordered form where the pores are nonuniformly distributed with different pore sizes at the each pore ends (see Figure A1 in Additional file 1) . Also, the pores are seriously interconnected and defects are often observed. The overall pore size is about 200 nm to approximately 300 nm and the pores are spanned along the whole template. However, at the one end, the pores are separated into several smaller pores having pore size of about 20 nm to approximately 40 nm. In sum, the use of Anodisc™ can provide a lower limit of nanowire uniformity in growth of large-area nanowires by electrodeposition.
Cu was chosen to exclude any complex reagents and additives that may influence the ionic transport behavior. The aqueous Cu electrolyte simply consisted of 220 g/l CuSO4·2O (99%) and 32 g/l H2SO4 (95%) with highly deionized water (18.2 MΩ cm). All chemicals were purchased from Duksan Pure Chemicals (Seoul, Korea) and used as received without further purification process.
A three-electrode electrochemical cell was employed for Cu electrodeposition. A 300-nm Au with 20 nm of Cr adhesion layer was coated on one side of the template (narrow pore end) using e-beam evaporator to act as a working electrode. Ag/AgCl (saturated KCl) and Pt mesh electrodes were employed for reference and counter electrodes, respectively. All potentials in this study are given in relation to the standard hydrogen electrode (SHE) since the electrode potential of the Ag/AgCl electrode is temperature dependent . To calibrate the temperature effect, linear temperature coefficient of the Ag/AgCl electrode versus SHE is given as -1.01 mV/K . Linearvoltametry and potentiostatic electrodeposition were done using a standard potentiostat (VersaSTAT3, Princeton Applied Research). The deposition temperature was controlled in the range of -2.4 to 60.5°C using a constant temperature circulating bath (HI-1030I, Hanil Industrial Machine, Seoul, Korea) and the temperature was precisely maintained under ± 0.1°C of deviation.
After electrodeposition, nanowire-embedded AAO template was cleaved and the cross section was observed using an optical microscope (BX51M, Olympus, Olympus America, Inc., Center Valley, PA, USA) to verify the large-area length uniformity of the nanowires. Subsequently, the Au/Cr working electrode was partially etched away and placed into the scanning electron microscope (SEM; S-4300, Hitachi Co., Tokyo, Japan) and the X-ray diffractometer (XRD; Rint-2000, Rigaku Corporation, Tokyo, Japan) in order to determine the pore nucleation and the preferential nanowire growth direction, respectively. For XRD measurement, Cu-Kα radiation source at 40 kV and 30 mA was used in 2θ range of 30° to approximately 90° with scan rate of 0.02°/s.
The crystallinity of the individual Cu nanowires was observed using transmission electron microscope (TEM; JEM-3010, JEOL, Tokyo, Japan). Individual nanowire samples were prepared by dissolving the AAO template in 1 M NaOH for 1 day followed by thorough rinsing with an absolute ethanol and 10 min of sonication.
Results and discussion
This extremely high length uniformity in a disordered AAO template is mainly attributed to the slow nanowire growth rate which is achieved by reducing the ion transport rate at low temperature. The slow ion diffusion may inhibit two major ion transport regions that can lead to the nonuniform nanowire growth: First is the transport of cations from the bulk electrolyte to the pore entrance. At room temperature, without any forced convection, cations entering the pores tend to be concentrated at the edge area of the template since the excess cations are constantly diffused from the adjacent bulk electrolyte due to the hemispherical diffusion layers formed at the edge area . Second is the cation transport along the pore channels. Different pore diameters and native defects inside the pores can lead to nonuniform ion transport [15, 17], resulting nonuniform nanowire growth. These two unfavorable transport behaviors are believed to be significantly hindered even without any stirring or pulsed electrodeposition when the deposition temperature is sufficiently lowered, thereby achieving extremely high length uniformity.
It is also known that the pore nucleation is dependent on the deposition temperature . It is interesting to note that the Anodisc™ template may provide an effective way to evaluate the pore nucleation. As mentioned earlier, Anodisc™ exhibits interbranched pore structures at the narrow-end side of the template. As the electrodeposition proceeds, the fastest nucleated pore will reach the main (wide) pore and eventually block all the other narrow pores that share the same main pore. The narrow end is about 100 nm to approximately 200 nm long (Figure A1(f) in Additional file 1) and regarding the fast growth rate, this narrow end will be filled in a very short period of time, especially when the deposition temperature is high. By blocking other pores, we can easily distinguish the pores that are not nucleated at the initial stage since the cations cannot be supplied to the non-nucleated pores. Therefore, this narrow feature may provide an effective means of evaluating the instantaneous pore nucleation.
This different nucleation and growth processes can also affect the crystallinity of the nanowires . In order to investigate the influence of deposition temperature on the crystallinity of the electrodeposited Cu nanowires, we conducted XRD and TEM studies. In general, it is well known that the electrodeposited nanowire exhibits a polycrystalline nature when grown potentiostatically [32, 33]. However, the crystallinity can be enhanced to a certain degree by increasing the deposition temperature . When the deposition temperature is low, slow growth rate promotes increased nucleation sites and growth of new grains. In contrary, high deposition temperature favors the growth of pre-existing grains which leads to the deposition of single crystals rather than the creation of new grains, thereby enhancing the crystallinity .
In summary, we have achieved length uniformity of template-assisted electrodeposited nanowires over 95%, even in highly disordered commercial AAO template, when the deposition temperature was lowered down to subzero centigrade degrees. Due to the decreased ion diffusion rate and thereby decreased nanowire growth rate, uniform electrodeposition was enabled. Moreover, when the deposition temperature was lowered, pore nucleation was also significantly enhanced whereas the crystallinity was slightly decreased as the nucleation mechanism tended to proceed toward progressive nucleation. Therefore, by lowering the deposition temperature, large-scale length uniformity and pore filling can be simultaneously achieved which are both extremely important in realizing the nanowire array as practical large-scale applications.
This study was supported by Mid-career Researcher Program through NRF grant funded by the MEST (No. 2011-0000252 and No. 2011-0017673). The authors greatly appreciate Ha-Yeong Kim for valuable effort on help with the XRD measurements.
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