Skip to main content
Log in

The Influence of the Medium Polarity on the Molecular Weight of Poly-2-hydroxyethyl Methacrylate

  • Published:
Polymer Science, Series D Aims and scope Submit manuscript

Abstract

The results of experimental studies on the kinetics of polymerization of 2-hydroxyethyl methacrylate in water and in water–dimethyl sulfoxide and water–dimethylformamide mixtures are summarized. The influence of the polarity of the medium on the molecular weight of the resulting polymers was analyzed. It has been shown that the introduction of additives of organic solvents, which reduce the polarity of the reaction medium, causes a decrease in the rates of chain-propagation reactions, which, together with the reactions of chain transfer to the solvent, leads to a decrease in the molecular weight of polymers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. V. N. Kuleznev and V. A. Shershnev, Chemistry and Physics of Polymers, 3rd ed. (KolosS, Moscow, 2014) [in Russian].

    Google Scholar 

  2. Yu. D. Semchikov, High-Molecular Weight Compounds, 3rd ed. (Akademiya, Moscow, 2006) [in Russian].

    Google Scholar 

  3. N. A. Lavrov, “Complexation in a monomer-monomer system upon copolymerization of 2-hydroxyethyl methacrylate with acrylic acid,” Polym. Sci., Ser. D 14, 77–79 (2021).

    CAS  Google Scholar 

  4. N. A. Lavrov, Polymers on the Basis of 2-Hydroxyethylmetacrilate (Professiya, St. Petersburg, 2017) [in Russian].

    Google Scholar 

  5. A. F. Nikolaev, Structure and Properties of Water (St. Petersburg Gos. Tekhnol. Inst., St. Petersburg, 2016) [in Russian].

    Google Scholar 

  6. K. K. Kalnin’sh and L. P. Pavlova, Voda: A Life Source. Monography (Inst. Macromolecular Comp. Russ. Acad. Sciences, St. Petersburg, 2005) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. A. Lavrov.

Additional information

Translated by Sh. Galyaltdinov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lavrov, N.A. The Influence of the Medium Polarity on the Molecular Weight of Poly-2-hydroxyethyl Methacrylate. Polym. Sci. Ser. D 15, 464–466 (2022). https://doi.org/10.1134/S1995421222030170

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995421222030170

Keywords:

Navigation