Abstract
The results of experimental studies on copolymerization kinetics of 2-hydroxyethyl methacrylate with carboxyl-containing monomers of acrylic, methacrylic, and maleic acids in water using the redox initiator system of ammonium persulfate–ascorbic acid are summarized. The effect of process conditions on the reaction rate, relative activity of monomers, composition, and microstructure of copolymers is analyzed.
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REFERENCES
S. N. Ushakov, Synthetic Medicinal Polymers (Medgiz, Leningrad, 1962) [in Russian].
E. F. Panarin, “Biologically active polymer nanosystems,” Russ. Chem. Bull. 66 (10), 1812–1820 (2017).
M. V. Solovskii, G. M. Pavlov, E. V. Korneeva, S. E. Harding, V. M. Denisov, and N. V. Nikol’skaya, “Synthesis of N-vinylpyrrolidone-crotonic acid-2-hydroxyethyl methacrylate terpolymers as carriers of biologically active substances,” Russ. J. Appl. Chem. 75 (2), 276–280 (2002).
N. A. Lavrov, “Properties of 2-hydroxyethylmethacrylate copolymers and hydrogels based on them,” Polym. Sci., Ser. D 5 (2), 77–82 (2012).
K. K. Kalnin’sh and L. P. Pavlova, Water—A Spring of Life: Monograph (Inst. Vysokomol. Soedin. Ross. Akad. nauk, S.-Peterb. Gos. Univ. Tekhnol. Dizaina, St. Petersburg, 2005) [in Russian].
N. A. Lavrov, “Kinetic features of the homopolymerisation of 2-hydroxyethylmethacrylate in various media,” Int. Polym. Sci. Technol. 31 (5), 44–59 (2004).
N. A. Nesterova, I. N. Gavrilova, and E. F. Panarin, “Radical copolymerization of N-vinylformamide with unsaturated carboxylic acids,” Russ. J. Appl. Chem. 82 (4), 618–621 (2009).
M. V. Solovskii, M. Yu. Eropkin, M. Yu. Smirnova, and I. I. Gavrilova, “Complexes of antibiotics-aminoglycosides with copolymers of acrylamide with acrylic and methacrylic acids,” Pharm. Chem. J. 44 (6), 314–318 (2010).
A. F. Nikolaev, Structure and Properties of Water (S.‑Peterb. Gos. Tekhnol. Inst., St. Petersburg, 2006) [in Russian].
N. A. Lavrov, “Theoretical and practical aspects of the synthesis of medical polymers based on nvinylsuccinimide in aqueous media,” Int. Polym. Sci. Technol. 39 (1), 47–60 (2012).
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Translated by Sh. Galyaltdinov
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Lavrov, N.A. Copolymerization of 2-Hydroxyethyl Methacrylate with Carboxylic Monomers. Polym. Sci. Ser. D 12, 64–68 (2019). https://doi.org/10.1134/S1995421219010118
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DOI: https://doi.org/10.1134/S1995421219010118