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Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions

  • ON THE 80th ANNIVERSARY OF THE BIRTH OF A. B. ZEZIN
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Abstract

The kinetic features of the radical polymerization of trimethylmethacryloyloxyethylammonium methyl sulfate in micellar solutions of an oppositely charged surfactant—sodium dodecyl sulfate—are studied by NMR spectroscopy. It is shown that matrix polymerization occurs by the zip mechanism only in dilute surfactant solutions containing spherical micelles at a molar ratio of [monomer]/[surfactant] ≤ 1 and at a significant increase in the polymerization rate. An increase in surfactant concentration leads to a change in the mechanism of matrix polymerization accompanied by a decrease in the rate of polymerization, which is probably related to a change in the shape of micelles. The molecular weight of the obtained polyelectrolytes depends on the molar ratio of the components and is minimal at the [monomer]/[surfactant] equimolar ratio.

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Notes

  1. The polymerization rate was calculated according to the additivity rule under the assumption that, under conditions of monomer excess, its part equimolar to DDS is bound to surfactant micelles and polymerizes by the matrix mechanism at a constant rate VMP and the remaining amount of the monomer is polymerized in solution by the free radical mechanism at rate VRP. It was believed that the rate of matrix polymerization corresponds to the maximum rate values on curves 1 and 2, respectively, and the polymerization rate in water was determined from curve 3 in Fig. 2 for the corresponding “residual” concentration of M not bound to surfactant micelles. Total polymerization rate, VΣ, was calculated by the formula VΣ = VMPx + VRP (1 – x), where x is the molar fraction of monomer bound to surfactant micelles.

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Funding

This work was carried out within the framework of the agreement on joint scientific research between the Volgograd State Technical University and St. Petersburg State University (no. С-119/7) and the design part of the State Assignment (no. 4.3230.2017/4.6).

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Authors and Affiliations

  1. Volgograd State Technical University, 400005, Volgograd, Russia

    Yu. V. Shulevich, E. G. Dukhanina, D. S. Bykov, A. V. Navrotskii & I. A. Novakov

  2. Faculty of Chemistry, Moscow State University, 119899, Moscow, Russia

    Yu. A. Zakharova

  3. Magnetic Resonance Research Center, St. Petersburg State University, 198504, St. Petersburg, Peterhof, Russia

    P. M. Tolstoi & M. A. Vovk

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  1. Yu. V. Shulevich
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  2. Yu. A. Zakharova
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  5. E. G. Dukhanina
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  8. I. A. Novakov
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Correspondence to Yu. V. Shulevich.

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Shulevich, Y.V., Zakharova, Y.A., Tolstoi, P.M. et al. Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions. Polym. Sci. Ser. B 61, 715–724 (2019). https://doi.org/10.1134/S1560090419060125

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