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Concentration effect in copolymerization of sodium 2-acrylamido-2-methylpropanesulfonate with sodium acrylate in aqueous solutions

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Abstract

The effect of the concentration of the initial monomer mixture, the comonomer ratio, and temperature on the kinetic parameters of the process and the characteristics of the resulting copolymers in the homogeneous copolymerization of sodium 2-acrylamido-2-methylpropanesulfonate with sodium acrylate in aqueous solutions at 50–80°C in the presence of potassium persulfate is studied. The initial rate of copolymerization and the molecular mass of copolymers increase with the total initial concentration of the monomer mixture and the content of sodium 2-acrylamido-2-methylpropanesulfonate. As temperature increases, the initial rate of copolymerization increases and the molecular mass of the copolymer diminishes. When copolymerization is performed in 10, 30, and 40% aqueous solutions of the monomers, the resulting copolymers are enriched in sodium acrylate units. The content of sodium 2-acrylamido-2-methylpropane-sulfonate units in the copolymer slightly increases with an increase in the total initial concentration of the monomer mixture.

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References

  1. S. F. Naumova, L. N. Skripnichenko, T. V. Konysheva, et al., Vestn. Akad. Nauk Bel. SSR, Ser. Khim., No. 2, 78 (1985).

  2. S. L. Sahli and N. S. Sherwood, EP Patent No. 309049 (1989).

  3. B. P. Boffardi, US Patent No. 4693829 (1987).

  4. C. Y. Cha and R. G. Varsanik, US Patent No. 4680135 (1987).

  5. V. F. Kurenkov, A. V. Kurenkov, and F. I. Lobanov, Polymer Science, Ser. B 51, 291 (2009) [Vysokomol. Soedin., Ser. B 51, 1554 (2009)].

    Article  Google Scholar 

  6. A. V. Kurenkov, D. F. Sultanova, V. F. Kurenkov, and F. I. Lobanov, Entsikl. Inzh.-Khim., No. 4, 36 (2009).

  7. V. A. Kabanov and D. A. Topchiev, Polymerization of Ionizable Monomers (Nauka, Moscow, 1975) [in Russian].

    Google Scholar 

  8. V. F. Kurenkov and V. A. Myagchenkov, Eur. Polym. J. 15, 849 (1979).

    Article  CAS  Google Scholar 

  9. V. F. Kurenkov and V. A. Myagchenkov, Zh. Prikl. Khim. (S.-Peterburg) 72, 881 (1999).

    CAS  Google Scholar 

  10. V. F. Kurenkov, T. A. Zhelonkina, and V. I. Kovalenko, Zh. Prikl. Khim. (S.-Peterburg) 78, 301 (2005).

    Google Scholar 

  11. G. Charlot, Les methodes de la chimie analytique. Analyse quantitative minerale (Masson, Paris, 1961; Khimiya, Moscow, 1969).

    Google Scholar 

  12. K. I. Kholodnova, V. N. Pavlyuchenko, Z. M. Alekseeva, and A. I. Andreeva, Catalytic and Initiating Systems for Synthesis and Modification of Polymers (NPO Plastpolimer, Leningrad, 1984) [in Russian].

    Google Scholar 

  13. T. M. Kolthoff and I. K. Miller, J. Am. Chem. Soc. 73, 3055 (1951).

    Article  CAS  Google Scholar 

  14. 2-Acrylamido-2-methylpropane Sulfonic Acid Monomer (The Lubrizol Corp., Wickliffe, 1994).

  15. Ch. Tanford, Physical Chemistry of Macromolecules (Wiley, New York, 1961; Khimiya, Moscow, 1965).

    Google Scholar 

  16. V. A. Kabanov, V. P. Zubov, and Yu. D. Semchikov, Complex-Radical Polymerization (Khimiya, Moscow, 1987) [in Russian].

    Google Scholar 

  17. Yu. E. Kirsh, Poly(N-vinylpyrrolidone) and Other Poly(N-vinylamides) (Nauka, Moscow, 1998) [in Russian].

    Google Scholar 

  18. V. F. Kurenkov and A. G. Safin, Polymer Science, Ser. A 39, 1163 (1997) [Vysokomol. Soedin., Ser. A 39, 1749 (1997)].

    Google Scholar 

  19. V. F. Kurenkov and A. G. Safin, Zh. Prikl. Khim. (St. Petersburg) 70, 2030 (1997).

    CAS  Google Scholar 

  20. N. N. Loginova, R. K. Gavurina, and M. L. Aleksandrova, Vysokomol. Soedin., Ser. B 11, 643 (1969).

    CAS  Google Scholar 

  21. D. A. Topchiev and G. T. Nazhmetdinova, Vysokomol. Soedin., Ser. A 25, 636 (1983).

    CAS  Google Scholar 

  22. F. De Schrijver and G. Smets, J. Polym. Sci., Part A-1 4, 2201 (1966).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Kazan State Technological University, ul. Karla Marksa 68, Kazan, 420015, Tatarstan, Russia

    V. F. Kurenkov & A. V. Kurenkov

  2. OOO KNT Plus, Vostryakovskii pr. 10 B/1, Moscow, 117403, Russia

    F. I. Lobanov

Authors
  1. V. F. Kurenkov
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  2. A. V. Kurenkov
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  3. F. I. Lobanov
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Correspondence to V. F. Kurenkov.

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Original Russian Text © V.F. Kurenkov, A.V. Kurenkov, F.I. Lobanov, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 8, pp. 1530–1534.

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Kurenkov, V.F., Kurenkov, A.V. & Lobanov, F.I. Concentration effect in copolymerization of sodium 2-acrylamido-2-methylpropanesulfonate with sodium acrylate in aqueous solutions. Polym. Sci. Ser. B 52, 487–491 (2010). https://doi.org/10.1134/S1560090410070146

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  • DOI: https://doi.org/10.1134/S1560090410070146

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