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Specific features of the copolymerization of acrylonitrile and acrylamide in the presence of low-molecular-mass and polymeric trithiocarbonates and properties of the obtained copolymers

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Abstract

Regularities of the formation of acrylonitrile-acrylamide copolymers obtained from initial monomer feeds containing 1–50 wt % acrylamide in DMSO solutions with the participation of low-molecular-mass and polymeric trithiocarbonates as reversible addition-fragmentation chain transfer agents are studied for the first time. It is shown that the copolymerization in the presence of low-molecular-mass trithiocarbonates proceeds via a pseudo-living mechanism. The synthesized copolymers prove to be inefficient as reversible addition-fragmentation chain transfer agents, a result that leads to products with bimodal molecular-mass distributions. The rheological characteristics of solutions, as well as the thermal behavior of the copolymers obtained in the absence and in the presence of reversible addition-fragmentation chain transfer agents, are studied. The effect of the synthesis conditions on the properties of the synthesized copolymers is discussed.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    E. V. Chernikova, S. M. Kishilov & A. V. Plutalova

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    Yu. V. Kostina, G. N. Bondarenko, A. A. Baskakov & S. O. Il’in

  3. Lomonosov State University of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia

    A. Yu. Nikolaev

Authors
  1. E. V. Chernikova
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  2. S. M. Kishilov
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  3. A. V. Plutalova
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  4. Yu. V. Kostina
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  5. G. N. Bondarenko
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  6. A. A. Baskakov
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  7. S. O. Il’in
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  8. A. Yu. Nikolaev
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Corresponding author

Correspondence to E. V. Chernikova.

Additional information

Original Russian Text © E.V. Chernikova, S.M. Kishilov, A.V. Plutalova, Yu.V. Kostina, G.N. Bondarenko, A.A. Baskakov, S.O. Il’in, A.Yu. Nikolaev, 2014, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2014, Vol. 56, No. 5, pp. 454–467.

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Chernikova, E.V., Kishilov, S.M., Plutalova, A.V. et al. Specific features of the copolymerization of acrylonitrile and acrylamide in the presence of low-molecular-mass and polymeric trithiocarbonates and properties of the obtained copolymers. Polym. Sci. Ser. B 56, 553–565 (2014). https://doi.org/10.1134/S1560090414050029

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  • DOI: https://doi.org/10.1134/S1560090414050029

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