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Synthesis of δ-Valerolactone Using Stable Hydrogen Peroxide Derivatives

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Abstract

The efficiencies of hydrogen peroxide derivatives in the Baeyer–Villiger oxidation of cyclopen­tanone to δ-valerolactone have been compared. The oxidants used were hydrogen peroxide in acetic, formic, or trifluoroacetic acid, magnesium and sodium monoperoxyphthalates, cumene hydroperoxide, and tert-butyl hydroperoxide. The oxidation was carried out in water, aqueous methanol, and water–ethyl acetate. Sodium and magnesium monoperoxyphthalates turned out to provide high conversion and selectivity under mild conditions.

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Authors and Affiliations

  1. Yeltsin Ural Federal University, 620002, Yekaterinburg, Russia

    Ya. V. Solovyova & A. V. Pestov

  2. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, 620108, Yekaterinburg, Russia

    Ya. V. Solovyova, I. S. Puzyrev, M. G. Pervova, V. A. Kuznetsov, I. A. Vlasov, G. A. Artemiev & A. V. Pestov

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  1. Ya. V. Solovyova
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  2. I. S. Puzyrev
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  3. M. G. Pervova
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  4. V. A. Kuznetsov
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  5. I. A. Vlasov
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  6. G. A. Artemiev
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Correspondence to Ya. V. Solovyova.

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Translated from Zhurnal Organicheskoi Khimii, 2022, Vol. 58, No. 4, pp. 381–386 https://doi.org/10.31857/S0514749222040024.

This article is published according to the report presented at the Vth International Conference “Modern Synthetic Methodologies for the Design of Drugs and Functional Materials” which was held on November 8–12, 2021, in Yekaterinburg and Perm.

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Solovyova, Y.V., Puzyrev, I.S., Pervova, M.G. et al. Synthesis of δ-Valerolactone Using Stable Hydrogen Peroxide Derivatives. Russ J Org Chem 58, 480–483 (2022). https://doi.org/10.1134/S1070428022040029

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  • DOI: https://doi.org/10.1134/S1070428022040029

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