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Alternative Synthetic Routes to Dioxolanes and Thiadiazines

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Abstract

The hydrolysis of 2-methylbut-3-yn-2-yl carbamate gave 4,4-dimethyl-5-methylidene-1,3-dioxo­lan-2-one, whereas 2-methylbut-3-yn-2-ol was converted under similar conditions to 3-hydroxy-3-methylbutan-2-one. 2-[2-Amino(hydrazinyl)-6H-1,3,4-thiadiazin-5-yl]propan-2-yl carbamates were synthesized by reacting 4-bromo-2-methyl-3-oxobutan-2-yl carbamate with thiosemicarbazide and carbonothioic dihydrazide, respectively.

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Funding

This study was performed under financial support by the Ministry of Economy and Trade of Tajikistan Republic (project no. 0116 EO 00547).

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Authors and Affiliations

  1. Nikitin Institute of Chemistry, National Academy of Sciences of Tajikistan, 734063, Dushanbe, Tajikistan

    M. D. Isobaev, E. Kh. Pulatov, T. Kh. Abdullaev, M. Z. Turdialiev, B. G. Mavlonov & M. I. Jumaeva

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  1. M. D. Isobaev
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  2. E. Kh. Pulatov
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  3. T. Kh. Abdullaev
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  4. M. Z. Turdialiev
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  5. B. G. Mavlonov
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  6. M. I. Jumaeva
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Correspondence to M. D. Isobaev.

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Additional information

Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 3, pp. 391–399 https://doi.org/10.31857/S0514749221030071.

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Isobaev, M.D., Pulatov, E.K., Abdullaev, T.K. et al. Alternative Synthetic Routes to Dioxolanes and Thiadiazines. Russ J Org Chem 57, 369–375 (2021). https://doi.org/10.1134/S1070428021030076

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  • DOI: https://doi.org/10.1134/S1070428021030076

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