Abstract
An efficient one-pot procedure has been developed for the synthesis of bis-1,5,3-dithiazepanes by reaction of ethane-1,2-dithiol with formaldehyde and ammonium salts. According to the X-ray diffraction data, the heterorings in 3,3′-[ethane-1,2-diylbis(sulfanediylmethanediyl)]bis(1,5,3-dithiazepane) in crystal adopt a chair conformation with axial orientation of the substituent on the nitrogen atom.
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Original Russian Text © G.R. Khabibullina, V.R. Akhmetova, I.S. Bushmarinov, A.G. Ibragimov, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 10, pp. 1563–1567.
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Khabibullina, G.R., Akhmetova, V.R., Bushmarinov, I.S. et al. One-pot synthesis of bis-1,5,3-dithiazepanes from ethane-1,2-dithiol, formaldehyde, and ammonium salts. Russ J Org Chem 49, 1542–1545 (2013). https://doi.org/10.1134/S1070428013100229
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DOI: https://doi.org/10.1134/S1070428013100229