Abstract
The equilibrium in the reversible rearrangement of 5-methyl-1,2,3-thiadiazole-4-carbothioamides into 5-amino-4-thioacetyl-1,2,3-thiadiazoles is displaced toward the former, and polar solvents favor increased fraction of the thioketone.
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Original Russian Text © P.E. Prokhorova, T.A. Kalinina, T.V. Glukhareva, Yu.Yu. Morzherin, 2012, published in Zhurnal Organicheskoi Khimii, 2012, Vol. 48, No. 10, pp. 1338–1341.
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Prokhorova, P.E., Kalinina, T.A., Glukhareva, T.V. et al. Synthesis of 4-thioacetyl-1,2,3-thiadiazoles. Reversible rearrangement of N-Substituted 5-methyl-1,2,3-thiadiazole-4-carbothioamides. Russ J Org Chem 48, 1333–1336 (2012). https://doi.org/10.1134/S1070428012100132
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DOI: https://doi.org/10.1134/S1070428012100132