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1,7-Dithioxo systems. Reaction of bis(5,5-dimethyl-3-thioxo-cyclohex-1-en-1-yl) sulfide with amines

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Abstract

Reactions of amines (N,N-dimethylethane-1,2-diamine, benzylamine, aniline) with bis(5,5-dimethyl-3-thioxocyclohex-1-en-1-yl) sulfide result in cleavage of the sulfide bond and formation of the corresponding 3-amino-5,5-dimethylcyclohex-2-ene-1-thiones. Aminolysis of bis(5,5-dimethyl-3-oxocyclohex-1-en-1-yl) sulfide occurs at the carbonyl groups with conservation of the divinyl sulfide fragment.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    L. V. Timokhina, O. V. Sokol’nikova, L. V. Kanitskaya, M. P. Yashchenko & M. G. Voronkov

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  1. L. V. Timokhina
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  2. O. V. Sokol’nikova
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  3. L. V. Kanitskaya
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  4. M. P. Yashchenko
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  5. M. G. Voronkov
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Correspondence to L. V. Timokhina.

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Original Russian Text © L.V. Timokhina, O.V. Sokol’nikova, L.V. Kanitskaya, M.P. Yashchenko, M.G. Voronkov, 2008, published in Zhurnal Organicheskoi Khimii, 2008, Vol. 44, No. 4, pp. 537–540.

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Timokhina, L.V., Sokol’nikova, O.V., Kanitskaya, L.V. et al. 1,7-Dithioxo systems. Reaction of bis(5,5-dimethyl-3-thioxo-cyclohex-1-en-1-yl) sulfide with amines. Russ J Org Chem 44, 532–535 (2008). https://doi.org/10.1134/S1070428008040118

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  • DOI: https://doi.org/10.1134/S1070428008040118

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