Skip to main content
SpringerLink
Log in

Synthesis of 3-imino and 3-ylideno derivatives of 4-fluoro-5-polyfluoroalkyl-1,2-dithiolenes

  • Published:
Russian Journal of Organic Chemistry Aims and scope Submit manuscript

Abstract

Reactions of 4-fluoro-5-polyfluoroalkyl-1,2-dithiol-3-thiones with hydroxylamine and hydrazines occur with replacement of the thiocarbonyl by imino group affording oximes and hydrazones respectively. N-Alkyl-and N-aryl-3-imino-1,2-dithiolenes formed in reactions of 3-chlorothio-1,2-dithiolium salts with primary alkyl-or arylamines. 3-Chlorothio-1,2-dithiolium salts react with compounds possessing an active methylene group yielding 3-ylideno derivatives of 1,2-dithiolenes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Timoshenko, V. M., Bouillon, J.-P., Shermolovich, Yu. G., and Portella, C., Tetrahedron Lett., 2002, vol. 43, p. 5809.

    Article  CAS  Google Scholar 

  2. Fesun, I.N., Timoshenko, V.M., Chernega, A.N., and Shermolovich, Yu.G., Zh. Org. Khim., 2005, no. 350/04.

  3. Vasil’eva, T.P., Lin’kova, M.G., and Kil’disheva, O.V., Usp. Khim., 1976, vol. 45, p. 1269.

    CAS  Google Scholar 

  4. Timoshenko, V.M., Nikolin, Ya.V., Kolesnik, N.P., and Shermolovich, Yu.G., Zh. Org. Khim., 2001, vol. 37, p. 666.

    Google Scholar 

  5. Pedersen, C.T., Adv. Heterocycl. Chem., 1982, vol. 31, p. 63.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, 02094, Ukraine

    I. N. Fesun, V. M. Timoshenko & Yu. G. Shermolovich

Authors
  1. I. N. Fesun
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Timoshenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. G. Shermolovich
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. G. Shermolovich.

Additional information

Original Russian Text © I.N. Fesun, V.M. Timoshenko, Yu.G. Shermolovich, 2006, published in Zhurnal Organicheskoi Khimii, 2006, Vol. 42, no. 2, pp. 272–276.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fesun, I.N., Timoshenko, V.M. & Shermolovich, Y.G. Synthesis of 3-imino and 3-ylideno derivatives of 4-fluoro-5-polyfluoroalkyl-1,2-dithiolenes. Russ J Org Chem 42, 261–265 (2006). https://doi.org/10.1134/S1070428002120187

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070428002120187

Keywords

Search

Navigation