Abstract
In the present work, an endeavor has been made to develop an effective and binder-free CuO/Cu(OH)2 nanostructure based electrode by facile one-step solution-immersion method. FESEM, XRD and Raman spectroscopy are utilized to identify structural and morphological character of the prepared CuO/Cu(OH)2 nanostructures on the Cu foil. The electrochemical analysis has shown that CuO/Cu(OH)2 nanostructures developed on the Cu foil upon immersion in 0.15 M ammonium persulfate based aqueous solution for 100 min, have displayed a very high specific capacity of 339.7 C g–1/303.7 C g–1 at scan rate 10m V s–1/current density 3.33 A g–1. After 1000 cycles of galvanostatic charge-discharge at a high current density of 10 A g–1, CuO/Cu(OH)2 nanostructures based binder-free electrode has shown no decrease of specific capacity, instead an increase in the value of specific capacity by ~26% is observed. The cyclic voltammetry, galvanostatic charge discharge as well as electrochemical impedance spectroscopic results are justifying the potential candidature of CuO/Cu(OH)2 nanostructures on copper foil as a high performance, binder-free, battery-type electrode for hybrid supercapacitor application.
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ACKNOWLEDGMENTS
The authors are thankful to the Lovely Professional University for providing the characterization facilities and funds under the scheme LPU/DRDSEED/SAC/65. Further, the authors also want to thank Council of Scientific and Industrial Research, New Delhi, India for providing the funding assistance under the EMR scheme (Grant number: 03(1469)/19/EMR-II).
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KP, J., Kumar, P., Jabeen, S. et al. Facile Synthesis and Optimization of CuO/Cu(OH)2 Nanostructures on Cu-Foil for an Energy Storage Application. Russ J Appl Chem 95, 1723–1737 (2022). https://doi.org/10.1134/S1070427222110076
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DOI: https://doi.org/10.1134/S1070427222110076