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Behavior of Polytrimethylsilylpropyne-Based Composite Membranes in the Course of Continuous and Intermittent Gas Permeability Measurements

  • Membrane Processes
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Abstract

Two methods for monitoring the physical aging of polymer membranes by gas permeability measurements are compared. The traditional method with intermittent permeability monitoring is compared to the continuous permeability monitoring when the membrane occurs under excess pressure of the permeating gas throughout the experiment. A composite membrane with a thin (1 μm) selective polytrimethylsilylpropyne layer containing 10 wt % organic nanoparticles (porous aromatic frameworks) was taken as an example. The continuous permeability monitoring allows acceleration of the physical aging of the membrane and considerable (by two orders of magnitude) reduction of the experiment time. Fast physical aging in a carbon dioxide stream can be an efficient way to reach equilibrium gas permeability of membranes based on glassy polymers with high void volume.

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Funding

The study was supported by the Russian Science Foundation (project no. 18-19-00738).

Author information

Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    D. S. Bakhtin, A. O. Malakhov, V. G. Polevaya, L. A. Kulikov, A. M. Grekhov, S. D. Bazhenov & A. V. Volkov

  2. Moscow State University, 119991, Moscow, Russia

    L. A. Kulikov

  3. National Research Nuclear University Moscow Engineering Physics Institute, 115409, Moscow, Russia

    A. M. Grekhov

Authors
  1. D. S. Bakhtin
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  2. A. O. Malakhov
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  3. V. G. Polevaya
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  4. L. A. Kulikov
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  5. A. M. Grekhov
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  6. S. D. Bazhenov
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  7. A. V. Volkov
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Contributions

A.V. Volkov and A.M. Grekhov, idea and methodology of the study; V.G. Polevaya and L.A. Kulikov, synthesis of polytrimethylsilylpropyne and PAF-11 samples, respectively; D.S. Bakhtin, membrane preparation and characterization by SEM and gas permeability; A.O. Malakhov, S.D. Bazhenov, and D.S. Bakhtin, manuscript preparation; A.O. Malakhov, model processing of experimental data.

Corresponding author

Correspondence to D. S. Bakhtin.

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The authors declare that they have no conflict of interest.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 5, pp. 612–620, January, 2021 https://doi.org/10.31857/S0044461821050091

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Bakhtin, D.S., Malakhov, A.O., Polevaya, V.G. et al. Behavior of Polytrimethylsilylpropyne-Based Composite Membranes in the Course of Continuous and Intermittent Gas Permeability Measurements. Russ J Appl Chem 94, 616–623 (2021). https://doi.org/10.1134/S1070427221050098

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