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Influence of Hydrothermal Treatment Conditions on the Formation of Lanthanum Orthophosphate Nanoparticles of Monazite Structure

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The inluence of the heat treatment conditions and of the time of hydrothermal treatment at 210°С on the phase composition and size of crystallites and nanoparticles of lanthanum orthophosphate (LaPO4) was considered. The heating conditions in the course of hydrothermal synthesis of LaPO4 influence the structural transition of lanthanum orthophosphate of rhabdophane structure into the phase of monazite structure, and also the particle morphology and crystallite size. The phase of monazite structure with the crystallite size of approximately 12 nm without rhabdophane impurity is formed after hydrothermal treatment at 210°С for 30 min in the case of microwave heating of the hydrothermal fluid. When using external heating of autoclaves, at the same temperature inside the autoclave, the mean size of the crystallites of the monazite phase formed is 17 nm.

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ACKNOWLEDGMENTS

X-ray diffraction studies, scanning electron microscopy, and elemental analysis of the samples were performed using devices of the Engineering Center of the St. Petersburg State Institute of Technology (Technical University).

Funding

The study was financially supported by the Russian Foundation for Basic Research, project no. 19-33-50056.

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Authors and Affiliations

  1. Ioffe Institute, 194021, St. Petersburg, Russia

    M. O. Enikeeva, O. V. Proskurina & V. V. Gusarov

  2. St. Petersburg State Institute of Technology, 190013, St. Petersburg, Russia

    M. O. Enikeeva, O. V. Proskurina & D. P. Danilovich

  3. Al-Farabi Kazakh National University, 050040, Almaty, Kazakhstan

    K. M. Kenges

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  1. M. O. Enikeeva
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  2. K. M. Kenges
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  3. O. V. Proskurina
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Correspondence to M. O. Enikeeva.

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V.V. Gusarov is the member of the Editorial Board of Zhurnal Prikladnoi Khimii/Russian Journal of Applied Chemistry. The other authors have no conflict of interest.

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Enikeeva, M.O., Kenges, K.M., Proskurina, O.V. et al. Influence of Hydrothermal Treatment Conditions on the Formation of Lanthanum Orthophosphate Nanoparticles of Monazite Structure. Russ J Appl Chem 93, 540–548 (2020). https://doi.org/10.1134/S1070427220040084

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