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Sulfated Halloysite Nanoscrolls as Superacid Catalysts for Oligomerization of Hexene-1

  • Catalysis
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Abstract

Possibility of creating superacid catalysts on the basis of sulfated hydrosilicate nanoscrolls with halloysite structure and catalytic activity of the resulting materials in the model reaction of hexene-1 oligomerization were studied. The sulfation was performed with sulfuric acid solutions at concentrations of 0.25–1 M. The number of acid centers on the surface of the scrolls decreases with increase of the scid concentration, most probably due to the selective dissolution of the aluminum oxide sheet. In this case, the composition of the reaction products also changes, with the content of hexene-1 isomers increasing as compared with the oligomers. It was possible to obtain, at the lower boundary of the concentration range, an increased content of heavy fractions in the oligomerization products.

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Acknowledgments

The X-ray diffraction analysis was made on the equipment of the Engineering center of St. Petersburg State Technological Institute (Technical University). The electron microscopy was performed on the equipment of of the JRC PMR IGIC RAS. The liquid chromatography was performed on the equipment of the Center of for Collective Use “New Petrochemical Processes, Polymere Composites and Adhesives,” no. 77601.

Funding

The study was supported by the Russian Science Foundation (grant no. 17-73-10426).

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Krasilin & V. K. Ivanov

  2. Ioffe Institute, Russian Academy of Sciences, St. Petersburg, 194021, Russia

    A. A. Krasilin, E. K. Khrapova & M. V. Tomkovich

  3. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, 142432, Russia

    E. A. Straumal, L. L. Yurkova & S. A. Lermontov

  4. St. Petersburg Electrotechnical University “LETI,”, St. Petersburg, 197022, Russia

    E. K. Khrapova & I. G. Shunina

  5. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Russia

    L. P. Vasil’eva

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  1. A. A. Krasilin
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  2. E. A. Straumal
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  3. L. L. Yurkova
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  9. V. K. Ivanov
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Correspondence to A. A. Krasilin.

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The authors state that they have no conflict of interest to be disclosed in this communication.

Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 9, pp. 1170–1178.

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Krasilin, A.A., Straumal, E.A., Yurkova, L.L. et al. Sulfated Halloysite Nanoscrolls as Superacid Catalysts for Oligomerization of Hexene-1. Russ J Appl Chem 92, 1251–1257 (2019). https://doi.org/10.1134/S1070427219090106

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