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Sulfated alumina aerogel-based superacid catalysts for 1-hexene oligomerization

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Al2O3 aerogel samples were synthesized by supercritical drying in two different media: isopropanol and methyl tert-butyl ether. After sulfation in a SO2Cl2 vapor, the aerogel acquired superacid properties (–12.4 ≤ H 0 ≤–11.99) and efficiently catalyzed 1-hexene oligomerization and dimerization.

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References

  1. Aerogels Handbook, Ed. by M. A. Aegerter, N. Leventis, and M. M. Koebel (Springer, New York, 2011), p. 932.

  2. F. Blanchard, B. Pommier, J. P. Reymond, and S. J. Teichner, J. Mol. Catal. 17, 171 (1982).

    Article  CAS  Google Scholar 

  3. A. Sayari, A. Ghorbel, G. M. Pajonk, and S. J. Teichner, React. Kinet. Catal. Lett. 15, 459 (1980).

    Article  CAS  Google Scholar 

  4. R. Tleimat-Manzalji, T. Manzalji, and G. M. Pajonk, J. Non-Cryst. Solids 147–148, 744 (1992).

    Article  Google Scholar 

  5. C. Moreno-Castilla, F. Carrasco-Marín, and M. B. Dawidziuk, Catalysts 2, 422 (2012).

    Article  CAS  Google Scholar 

  6. I. V. Mishakov, E. V. Ilyina, A. F. Bedilo, and A. A. Vedyagin, React. Kinet. Catal. Lett. 97, 355 (2009).

    Article  CAS  Google Scholar 

  7. H. Hirashima, K. Kohama, and H. Imai, J. Sol-Gel Sci. Technol. 8, 843 (1997).

    CAS  Google Scholar 

  8. H. Hirashima, C. Kojima, K. Kohama, et al., J. Non-Cryst. Solids 225, 153 (1998).

    Article  CAS  Google Scholar 

  9. Y. Mizushima and M. Hori, Appl. Catal. A: Gen. 88, 137 (1992).

    Article  CAS  Google Scholar 

  10. J. N. Armor, E. J. Carlson, and P. M. Zambri, Appl. Catal. 19, 339 (1985).

    Article  CAS  Google Scholar 

  11. G. A. Olah, G. K. Prakash, and J. Sommer, Science 206, 13 (1979).

    Article  CAS  Google Scholar 

  12. K. Arata, Adv. Catal. 37, 165 (1990).

    CAS  Google Scholar 

  13. B. Fu, L. Gao, L. Niu, et al., Energy Fuels 23, 569 (2009).

    Article  CAS  Google Scholar 

  14. M. Marczewski, A. Jakubiak, H. Marczewska, et al., Phys. Chem. Chem. Phys. 6, 2513 (2004).

    Article  CAS  Google Scholar 

  15. L. M. Rodriguez, J. Alcaraz, M. Hernandez, et al., Appl. Catal. A: Gen. 189, 53 (1999).

    Article  CAS  Google Scholar 

  16. A. V. Lavrenov, I. A. Basov, M. O. Kazakov, et al., Ross. Khim. Zh. (Zh. Ross. Khim. Ob-va Im. D. I. Mendeleeva) 51 (4), 75 (2007).

    CAS  Google Scholar 

  17. V. K. Ivanov, A. E. Baranchikov, G. P. Kopitsa, et al., J. Solid State Chem. 198, 496 (2013).

    Article  CAS  Google Scholar 

  18. D. A. Ward and E. I. Ko, J. Catal. 150, 18 (1994).

    Article  CAS  Google Scholar 

  19. S. A. Lermontov, A. N. Malkova, L. L. Yurkova, et al., Nanosist.: Fiz., Khim., Mat. 4 (1), 113 (2013).

    CAS  Google Scholar 

  20. K. Tanabe, Solid Acids and Bases (Academic, New York, 1970).

    Book  Google Scholar 

  21. T.-S. Yang, T.-H. Chang, and C.-T. Yeh, J. Mol. Catal. A: Chem. 115, 339 (1997).

    Article  CAS  Google Scholar 

  22. A. Mantilla, F. Tzompantzi, G. Ferrat, et al., Chem. Commun., 13, 1498 (2004).

    Article  Google Scholar 

  23. A. K. Dalai, R. Sethuraman, S. P. R. Katikaneni, and R. O. Idem, Ind. Eng. Chem. Res. 37, 3869 (1998).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432, Russia

    S. A. Lermontov, L. L. Yurkova & E. A. Straumal

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. E. Baranchikov & V. K. Ivanov

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    I. G. Shunina

Authors
  1. S. A. Lermontov
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  2. L. L. Yurkova
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  3. E. A. Straumal
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  4. A. E. Baranchikov
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  5. I. G. Shunina
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  6. V. K. Ivanov
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Corresponding author

Correspondence to S. A. Lermontov.

Additional information

Original Russian Text © S.A. Lermontov, L.L. Yurkova, E.A. Straumal, A.E. Baranchikov, I.G. Shunina, V.K. Ivanov, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 1, pp. 9–12.

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Lermontov, S.A., Yurkova, L.L., Straumal, E.A. et al. Sulfated alumina aerogel-based superacid catalysts for 1-hexene oligomerization. Russ. J. Inorg. Chem. 61, 7–10 (2016). https://doi.org/10.1134/S0036023616010137

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  • DOI: https://doi.org/10.1134/S0036023616010137

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