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Physicochemical and catalytic properties of SAPO-31 materials prepared from the silica sources characterized by a different degree of polymerization

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Abstract

Two series of microporous silicoaluminophosphates SAPO-31 with different Si content (Si/Al = 0—0.5) were synthesized using silica sources characterized by various degree of polymerization (fumed silica and tetraethoxysilane). Physicochemical properties of the resulted materials were studied by X-ray diffraction, XPS, scanning (SEM) and transmission (TEM) electron microscopy. The nature of the silicon species was identified by 29Si NMR method and the acidity was measured by IR-spectroscopy of adsorbed pyridine. The activity and selectivity of Pd modified SAPO-31 samples from both series were evaluated in the isomerization of n-decane. It was found that the use of the monomer as a silicon source ensured more efficient silicon incorporation, which resulted in the higher activity of Pd/SAPO-31 catalysts. Moreover, the selectivity of these samples for isomerization was found to be independent of the silicon content and its distribution.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    M. Yu. Smirnova, M. G. Davydova & A. B. Ayupov

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    M. Yu. Smirnova

  3. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, 18 ul. Kutateladze, 630128, Novosibirsk, Russian Federation

    A. I. Titkov

  4. Research Institute of Inorganic Chemistry, RENTECH-UniCRE, Areal Chempark, Zaluzi, 436 70, Litvinov, Czech Republic

    O. V. Kikhtyanin

Authors
  1. M. Yu. Smirnova
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  2. M. G. Davydova
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  3. A. I. Titkov
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  4. A. B. Ayupov
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  5. O. V. Kikhtyanin
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Correspondence to M. Yu. Smirnova.

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Research Institute of Inorganic Chemistry, RENTECH-Uni-CRE, Czech Republic, 436 70 Litvinov, Chempark Litvinov, Zaluzi.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0231—0240, February, 2017.

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Smirnova, M.Y., Davydova, M.G., Titkov, A.I. et al. Physicochemical and catalytic properties of SAPO-31 materials prepared from the silica sources characterized by a different degree of polymerization. Russ Chem Bull 66, 231–240 (2017). https://doi.org/10.1007/s11172-017-1723-x

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  • DOI: https://doi.org/10.1007/s11172-017-1723-x

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