Abstract
Molecular theory of wetting was used to calculate the specific free surface energy of membranes based on amorphous polymers of varied chemical structure from experimental wetting angles obtained for test fluids. A relationship was found between the dispersion component of the surface energy of a membrane, its gas permeability, and free volume of the polymer. This makes it possible to employ the wetting method to prognosticate the transport properties of polymeric membranes. In wetting of membranes with aqueous solutions of alcohols, the concentration of an alcohol corresponding to the onset of its sorption into the membrane was determined. The correlation of the value obtained with the alcohol concentration that corresponds to the onset of sorption and is determined independently by the gravimetric method enables use of wetting angles for optimizing the conditions of experiments on nanofiltration and pervaporation.
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References
Kloubek, J., Adv. Colloid Int. Sci., 1992, vol. 38, pp. 99–142.
Vojtechovska, J. and Kvitek, L., Acta Univ. Palacki. Olomu., Fac. Rerum Nat., Chem., 2005, vol. 44, pp. 25–48.
Van Krevelen, D.V., Properties of Polymers: Correlations with Chemical Structure, EPC. Amsterdam, 1972.
Vakula, V.L. and Pritykin, L.M., Fizicheskaya khimiya adgezii polimerov (Physical Chemistry of Polymer Adhesion), Moscow: Khimiya, 1984.
Ruckenstein, E. and Gourisankar, S.V., Biomaterials, 1986, vol. 7, pp. 403–422.
Bogdanova, Yu.G., Dolzhikova, V.D., Karzov, I.M., and Alentiev, A.Yu., Molecular Mobility and Order in Polymer System, Darinskii, A., Ed., Weinheim, Wiley–VCH VerlagGmbH & Co. KGaA, 2012, vol. 316, pp. 63–70.
Adamson, A.W., Physical Chemistry of Surfaces, New York: John Wiley and Sons, 1976.
Summ, B.D. and Goryunov, Yu.V., Fiziko-khimicheskie osnovy smachivaniya i rastekaniya (Physicochemical Foundations of Wetting and Spreading), Moscow: Khimiya, 1976.
Staiger, C.L., Pas, S.J., Hill, A.J., and Cornelius, C.J., Chem. Mater., 2008, vol. 20, no. 8, pp. 2906–2608.
Volkov, A.V., Volkov, V.V., and Khotimskii, V.S., Polym. Sci., Ser. A, vol. 51, nos. 11–12, pp. 1367–1382.
Yampol’skii, Yu.P., Ross. Khim. Zh., 2008, vol. 52, no. 3, pp. 123–130.
Yushkin, A., Grekhov, A., Matson, S., Bermeshev, M., Khotimsky, V., Finkelstein, E., Budd, P.M., Volkov, V., Vlugt, T.J.H., and Volkov, A., React. Funct. Polym., 2015, vol. 86, pp. 269–281.
Chalykh, A.E., Diffuziya v polimernykh sistemakh (Diffusion in Polymeric Systems), Moscow: Khimiya, 1987.
Yampol’skii, Yu.P., Russ. Chem. Rev., 2007, vol. 76, no. 1, pp. 59–78.
Alentiev, A.Yu., Loza, K.A., and Yampolskii, Yu.P., J. Membr. Sci., 2000, vol. 167, pp. 91–106.
Baza dannykh “Gazorazdelitel’nye parametry stekloobraznykh polimerov” (Gas-separation Parameters of Glassy Polymers database), Informregistr RF. 1998, no. 3585.
Yushkin, A., Vasilevsky, V., Khotimskiy, V., Szymczyk, A., and Volkov, A., J. Membr. Sci., 2018, vol. 554, pp. 346–356.
Shchukin, E.D., Pertsov, A.V., Amelina, E.A., and Zelenev, A.S., Colloid and Surface Chemistry, Elsevier, 2001.
CRC Handbook of Chemistry and Physics, David R. Lide, Ed., CRC Press LLC, 2005.
Kratkaya khimicheskaya entsiklopediya v 5 tomakh (Concise Chemical Encyclopedia in 5 vols.), Knunyants, I.L., Ed., Moscow: Sovetskaya entsiklopediya, 1967.
Bondi, A., Physical Properties of Molecular Crystals, Liquids, and Glasses,. New York: Wiley, 1968.
Bogdano va, Yu.G., Dolzhikova, V.D., Gringol’ts, M.L., Kostina, J.V., Tikhonov, N.A., and Alentiev, A.Yu., Polym. Sci., Ser. A, 2013, vol. 55, no. 8, pp. 471–479.
Bogdanova, Yu.G., Dolzhikova, V.D., and Yushkin, A.A., Chem. Bull. Kazakh National. Univ., 2015, vol. 79, no. 3, pp. 50–57.
Golemme, G., Nagy, J.B., Fonseca, A., Algieri, C., and Yampolskii, Yu., Polymer, 2003, vol. 44, pp. 5039–5045.
Finkelshtein, E.Sh., Makovetskii, K.L., Yampol’skii, Yu.P., Portnykh, E.B., Ostrovskaya, I.Ya., Kaliuzhnyi, N.E., Pritula, N.A., Golberg, A.I., Yatsenko, M.S., and Plate, N.A., Makromol. Chem., 1991, vol. 192, no. 1, pp. 1–9.
Finkelshtein, E.Sh., Gringolts, M.L., Ushakov, N.V., Lakhin, V.G., Sobolev, S.A., and Yampol'skii, Yu.P., Polymer, 2003, vol. 44, pp. 2843–2851.
Yampolskii, Yu., Soloviev, S.A., and Gringolts, M.L., Polymer, 2004, vol. 45, pp. 6945–6952.
Finkelshtein, E.Sh., Makovetskii, K.L., Gringolts, M.L., Rogan, Yu.V., Golenko, T.G., Starannikova, L.E., Yampolskii, Yu.P., Shantarovich, V.P., and Suzuki, T., Macromolecules, 2006, vol. 39, no. 20, pp. 7022–7029.
Masuda, T., Kawasaki, M., Okano, Y., and Higashimura, T., Polym. J., 1982, vol. 14, pp. 371–380.
Hofmann, D., Heuchel, M., Yampolskii, Yu., Khotimskii, V., and Shantarovich, V., Macromolecules, 2002, vol. 35, no. 6, pp. 2129–2140.
Morisato, A. and Pinnau, I., J. Membr. Sci., 1996, vol. 121, pp. 243–250.
Alentiev, A.Yu., Yampolskii, Yu.P., Shantarovich, V.P., Nemser, S.M., and Plate, N.A., J. Membr. Sci., 1997, vol. 126, pp. 123–132.
Grin golts, M.L., Bermeshev, M.V., Starannikova, L.E., Rogan, Yu.V., Yampolskii, Yu.P., and Finkelshtein, E.Sh., Polym. Sci., Ser. A, 2009, vol. 51, nos. 11–12, pp. 1233–1240.
Khotimsky, V.S., Matson, S.M., Litvinova, E.G., Bondarenko, G.N., and Rebrov, A.I., Polym. Sci., Ser. A, 2003, vol. 45, pp. 740–746.
Bogdanova, Yu.G., Dolzhikova, V.D., and Mazhuga, A.G., Russ. Chem. Bull., 2010, vol. 59, no. 7, pp. 1343–1348.
Onosova, L.A., Avdeeva, E.A., Chalykh, A.E., and Tseitlin, G.M., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2006, vol. 49, no. 11, pp. 45–48.
Tavana, H., Simon, F., Grundke, K., Kwok, D.Y., Hair, M.L., and Neumann, A.W., J. Colloid Int. Sci., 2005, vol. 291, no. 2, pp. 497–506.
Rostiashvili, V.G., Irzhak, V.I., and Rozenberg, B.A., Steklovanie polimerov (Vitrification of Polymers), Leningrad: Khimiya, 1987.
Batschinsky, A., Ztschr. phys. Chem., 1913, vol. 84, pp. 643–706.
Ferguson, A. and Sc, M.A.D., Trans. Faraday Soc., 1923, vol. 19, pp. 407–412.
Volynskii, A.L. and Bakeev, N.F., Rol’ poverkhnostnykh yavlenii v strukturno-mekhanicheskom povedenii tverdykh polimerov (Role Played by Surface Phenomena in Structural-Mechanical Behavior of Solid Polymers), Moscow: Fizmatlit, 2005.
Reitlinger, S.A., Pronitsaemost’ polimernykh materialov (Permeability of Polymeric Materials), Moscow: Khimiya, 1974.
Park, J.Y. and Paul, D.R., J. Membr. Sci., 1997, vol. 125, no. 1, pp. 23–39.
Bogdanova, L.M., Irzhak, V.I., Rozenberg, B.A., and Enikolopyan, N.S., Doklady Akad. Nauk SSSR, 1983, vol. 268, no. 5, pp. 1139–1141.
Genzer, J. and Efimenko, K., Biofouling, 2006, vol. 22, pp. 339–360.
Filippov, A.N., Ivanov, V.I., Yushkin, A.A., Volkov, V.V., Bogdanova, Yu.G., and Dolzhi kova, V.D., Petroleum Chem., 2015, vol. 55, no. 5, pp. 347–362.
Dolzhikova, V.D., Goryunov, Yu.V., and Summ, B.D., Kolloid. Zh., 1981, vol. 21, no. 3, pp. 560–563.
Volkov, A., Yushkin, A., Grekhov, A., Shutova, A., Bazhenov, S., Tsarkov, S., Khotimsky, V., Vlugt, T.J.H., and Volkov, V., J. Membr. Sci., 2013, vol. 440, pp. 98–107.
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Original Russian Text © Yu.G. Bogdanova, V.D. Dolzhikov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 8, pp. 1154−1165.
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Bogdanova, Y.G., Dolzhikov, V.D. Relationship between Energy Characteristics of Surface of Polymeric Membranes and Their Transport Properties. Russ J Appl Chem 91, 1311–1321 (2018). https://doi.org/10.1134/S1070427218080098
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DOI: https://doi.org/10.1134/S1070427218080098