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Hydrocracking of vacuum gas oil in the presence of catalysts NiMo/Al2O3–amorphous aluminosilicates and NiW/Al2O3–amorphous aluminosilicates

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Supported nickel–molybdenum and nickel–tungsten hydrocracking catalysts prepared using a support that consists of 70% Al2O3 and 30% amorphous aluminosilicate were characterized by nitrogen and mercury porosimetry, IR spectroscopy of adsorbed CO, and high-resolution electron microscopy. The catalytic tests in hydrocracking of vacuum gas oil containing 3.39% sulfur showed that the nature of the hydrogenating component (NiMo or NiW) only slightly influences the vacuum gas oil conversion and the diesel fraction yield, but noticeable influences the properties of the diesel fraction obtained. The catalyst NiMo/Al2O3–amorphous aluminosilicates, compared to NiW/Al2O3–amorphous aluminosilicates, ensures lower sulfur content in the diesel fraction obtained, whereas the catalyst NiW/Al2O3–amorphous aluminosilicates allows obtaining a diesel fraction with lower content of polyaromatic compounds.

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References

  1. Dik, P.P., Klimov, O.V., Koryakina, G.I., et al., Catal. Today, 2014, vols. 220–222, pp. 124–132.

    Article  Google Scholar 

  2. Dik, P.P., Klimov, O.V., Budukva, S.V., et al., Catal. Ind., 2014, vol. 6, no. 3, pp. 231–238.

    Article  Google Scholar 

  3. Yasuda, H., Higo, M., Yoshitomi, S., et al., Catal. Today, 1997, vol. 39, nos. 1–2 pp. 77–87.

    Article  CAS  Google Scholar 

  4. Halachev, T., Nava, R., and Dimitrov, L., Appl. Catal. A, 1998, vol. 169, no. 1, pp. 111–117.

    Article  CAS  Google Scholar 

  5. Kabe, T., Aoyama, Y., and Wang, D., Appl. Catal. A, 2001, vol. 209, nos. 1–2 pp. 237–247.

    Article  CAS  Google Scholar 

  6. Alsobaai, A.M., Zakaria, R., and Hameed, B.H., Chem. Eng. J., 2007, vol. 132, nos. 1–3 pp. 77–83.

    Article  CAS  Google Scholar 

  7. Ali, M.A., Tatsumi, T., and Masuda, T., Appl. Catal. A, 2002, vol. 233, nos. 1–2 pp. 77–90.

    Article  CAS  Google Scholar 

  8. US Patent 6399530 B1, Publ. 2002.

  9. RF Patent 2472585, Publ. 2013.

  10. Pereyma, V.Yu., Gerasimov, E.Yu., Klimov, O.V., and Noskov, A.S., Russ. J. Appl. Chem., 2015, vol. 88, no. 9, pp. 1458–1463.

    Article  CAS  Google Scholar 

  11. Ivanova, A.S., Korneeva, E.V., Bukhtiyarova, G.A., et al., Kinet. Catal., 2011, vol. 52, no. 3, pp. 446–458.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, ul. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    V. Yu. Pereyma, P. P. Dik, O. V. Klimov, S. V. Budukva, K. A. Leonova & A. S. Noskov

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  1. V. Yu. Pereyma
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  2. P. P. Dik
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  3. O. V. Klimov
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  4. S. V. Budukva
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  5. K. A. Leonova
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  6. A. S. Noskov
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Correspondence to V. Yu. Pereyma.

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Original Russian Text © V.Yu. Pereyma, P.P. Dik, O.V. Klimov, S.V. Budukva, K.A. Leonova, A.S. Noskov, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 12, pp. 1722–1728.

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Pereyma, V.Y., Dik, P.P., Klimov, O.V. et al. Hydrocracking of vacuum gas oil in the presence of catalysts NiMo/Al2O3–amorphous aluminosilicates and NiW/Al2O3–amorphous aluminosilicates. Russ J Appl Chem 88, 1969–1975 (2015). https://doi.org/10.1134/S10704272150120113

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  • DOI: https://doi.org/10.1134/S10704272150120113

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