Skip to main content

Advertisement

SpringerLink
Log in

Hydrocracking of Vacuum Gas Oil on Bimetallic Ni-Mo Sulfide Catalysts Based on Mesoporous Aluminosilicate Al-HMS

  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

The activity and selectivity of a bimetallic Ni-Mo sulfide catalyst based on mesoporous aluminosilicate Al-HMS with Si/Al ratio of 10 in the vacuum gas oil hydrocracking process in a reactor with a fixed catalyst bed was studied. The dependence of the activity and selectivity of the NiS-MoS2/Al-HMS (Si/Al = 10) catalyst on the process parameters (temperature, hydrogen pressure, volume stock feed rate, etc.) was investigated. It was shown that in the 380-450°C range at 5 MPa hydrogen pressure the catalyst ensures conversion of the heavy part of the hydrocarbon stock into fuel fractions with high selectivity in the middle distillates and makes it possible to reduce the sulfur content of the liquid hydrocracking products.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. R. E. Palmer, G. U. Johnson, Neftegazovye Tekhnologii, No. 4, 46-47 (2004).

    Google Scholar 

  2. O. V. Kimov, Khimiya v Interesov, Ustoichivogo Razvitiya, No. 19, 59-66 (2011).

  3. M. S. Rana, V. Sámano, J. Ancheyta, J. A. I Diaz, Fuel , 86,1216-1231 (2007).

  4. R. Sahu, B. J. Song, J. S. Im, et. al, Journal of Industrial and Engineering Chemistry, 27, 12-24 (2015).

  5. T. Chiranjeevi, P. Kumar, M. S. Rana, et. al., Journal of Molecular Catalysis A: Chemical, 181, 109-117 (2002).

    Article  CAS  Google Scholar 

  6. A. Corma, A. Martinez, V. Martinez-Soria, Journal of Catalysis, 200, 259-269 (2001).

    Article  CAS  Google Scholar 

  7. A. Alvarez, J. Ancheyta, Chemical Engineering Science, 63, 662-673 (2008).

    Article  CAS  Google Scholar 

  8. T. Linssen, K. Cassiers, P. Cool, E. F. Vansant, Advances in Colloid and Interface Science, 103, 121 (2003).

    Article  CAS  Google Scholar 

  9. B. Pawelec, S. Damyanova, R. Mariscal, et al., Journal of Catalysis, 223, 86-97 (2004).

    Article  CAS  Google Scholar 

  10. A. Tuel, S. Gontier, Chemistry of Materials, 8, 114-122 (1996).

    Article  CAS  Google Scholar 

  11. F. Subhan et al., Fuel Processing Technology, 97(0), 71-78 (2012).

  12. R. Mokaya, W. Jones, Journal of Catalysis, 172, 211 (1997).

    Article  CAS  Google Scholar 

  13. J. P. Gilson, G. C. Edwards, A. W. Peters, et. al., Journal of the Chemical Society, Chemical Communications, 91-92 (1987).

  14. G. Kishan, L. Coulier, J. A. R. Veen, et. al., Journal of Catalysis, 200, 194-196 (2001).

    Article  CAS  Google Scholar 

  15. H. Topsoe, B. S. Clausen, Catalysis Reviews: Science and Engineering, No. 26 (3-4), 395-420 (1984).

  16. S. B. Petrykin, D. O. Kapustin, Zh. Xinping, et al., Nefteprodukty: Tekhnologiya, Innovatsiya, Rynok, No. 4-5, 54-57 (2010).

  17. K. T. Ng, D. M. Hercules, Journal of Physical Chemistry, 80, 2094-2102 (1976).

    Article  CAS  Google Scholar 

  18. R. A. Meyers, Fundamental Processes of Oil Refining [Russian translation] (Eds. O. F. Glagoleva, O. P. Lykov), TsOP “Professiya”, St. Petersburg (2011), 944 pp.

  19. P. Raybaud, J. Hafner, G. Kresse, et. al, Journal of Catalysis, 190, 128-143 (2000).

    Article  CAS  Google Scholar 

Download references

The authors express their gratitude to GK “Khromos” for supplying the equipment (the “Khromos GKh-1000” gas chromatograph).

Author information

Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, Moscow, Russia

    A. V. Vutolkina, A. P. Glotov, S. V. Egazar’yants, M. Yu. Talanova, N. A. Sinikova, S. V. Kardashev, A. L. Maksimov & E. A. Karakhanov

  2. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    A. L. Maksimov

Authors
  1. A. V. Vutolkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. P. Glotov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Egazar’yants
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Yu. Talanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. A. Sinikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. V. Kardashev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. L. Maksimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. E. A. Karakhanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. A. Karakhanov.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 5, pp. 34 – 41, September– October, 2016.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vutolkina, A.V., Glotov, A.P., Egazar’yants, S.V. et al. Hydrocracking of Vacuum Gas Oil on Bimetallic Ni-Mo Sulfide Catalysts Based on Mesoporous Aluminosilicate Al-HMS. Chem Technol Fuels Oils 52, 515–526 (2016). https://doi.org/10.1007/s10553-016-0738-6

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10553-016-0738-6

Keywords

Search

Navigation