Abstract
The electrochemical deposition of silver was investigated from 0.01–0.1 M acetonitrile solutions of Ag NO3 by stationary and pulse current. An effect of the main parameters of the pulse current (duration and pause of pulse), concentrations of silver ions, time of electrolysis, and nature of support was considered on form and size of structural particles of deposit.
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References
Hasse, U. and Scholz, F., J. Solid State Electrochem., 2006, vol. 10, pp. 380–382.
Maksimovic, V.M., Pavlovic, M.G., Pavlovic, Lj.J. et al., Hydrometallurgy, 2007, vol. 86, nos. 1–2, pp. 22–26.
Yasnikov, I.S. and Tsybuskina, I.I., ZhTF., 2008, vol. 53, no. 11, pp. 130–133.
Knauth, P., J. Solid State Electrochem., 2001, vol. 5, pp. 107–111.
Maciej Mazur., Electrochem. Commun., 2004, vol. 6, pp. 400–403.
Guoyu, Gao, Daojun, Guo, Ce, Wang, and Hulin, Li., Electrochem. Commun., 2007, vol. 9, pp. 1582–1586.
Hossain, Asadul, S.M., and Saitou, M., J. Appl. Electrochem., 2008, vol. 38, no. 12, pp. 1653–1657.
Gandhi, T., Raja, K.S., and Misra, M., Electrochim. Acta, 2006, vol. 51. N,26, pp. 5932–5942.
Kalymon, Ya.A., Bilan’, O.I., and Kuntyi, O.I., Zh. Prikl. Khim., 2009, vol. 82, no. 7, pp. 1130–1133.
Kuntyi, O.I., Okhremchuk, E.V., Bilan’, O.I., and Yavorskii, V.T., Vopr. Khimii Khim. Tekhnologii, 2007, no. 6, pp. 192–195.
Kuntyi, O.I., Electrochemistry and Morphology of Disperse Metals (Ukr.), Lviv: Publ. House Lviv Polytechnic National University, 2008., 208 p.
Kuntyi, O.I., Chemistry a. Chem. Technol., 2007, vol. 1, no. 3, pp. 117–120.
Nichiporenko, O.S., Pomosov, A.V., and Naboichenko, S.S., Poroshki medi i ee splavov, Moscow: Metallurgiya, 1988.
Kostin, N.A. and Kublanovskii, V.S., Impul’snyi elektroliz splavov (Pulse Electrolysis of Alloys), Kiev: Naukova Dumka, 1996.
Kuntyi, O.I., Vopr. Khimii Khim. Tekhnologii, 2004, no. 2, pp. 160–162.
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Original Russian Text © O.I. Kuntyi, O.I. Bilan’, E.V. Okhremchuk, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 2, pp. 203–207.
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Kuntyi, O.I., Bilan’, O.I. & Okhremchuk, E.V. Morphology of silver electrolytically precipitated from acetonitrile solutions of silver nitrate. Russ J Appl Chem 84, 199–203 (2011). https://doi.org/10.1134/S1070427211020066
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DOI: https://doi.org/10.1134/S1070427211020066